Adjuvants influence weed control and crop tolerance provided by postemergence (POST) herbicides. Adjuvant effects on weed control and corn and soybean tolerance with CGA-248757 and flumiclorac applied alone and soybean tolerance with CGA-248757 and flumiclorac applied in combination with imazethapyr or CGA-277476 were evaluated. Velvetleaf control in the greenhouse and common lambsquarters, redroot pigweed, and common ragweed control in the greenhouse and field with CGA-248757 and flumiclorac were increased by the addition of an adjuvant. However, corn and soybean tolerance to these herbicides was not affected by adding an adjuvant. Laboratory studies suggest enhanced weed control from the addition of an adjuvant resulted from an increase in CGA-248757 and flumiclorac foliar absorption. In greenhouse studies, velvetleaf, common lambsquarters, and redroot pigweed control with CGA-248757 plus imazethapyr; velvetleaf control with flumiclorac plus imazethapyr; redroot pigweed and common ragweed control with CGA-248757 plus CGA-277476; and velvetleaf, redroot pigweed, and common ragweed control with flumiclorac plus CGA-277476 increased by adding an organosilicone adjuvant when compared with adding a nonionic surfactant (NIS). However, in field evaluations of CGA-248757 or flumiclorac plus imazethapyr, the addition of NIS or an organosilicone adjuvant resulted in equivalent soybean injury, common lambsquarters and redroot pigweed control, and soybean yield. Yet in tank mixtures of CGA-248757 or flumiclorac plus CGA-277476, the addition of an organosilicone adjuvant increased redroot pigweed control and soybean yield compared to adding NIS.

Field experiments were conducted at East Lansing and Clarksville, MI, to evaluate the efficacy of imazamox, imazethapyr, and CGA-277476 plus quizalofop applied postemergence in wide- (76-cm) and narrow- (19-cm) row soybean. Soybean injury from all herbicides was minimal 14 days after treatment (DAT), except for CGA-277476 at 79 g ai/ha plus 69 g ai/ha quizalofop, which caused 30% soybean injury at the Clarksville location. Adding 4 g ai/ha CGA-248757 to 65 g ai/ha CGA-277476 plus quizalofop reduced common ragweed control, but increased redroot pigweed control in wide rows compared to 79 g ai/ha CGA-277476 plus quizalofop. Imazamox at 35 and 45 g ai/ha provided greater common ragweed and common lambsquarters control than imazethapyr at 70 g ai/ha 28 DAT. All herbicide treatments controlled velvetleaf. Common ragweed and common lambsquarters control by all herbicide treatments was enhanced in narrow- compared to wide-row soybean 56 DAT as was redroot pigweed control by CGA-277476 treatments. Total weed biomass and soybean yield in wide-row soybean treated with imazamox at 45 g/ha was not different from the hand-weeded control. In narrow-row soybean, soybean yield was equal to the hand-weeded control for 35 and 45 g/ha imazamox and 70 g/ha imazethapyr. Postemergence herbicide treatments resulted in less weed biomass and greater soybean yield in narrow- compared to wide-row soybean.

Field and greenhouse experiments were conducted to evaluate postemergence (POST) soybean injury and weed control with CGA-277476 and cloransulam-methyl alone and in tank mixtures. In the field, visible soybean injury was 12 to 14% from CGA-277476 and 9 to 13% from cloransulam-methyl 7 d after treatment. Tank mixtures of either herbicide with acifluorfen or acifluorfen plus thifensulfuron were more injurious than CGA-277476 or cloransulam-methyl applied alone. Both CGA-277476 and cloransulam-methyl reduced velvetleaf dry weight 82%, and cloransulam-methyl reduced common ragweed dry weight 92%. Neither herbicide adequately controlled common lambsquarters, redroot pigweed, nor eastern black nightshade. The addition of acifluorfen to the spray solution improved common ragweed, common lambsquarters, redroot pigweed, and eastern black nightshade control with CGA-277476 and improved common lambsquarters, redroot pigweed, and eastern black nightshade control with cloransulam-methyl. Tank mixing thifensulfuron with CGA-277476 or cloransulam-methyl increased common lambsquarters and redroot pigweed control. In the greenhouse, CGA-277476 at 20 g ai/ha reduced velvetleaf dry weight 98%, and 79 g/ha was required to reduce common ragweed dry weight 93%. Cloransulam-methyl at 4.4 g ai/ha reduced velvetleaf dry weight 98% and common ragweed dry weight 94% at 8.8 g/ha. Chlorimuron reduced yellow nutsedge dry weight more than CGA-277476 or cloransulam-methyl. Antagonism of POST graminicide activity by CGA-277476 was grass species and graminicide related. CGA-277476 reduced giant foxtail control by clethodim but not by quizalofop. Cloransulam-methyl tank mixed with clethodim or quizalofop controlled giant foxtail.

