Research on the associations between refugee children’s socioemotional development and bilingual outcomes is limited, although this population has unique migration experiences that could affect such development. This study examined Syrian refugee children’s socioemotional development, including well-being difficulties and acculturation, 4.5 years after their resettlement in Canada (N = 112; mean age = 11.97). It also investigated how socioemotional development was associated with refugee children’s bilingual outcomes in English and Arabic. The findings suggested that, although the children were developing an integration orientation of acculturation, a large proportion of them reported well-being difficulties. Socioemotional development had both direct and mediated associations with bilingual outcomes: children’s identification with Syrian culture influenced English outcomes positively, and their enjoyment of Arabic language activities influenced Arabic outcomes positively. Children’s enjoyment of Arabic language activities was related to less sibling interaction in English, which, in turn, was negatively associated with English outcomes. Somewhat similarly, identification with Canadian culture was related to less parent interaction in Arabic, which was negatively associated with Arabic outcomes. Well-being difficulties were negatively associated with outcomes in both languages. We conclude that refugee children are faced with unique challenges in their socioemotional development, which in turn influences their bilingual outcomes.