A celadonitic clay deposit is located ∼40 km north-west of Yazlıca-Kütahya (Türkiye) and has promising reserves for ceramic production. To evaluate the potential use of this region, 10 representative clay samples were collected and characterized using X-ray diffraction (XRD), polarized-light microscopy (PM), X-ray fluorescence (XRF), differential scanning calorimetry (DSC), Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). According to the Chemical Index of Alteration and Chemical Index of Weathering, the celadonitic clay samples were formed by strong chemical alteration of the Kızıltepe volcanic rocks occurring in the study area. Based on XRD data, SEM-EDS data and chemical and thermal analysis results, the primary minerals present were celadonite-Al, montmorillonite and nontronite in the clay samples formed by the weathering of basaltic rocks. The clay samples were used in thermal and physical tests. Firing properties, including water absorption, dry shrinkage, firing shrinkage, total shrinkage and glaze adhesion, were determined. The white clay specimens are suitable for more decorative and less load-bearing applications, having high porosity and low strength. The green clay samples, however, are ideal for technical and industrial ceramics, having an extremely compact structure and high strength. The properties of these two clays are beneficial for application in different areas in terms of their mechanical and ceramic performance. Additionally, the representative green celadonitic clay samples were used in recipes for opaque, transparent and matte glazes, creating artistic glaze effects for pigments. Hence, the green clay samples could be used as a ceramic pigment.

A clay from Weslatiya that is widely used in Tunisian ceramic production has abundant reserves but generates significant waste, posing environmental concerns if not handled appropriately. This study explores the valorization of this local clay by incorporating ceramic waste (chamotte) and quartz sand to produce eco-friendly materials, in line with sustainability and circular economy principles. X-ray diffraction and scanning electron microscopy analyses reveal that incorporating chamotte at levels exceeding 15% by weight improves the material’s properties. The Young’s modulus of the composite increases to 80 GPa, more than 2.5 times that of the basic clay. Chamotte can replace up to 30% of quartz sand without significantly affecting densification or porosity while preserving structural integrity. This approach offers flexibility in terms of material composition, enhancing performance and promoting sustainability by reusing waste materials for high-performance ceramics in industrial applications.

Peloids are natural therapeutic muds or clays used in balneotherapy and other health treatments. The aim of this study is to prepare and qualify three artificial peloids by maturation for 360 days of some Tunisian smectitic clays with a naturally chlorinated sodic mineral water from a spring in Korbous, Tunisia. This was done to improve our understanding of the behaviour of these clays and the physicochemical changes that affect the clays during maturation, with the purpose of providing suitable raw materials as a solid phase for peloid preparation. The results showed that parameters such as mineralogy, geochemistry, granulometry, cation-exchange capacity, consistency parameters (Atterberg limits and plasticity index), specific surface area, cooling kinetics and pH are all affected by the geochemistry of the thermal water used during maturation. Mineralogical modifications mostly concern the clay minerals’ contents, particularly smectite, and subordinately the dissolution of gypsum and the neoformation of halite. The observed improvements to the plasticity index and cooling kinetics can be explained by the ability of water molecules, and especially cations, to diffuse into the clay particles. The main exchangeable cations are Na+ and Ca2+, along with Mg2+ and K+, which promote swelling and increase water retention and consequently retention of heat in thermal spa treatments. The chemical composition of the major elements is closely linked to the mineralogical compositions of the clays, and also to the chemical composition of the thermal water used in their maturation. The safety profiles of the peloids obtained at different maturation times were evaluated, particularly regarding their content of potentially toxic elements such as arsenic.

This study investigates two clayey facies from the Bomkoul area in the littoral region of Cameroon for their suitability as fired clay building products. The field study consisted of a geological survey and a geotechnical mission (G0). Assessment of the raw clayey materials included their mineralogy, particle size, determination of Atterberg limits, density and shear stress. Firing properties (shrinkage, water absorption and flexural strength) at 900−1100°C were also determined. The two main facies observed in the field are the mottled red/yellow grey clays from surface ‘A’ with a thickness of 2.0–2.5 m and the deep blackish fossiliferous schisteous grey clays ‘B’ with a thickness of 8−10 m. Estimation based on boreholes revealed a minimum of 1,400,000 tons of clayey materials. These reserves will supply a small brick-manufacturing unit for a minimum period of 25 years at an extraction rate of 50,000 tons per year. The main clay minerals of both samples are kaolinite (35% and 49%) and illite (1–11%). Both samples contain quartz (47% and 49%) as non-clay minerals, associated with a small amount of anatase (0.5–2.6%) and trace hematite (<1%). The major oxides are SiO2 (71–76%) and Al2O3 (14%). The raw clayey material ‘A’ was finer and more plastic than the ‘B’ facies. The technological properties of the fired bricks obtained from the ‘A’ facies showed greater potential than the ‘B’ facies in terms of sonority and flexural strength. A mixture made of 40% ‘A’ and 60% ‘B’ yielded satisfactory brick properties at 1050°C.

Swelling soils, particularly those rich in smectite, present significant challenges to civil engineering due to their shrinking–swelling behaviour. Lime stabilization is a commonly used practice to address this, but the reactivity of smectite minerals in an alkaline limestone environment differs widely. This study investigates the reactivity of two Moroccan smectite-rich clays – montmorillonite-dominated bentonite and stevensite/saponite-rich bentonite – when treated with aerial lime. Through mineralogical, microstructural and mechanical analyses, this study highlights the distinct behaviour of montmorillonite, which reacts with lime to form calcium silicate hydrate gels, compared to the inert response of stevensite/saponite. Despite its low pozzolanic activity, stevensite-bentonite demonstrates greater mechanical strength, reaching 2.5 MPa in the S3 mixture (90% stevensite-bentonite and 10% lime). This strength is attributed to the formation of calcite through the de-dolomitization of dolomite. The findings reveal different stabilization mechanisms between dioctahedral and trioctahedral smectites, offering new insights for soil stabilization strategies involving these smectite types.

The present study documents coastal processes of movement and subsidence that affect the clayey sediments of the exposed mudflats (‘mudflat sediments’) on the receding western shore of the Deep Dead Sea (‘western Dead Sea shore’) and the formation of subsidence features: subsidence strips and clustered sinkholes. The properties of the clayey sediments that promote movement and subsidence and the development of the subsidence features in the exposed mudflats are the unconsolidated fine-particle texture composed of clay and carbonate minerals, their being dry near the surface and wet at the subsurface, their soaking with saline water and brine and the abundance of smectitic clays saturated with sodium and magnesium. Field observations indicate that narrow subsidence strips with/without clustered sinkholes were developed by movement and subsidence in mudflat sediments via lateral spreading. Wide subsidence strips with clustered sinkholes were developed via increased subsidence in mudflat sediments due to the progress of dissolution within a subsurface rock–salt unit. The emergence of sinkholes occurs via subsidence of mudflat sediments into subsurface cavities resulting from dissolution within a subsidence rock–salt unit. The coastal processes on the receding Dead Sea shore and the formation of the subsidence features are part of the adjustment of the Dead Sea periphery to the lowering of the base level. A contribution of slow mass movement seaward to the coastal processes on the receding Dead Sea shore is indicated.