Spring barley often is grown in rotation with winter wheat, and sometimes barley can overwinter in the subsequent winter wheat crop reducing grain yield and quality. Studies were established during 1996 and 1997 in winter wheat fields in southeastern Washington and near Moscow, ID, respectively, to evaluate control of ‘Steptoe’ volunteer barley with MON 37500, diclofop, and fenoxaprop/2,4-D/MCPA. Herbicides were applied to volunteer barley at two growth stages: two leaves to four tillers and more than four tillers with stems beginning to elongate. MON 37500 at 0.018, 0.026, and 0.035 kg ai/ha visibly controlled volunteer barley 83% or more at both application times. Diclofop at 1.12 kg ai/ha did not control volunteer barley, whereas fenoxaprop/2,4-D/MCPA at 0.66 kg ai/ha controlled volunteer barley 64 to 97% in 1996, but only 0 to 23% in 1997. In 1996 and 1997, volunteer barley density was reduced 80 to 99% in MON 37500-treated plots compared to the untreated control plots. Wheat grain grade was #1 for all MON 37500 treatments compared to grade #4 in 1996 and #3 in 1997 in the untreated plots. Grain price was reduced by dockage (barley kernels) for MON 37500-treated wheat $0 to $3.12/metric ton (MT), whereas price was reduced $23 to $26/MT for grain from untreated plots. In greenhouse studies, visible injury and height and biomass reduction varied among the 36 barley varieties treated with MON 37500.

Spurred anoda is an increasing weed problem in Colorado pinto bean production. This research was designed to evaluate reduced rates of bentazon and imazethapyr applied at various times for spurred anoda control and profitability. In 1993, spurred anoda control with early applications of either bentazon or imazethapyr was superior to late applications. Bentazon provided better spurred anoda control than imazethapyr in June. Spurred anoda control in 1993 was better than in 1994 due to late-emerging weeds and herbicide treatments not providing residual control. In 1994, bentazon controlled spurred anoda better than imazethapyr 1 and 3 wk after late POST, but no treatment provided commercially acceptable full-season control. The number of treatments with gross margins greater than the untreated check increased as pinto bean prices increased, but ranking of gross margin did not change due to pinto bean prices.

Wild carrot is becoming a serious weed problem in Michigan continuous no-tillage crop production. Greenhouse and field research was conducted to identify effective management strategies for wild carrot control in no-tillage cropping systems. In the greenhouse, PRE applications of acetochlor plus dichlormid (5.8:1 w:w), cyanazine, linuron plus chlorimuron (18:1), and metribuzin plus chlorimuron (10:1) and POST applications of bentazon, CGA-152005, clopyralid, cyanazine, and MON 12000 provided the greatest control of wild carrot seedlings. In the field, PRE and POST treatments containing chlorimuron consistently controlled overwintered wild carrot greater than 71% at 30 d after the POST application in no-tillage soybean. Atrazine, MON 12000, nicosulfuron, and primisulfuron applied POST consistently controlled overwintered wild carrot greater than 78% at 30 DAT in no-tillage corn. Glyphosate at 0.84 or 1.68 kg ae/ha applied in October to established wild carrot provided greater than 74% control the following spring. Early preplant (EPP) applications of glyphosate at 0.84 kg/ha in no-tillage soybean gave 95 and 24% control of overwintered wild carrot in St. Clair and Lenawee Counties, MI, respectively, at 70 DAT. PRE applications of glyphosate at 0.84 kg/ha controlled overwintered wild carrot less than 69% at 58 DAT in no-tillage corn and soybean. Fall applications of 2,4-D ester at 1.12 kg ae/ha provided 18 and 88% control of wild carrot the following spring in Clinton and Lenawee Counties, respectively. EPP applications of 2,4-D ester at 1.12 kg/ha provided 7 and 72% control of overwintered wild carrot in St. Clair and Lenawee Counties, respectively.

