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1 - Introduction

Published online by Cambridge University Press:  05 August 2012

Craig M. Bethke
Affiliation:
University of Illinois, Urbana-Champaign
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Summary

As geochemists, we frequently need to describe the chemical states of natural waters, including how dissolved mass is distributed among aqueous species, and to understand how such waters will react with minerals, gases, and fluids of the Earth's crust and hydrosphere. We can readily undertake such tasks when they involve simple chemical systems, in which the relatively few reactions likely to occur can be anticipated through experience and evaluated by hand calculation. As we encounter more complex problems, we must rely increasingly on quantitative models of solution chemistry and irreversible reaction to find solutions.

The field of geochemical modeling has grown rapidly since the early 1960s, when the first attempt was made to predict by hand calculation the concentrations of dissolved species in seawater. Today's challenges might be addressed by using computer programs to trace many thousands of reactions in order, for example, to predict the solubility and mobility of forty or more elements in buried radioactive waste.

Geochemists now use quantitative models to understand sediment diagenesis and hydrothermal alteration, explore for ore deposits, determine which contaminants will migrate from mine tailings and toxic waste sites, predict scaling in geothermal wells and the outcome of steam-flooding oil reservoirs, solve kinetic rate equations, manage injection wells, evaluate laboratory experiments, and study acid rain, among many examples. Teachers let their students use these models to learn about geochemistry by experiment and experience.

Many hundreds of scholarly articles have been written on the modeling of geochemical systems, giving mathematical, geochemical, mineralogical, and practical perspectives on modeling techniques.

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Publisher: Cambridge University Press
Print publication year: 2007

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  • Introduction
  • Craig M. Bethke, University of Illinois, Urbana-Champaign
  • Book: Geochemical and Biogeochemical Reaction Modeling
  • Online publication: 05 August 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511619670.004
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  • Introduction
  • Craig M. Bethke, University of Illinois, Urbana-Champaign
  • Book: Geochemical and Biogeochemical Reaction Modeling
  • Online publication: 05 August 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511619670.004
Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Introduction
  • Craig M. Bethke, University of Illinois, Urbana-Champaign
  • Book: Geochemical and Biogeochemical Reaction Modeling
  • Online publication: 05 August 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511619670.004
Available formats
×