Field studies were conducted in 1995 and 1996 at three locations in Illinois to determine soybean response to combinations of thifensulfuron and bentazon. Thifensulfuron was applied at 2.2 to 8.8 g ai/ha alone or in combination with 280 to 560 g/ha of bentazon. Soybean injury 30 d after treatment ranged from 0 to 22% when thifensulfuron was applied alone at 2.2 g/ha. Increasing thifensulfuron rate to 8.8 g/ha increased soybean injury to a range of 12 to 44%. Soybean grain yield was significantly reduced compared to the yield of untreated soybean when thifensulfuron was applied at 4.4 and 8.8 g/ha in two of five and four of five experiments, respectively. The addition of bentazon to thifensulfuron consistently reduced soybean injury and stunting. In many cases, increasing the bentazon rate to 420 g/ha decreased soybean injury from thifensulfuron to a greater extent than 280 g/ha. In cases where thifensulfuron decreased soybean yield, the addition of 420 or 560 g/ha of bentazon restored yields to levels that were not lower than untreated soybeans. These studies demonstrate that thifensulfuron at 2.2 to 8.8 g/ha in combination with bentazon at 420 g/ha may be safely applied to soybean for broadleaf weed control.

The effect of nonionic surfactant, crop oil concentrate, organosilicone surfactant, methylated seed oil, and a blend of organosilicone surfactant and methylated seed oil on absorption of 14C-clethodim was evaluated in barnyardgrass (Echinochloa crus-galli). Absorption of 14C-label was greatest during the first 40 min after application when 14C-clethodim was applied with methylated seed oil or a blend of methylated seed oil and organosilicone surfactant. These adjuvants increased the rate of absorption more than crop oil concentrate, organosilicone surfactant, or nonionic surfactant. Crop oil concentrate was more effective than organosilicone or nonionic surfactant in increasing absorption, with nonionic surfactant being more effective than organosilicone surfactant. These results generally agreed with the order of increasing efficacy of clethodim on barnyardgrass as affected by adjuvants in field experiments. Another study was conducted to determine the effect of bromoxynil on absorption and translocation of 14C-clethodim in yellow foxtail (Setaria glauca). Bromoxynil reduced absorption of 14C–clethodim 4, 8, and 24 h after application and also reduced the amount of 14C-label translocated from the treated leaf. These data suggest that antagonism of clethodim control of yellow foxtail by bromoxynil observed in previous research can be attributed partially to decreased absorption and translocation of clethodim.

Field experiments were conducted at Kalispell, MT, to determine the optimum adjuvant combination for wild oat control in peppermint with quizalofop. Quizalofop was applied to four- and eight-leaf wild oat plants at 20 and 50 g ai/ha with either a nonionic surfactant (NIS) or methylated seed oil (MSO) alone or in combination with 28% urea ammonium nitrate (UAN) liquid fertilizer. Differences among adjuvants were most apparent when quizalofop was applied at the lowest rate. MSO was more effective than NIS for enhancing quizalofop activity. Quizalofop efficacy with both adjuvants increased when applied with UAN. Greater than 90% wild oat control was obtained with the lowest rate when applied with MSO plus UAN to four-leaf wild oat plants. These results demonstrate the potential to improve the consistency of weed control as well as reduce postemergence herbicide rates when applied with the proper adjuvant combination.

Field studies were conducted from 1994 to 1996 in Michigan to evaluate postemergence (POST) herbicides for hemp dogbane control in corn. Studies were initiated at no-tillage and chisel-plowed sites each of the three years. Nicosulfuron and primisulfuron were evaluated alone and in combination with 2,4-D amine or dicamba. In 1995 and 1996, CGA-152005 plus primisulfuron was also applied alone and in combination with 2,4-D or dicamba. Control varied among years and sites. Nicosulfuron, primisulfuron, and CGA-152005 plus primisulfuron applied alone controlled 30% of the hemp dogbane, and dicamba or 2,4-D alone controlled 42 and 66%, respectively. Tank mixtures of nicosulfuron, primisulfuron, or CGA-152005 plus primisulfuron with dicamba were more effective and more consistent than dicamba alone. Combinations of nicosulfuron, primisulfuron, or CGA-152005 plus primisulfuron with 2,4-D gave the most effective and consistent control across sites, with an average of 93% control. In general, treatments controlled only shoots that had emerged at the time of application. New shoots emerged following herbicide application at the chisel-tillage sites in 1994 and 1995 but not at the no-tillage sites. However, in 1996, shoot emergence following treatment occurred in both no-tillage and chisel-tillage sites.

Currently, there are no effective herbicides registered for the control of hoary cress (Cardaria draba) in alfalfa (Medicago sativa) or alfalfa/grass mixtures. Due to this lack of control options, field experiments were conducted near St. Ignatius, MT, from 1995 through 1997 to determine the optimum imazethapyr rate and adjuvant combination for hoary cress control in alfalfa/orchardgrass (Dactylis glomerata) pastures. Imazethapyr was applied in the spring to rosette stage hoary cress plants at 33, 67, and 100 g ai/ha with either a nonionic surfactant or methylated seed oil alone or combined with 28% urea ammonium nitrate (UAN) liquid fertilizer. Hoary cress control was poorest when imazethapyr was applied at 33 g/ha, yet provided a minimum of 80% control. Imazethapyr applied at 67 and 100 g/ha provided greater than 90% control during the year of application regardless of surfactant or UAN additions. None of the treatments controlled hoary cress the year following application. Alfalfa yield was unaffected by imazethapyr applications. First-cutting orchardgrass yield decreased as imazethapyr rate increased, but total seasonal forage yield was unaffected.

Greenhouse and field studies were conducted to determine the interaction of clethodim sprayed in low volume with pyrithiobac or bromoxynil and to determine the influence of these mixtures on large crabgrass control. A low-volume, air-assisted spraying system was calibrated to deliver 26 L/ha and was compared to a conventional hydraulic fan spraying system calibrated to deliver 140 L/ha. Greenhouse data indicated that carrier volume had no effect on large crabgrass control with clethodim. The addition of pyrithiobac to clethodim in mixture was antagonistic compared to control with clethodim applied alone. The addition of bromoxynil to clethodim in mixture was synergistic. Field studies showed similar results.

The effect of adding a spray adjuvant to SAN 582H tank mixtures with fluazifop-P, imazethapyr, and sethoxydim was evaluated. SAN 582H synergistically increased broadleaf signalgrass control with reduced rates of all three postemergence (POST) herbicides when no spray adjuvant was used and when crop oil concentrate was added. For example, broadleaf signalgrass control increased from 50% to 83% when SAN 582H was tank-mixed with 52 g ai/ha sethoxydim and crop oil concentrate. In another experiment, several formulations of SAN 582H, including blank solvent-only formulations (no SAN 582H), were evaluated in combination with a reduced rate of sethoxydim to determine the source of synergism from tank mixtures. The SAN 582H molecule, not the carrier solvents in formulated product, was determined to be the source of synergism. The synergistic properties of SAN 582H were compared to other chloroacetamides. Synergism from acetochlor was similar to SAN 582H when applied POST with a reduced rate of either fluazifop-P, imazethapyr, or sethoxydim for grass control. Metolachlor also synergistically increased the control of grasses with the POST herbicides; however, metolachlor caused considerable phytotoxicity when applied alone and synergistic interactions were detected less frequently. The efficacy of sethoxydim mixed with SAN 582H was evaluated under different soil moisture conditions. Broadleaf signalgrass control increased from 81% to 93% under dry, moisture-stressed conditions when 210 g/ha sethoxydim was tank- mixed with SAN 582H.

Control of two perennial weeds, quackgrass and Canada thistle, and the differential sensitivities of three imidazolinone-resistant (IMI) corn hybrids and their sensitive isolines to various acetolactate synthase (ALS)-inhibiting herbicides were evaluated in greenhouse studies. The postemergence sulfonylurea herbicides nicosulfuron and primisulfuron controlled quackgrass > 80%. The imidazolinone herbicides imazapyr and imazamox applied postemergence controlled quackgrass 70 and 74%, respectively. Canada thistle control was 89% with the sulfonylurea herbicide metsulfuron. Primisulfuron, chlorsulfuron, and tribenuron controlled Canada thistle > 70%. The imidazolinonesensitive corn hybrids did not tolerate the imidazolinone herbicides imazethapyr, imazaquin, imazapyr, AC 263,222, and imazamox; the sulfonylurea herbicides chlorimuron, chlorsulfuron, metsulfuron, tribenuron, and triflusulfuron; and the pyrimidinylthiobenzoate herbicide pyrithiobac applied postemergence. The ‘Ciba 4393 IMR’ corn hybrid, homozygous for an unknown allele, was resistant to all of the various ALS-inhibiting herbicides that injured its sensitive isoline. The magnitude of resistance for this hybrid was greater than the other IR corn hybrids. The ‘Pioneer 3751 IR’ corn hybrid, homozygous for the XA-17 ALS allele, was also resistant to a number of ALS-inhibiting herbicides. The ‘ICI 8692 IT’ corn hybrid, heterozygous for the Mut2 allele, was only resistant to the imidazolinone herbicides.

Laboratory studies were conducted using a Malvern laser droplet/particle size analyzer to determine the droplet spectra of several venturi-type drift reduction nozzles compared to a standard single, elliptical-orifice flat fan nozzle. Spray solutions of glufosinate, glyphosate, and paraquat were applied through all combinations of five nozzle types (four drift reduction), three tip sizes, and four application pressures. Nozzles were also evaluated for pattern uniformity using water plus surfactant at one pressure. When averaged over herbicide, tip size, and pressure the venturi nozzles collectively produced larger volume median diameter (VMD) droplets than the standard nozzle. The percentage of spray volume in droplets < 205 μm was less for the venturi nozzles (17%) than for the standard nozzle (65%) when averaged across all factors. The order of herbicides producing the largest droplets was paraquat (470 μm) > glyphosate (460 μm) > glufosinate (400 μm), as measured by VMD. The venturi nozzles were more variable in their spray volume distribution than the standard nozzle. Utilization of venturi-type nozzles may minimize the drift potential of the herbicides evaluated but could also lead to uneven herbicide application and subsequent erratic weed control.

Studies were conducted at Rosemount and Crookston, MN, in 1994 and 1995 to determine weed control efficacy and crop injury of F8426 (proposed common name carfentrazone-ethyl) in hard red spring wheat. F8426 alone and with 2,4-D or dicamba generally controlled common lambsquarters, kochia, and velvetleaf 90% or more at 0.026 and 0.035 kg/ha. F8426 alone and with 2,4-D or dicamba controlled Pennsylvania smartweed, wild buckwheat, and wild mustard 39 to 100% and was less consistent than control of the aforementioned species. Weed control varied little among the F8426 rates. Weed control was inconsistent between location, year, and species when F8426 was combined with crop oil concentrate, urea–ammonium nitrate solution, and nonionic surfactant. Control was more consistent when 0.28 kg/ha 2,4-D or 0.07 kg/ha dicamba was tank mixed with either F8426 rate. The best control with an F8426 treatment was similar to control from MCPA tank mixed with thifensulfuron plus tribenuron, bromoxynil, or dicamba. Weed control 30 and 45 days after treatment (DAT) was less for F8426-containing treatments than standard treatments, which likely was related to reduced crop competition after severe crop injury. Increasing F8426 rate from 0.026 to 0.035 kg/ha did not greatly increase wheat injury, whereas adding 0.28 kg/ha 2,4-D to either F8426 rate greatly increased crop injury. Wheat yield was reduced up to 63% by F8426 and 2,4-D combinations.

In an attempt to refine calibration procedures for greenhouse spray chambers, the effects of an herbicide adjuvant, operating pressure, and travel speed on the static and dynamic spray patterns of single flat-fan hydraulic nozzle tips were studied. The volume output in the central 15 cm of the spray pattern (where target plants would ordinarily be positioned) was used as an indicator of the relative dosages received from both a tapered flat-fan tip (8001 VS) and an even-spray tip (8001 EVS). All tested variables significantly altered the spray pattern. Specifically, dynamic spray patterns differed from static patterns, and speed of travel affected the dynamic pattern for both tapered and even flat-fan sprays. Increasing the travel speed from 0.375 to 0.75 m/s reduced spray deposit in the central 15 cm of the spray pattern by up to 19% for water, and by up to 34% for water containing 0.1% v/v nonionic surfactant. Increasing surfactant concentration to 1% decreased the magnitude of the speed effect. Higher pressure sprays tended to reduce the effect of increased travel speeds. These results show that changes in physicochemical properties of the spray solution as well as air turbulence introduced by nozzle movement can affect the pesticide dosage to which a target plant is exposed in a spray chamber. For proper treatment comparison, delivery systems for greenhouse spray experiments should be calibrated with end-use spray liquids, operating pressures, and nozzle travel speeds.

Experiments were conducted in the greenhouse to determine the effects of adjuvant and herbicide concentrations on imazamox, imazethapyr, nicosulfuron, and ICIA 0604 phytotoxicity, independent of spray retention. Equal amounts of herbicide were applied to oat in a single 0.5-μl drop or four 0.5-μl drops. Changes in adjuvant concentration influenced herbicide phytotoxicity more with application in one concentrated drop rather than in four dilute drops. Overall, herbicide phytotoxicity was greater when low adjuvant concentrations were applied in four dilute drops compared with a single concentrated drop. But when the same total amount of adjuvant was applied in one or four drops, herbicide phytotoxicity in a single drop was generally equal to or greater than in four drops. These results suggest that high herbicide phytotoxicity with high herbicide and adjuvant concentrations in low spray volumes in the field was primarily because of increased herbicide absorption rather than spray retention.

Field experiments were conducted in 1999 and 2000 to evaluate reduced-rate split-applied treatments of imazamethabenz and ICIA 0604 for wild oat control in hard red spring wheat. Single herbicide treatments were applied at standard timing to wild oat at the two- to four-leaf stage. The first split-applied treatments were made when most of the wild oat had emerged but prior to the two-leaf stage. The second split-applied treatments were made after the surviving wild oat had visibly recovered and prior to the two-leaf stage of late-emerging wild oat. Split applications of imazamethabenz or ICIA 0604 allowed the herbicide rate to be reduced by half while maintaining or improving wild oat control. Both imazamethabenz and ICIA 0604 were most effective with methylated vegetable oil adjuvants. Wheat yield and net returns were greatest for half-rate split applications of imazamethabenz and ICIA 0604 in both years, likely because of less early-season wild oat competition and reduced wheat injury caused by ICIA 0604.

Increasing the pH of the spray water to solubilize the weak acid herbicide nicosulfuron and then decreasing pH below its pKa so that it converts into a neutral form enhances biological activity under some conditions. The water-dispersible granule formulation of nicosulfuron starts as dispersed particles. Adding 1% wt/wt K3PO4 solubilizes nicosulfuron and increases its activity compared to its dispersion without base. The type of buffer and the surfactant HLB or hydrophilic lipophilic balance, a measure of the molecular balance of the hydrophilic and lipophilic groups, altered the activity of nicosulfuron. Adding 1% wt/wt K3PO4 increases the pH, and the optimum HLB ranged from 13 to 17 on large crabgrass. Adding 1% wt/wt H3PO4 reduces the pH and lowers the optimum HLB range from 10 to 14 on large crabgrass. Adding the acidic buffer converts the solubilized nicosulfuron into its neutral form and increases activity under some surfactant conditions. Thus, neutral nicosulfuron is more active with lipophilic surfactants, while ionic nicosulfuron is more active with hydrophilic surfactants. When tested on other species, low HLB surfactants are the most active at low pH. These results support the concept that the physicochemical properties of the herbicide, adjuvants, and weed species should be matched for optimum activity.