Hostname: page-component-6766d58669-7cz98 Total loading time: 0 Render date: 2026-05-15T01:35:22.078Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and photocatalytic activity of nano V-doped TiO2 particles in MCM-41 under UV–visible irradiation

Published online by Cambridge University Press:  31 January 2011

Kaustava Bhattacharyya ,
Salil Varma ,
Arvind K. Tripathi  and
Avesh K. Tyagi
Avesh K. Tyagi*
Affiliation:
Chemistry Division, Bhabha Atomic Research Center, Mumbai 400085, India
*
a)Address all correspondence to this author. e-mail: aktyagi@barc.gov.in
Get access

Abstract

The vanadium (V)-doped titania (Ti0.95V0.05O2) was impregnated in the host matrix of the pre-synthesized siliceous mesoporous material MCM-41 in a single pot synthesis step, by the wet impregnation route. The samples were characterized by x-ray diffraction, transmission electron microscopy (TEM), N2 adsorption, diffuse reflectance ultraviolet–visible spectroscopy (DRUVS). As compared to Ti0.95V0.05O2, the DRUV spectra of the impregnated catalysts showed a blue shift; still the absorption lies in the visible region. Presence of nano-sized (∼2–12 nm) V-doped titania particles in V-TiO2/MCM-41 was revealed by TEM and the particle size was found to increase with the loading of the V-doped titania in the host matrix. All impregnated samples were found to be more active than either the bulk V-doped titania or titania for photocatalytic oxidation of ethylene in air at ambient conditions under both UV and visible irradiation.

Keywords

CatalyticTransmission electron microscopy (TEM)Zeolite

Information

Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 1: Photocatalysis for Energy and Environmental Sustainability , January 2010 , pp. 125 - 133
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1.Beck, J.S., Vartuli, J.V., Roth, W.J.A new family of mesoporous molecular prepared with liquid crystal templates. J. Am. Chem. Soc. 114, 10834 (1992)CrossRefGoogle Scholar
2.Hornebecq, V., Antonietti, M., Cardinal, T., Delapièrre, M.T.Stable silver nanoparticles immobilize in mesoporous silica. Chem. Mater. 15, 1993 (2003)CrossRefGoogle Scholar
3.Bandyopadhyay, M., Birkner, A., van den Berg, M.W.E., Klementiev, K.V., Schmidt, W., Grunert, W., Gies, H.Synthesis and characterization of mesoporous MCM-48 containing TiO2 nanoparticles. Chem. Mater. 17, 3820 (2005)CrossRefGoogle Scholar
4.Occelli, M.L., Biz, S., Auroux, A.Effects of isomorphous substitution of Si with Ti and Zr in mesoporous silicates with the MCM-41 structure. Appl. Catal., A 183, 231 (1999)CrossRefGoogle Scholar
5.Cagnoli, M.V., Casuscelli, S.G., Alvarez, A.M., Bengoa, J.F., Gallegos, N.G., Crivello, M.E., Herrero, E.R., Marchetti, S.G.Ti–MCM-41 silylation: Development of a simple methodology for its estimation silylation effect on the activity and selectivity in the limonene oxidation with H2O2. Catal. Today 397, 107 (2005)Google Scholar
6.Lensveld, D.J., Mesu, J.G., Dillen, A.J., Jong, K.P.Synthesis and characterization of MCM-41 supported nickel oxide catalysts. Microporous Mesoporous Mater. 44–45, 401 (2001)CrossRefGoogle Scholar
7.Jiang, T., Tang, Y., Zhao, Q., Yin, H.Effect of Ni-doping on the pore structure of pure silica MCM-41 mesoporous molecular sieve under microwave irradiation. Colloids Surf., A 315, 299 (2008)CrossRefGoogle Scholar
8.Parvulescu, V., Su, B.L.Iron, cobalt or nickel substituted MCM-41 molecular sieves for oxidation of hydrocarbons. Catal. Today 69, 315 (2001)CrossRefGoogle Scholar
9.Bore, M.T., Pham, H.N., Switzer, E.E., Warb, T.L., Fukuoka, A., Datye, A.K.The role of pore size and structure on the thermal stability of gold nanoparticles within mesoporous silica. J. Phys. Chem. B 109, 2873 (2005)CrossRefGoogle ScholarPubMed
10.Yang, H., Du, C., Jin, S., Tang, A., Li, G.Enhanced photoluminescence property of SnO2 nanoparticles contained in mesoporous silica synthesized with leached talc as Si source. Microporous Mesoporous Mater. 102, 204 (2007)CrossRefGoogle Scholar
11.Mukai, S.R., Nishihara, H., Shichi, S., Tamon, H.Preparation of porous TiO2 cryogel fibers through unidirectional freezing of hydrogel followed by freeze-drying. Chem. Mater. 16, 4987 (2004)CrossRefGoogle Scholar
12.Yoshitake, H., Sugihara, T., Tatsumi, T.Preparation of wormlike mesoporous TiO2 with an extremely large surface area and stabilization of its surface by chemical vapor deposition. Chem. Mater. 14, 1023 (2002)CrossRefGoogle Scholar
13.Nakashima, T., Kimizuka, N.Interfacial synthesis of hollow TiO2 microspheres in ionic liquids. J. Am. Chem. Soc. 125, 6386 (2003)CrossRefGoogle ScholarPubMed
14.Caruso, R.A., Giersig, M., Willig, F., Antonietti, M.Porous “coral-like” TiO2 structures produced by templating polymer gels. Langmuir 14, 6333 (1998)CrossRefGoogle Scholar
15.Reddy, E.P., Sun, B., Smirniotis, P.G.Transition metal modified TiO2-loaded MCM- 41 catalysts for visible- and UV-light driven photodegradation of aqueous organic pollutants. J. Phys. Chem. B 108, 17198 (2004)CrossRefGoogle Scholar
16.Liang, C.H., Li, F.B., Liu, C.S., Lu, J.L., Wang, X.G.The enhancement of adsorption and photocatalytic activity of rare earth ions doped TiO2 for the degradation of orange. Dyes Pigm. 76, 477 (2008)CrossRefGoogle Scholar
17.Davydov, L., Reddy, E.P., France, P., Smirniotis, P.G.Transition-metal-substituted titania-loaded MCM-41 as photocatalysts for the degradation of aqueous organics in visible light. J. Catal. 203, 157 (2001)CrossRefGoogle Scholar
18.Matsuoka, M., Anpo, M.Local structures, excited states, and photocatalytic reactivities of highly dispersed catalysts constructed within zeolites. J. Photochem. Photobiol., A 3, 225 (2003)CrossRefGoogle Scholar
19.Sun, B., Reddy, E.P., Smirniotis, P.G.TiO2-loaded Cr-modified molecular sieves for 4-chlorophenol photodegradation under visible light. J. Catal. 237, 314 (2006)CrossRefGoogle Scholar
20.Marques, F.C., Canela, M.C., Stumbo, A.M.Use of TiO2/Cr–MCM-41 molecular sieve irradiated with visible light for the degradation of thiophene in the gas phase. Catal. Today 133–135, 594 (2008)CrossRefGoogle Scholar
21.Sun, B., Reddy, E.P., Smirniotis, P.G.Effect of the Cr6+ concentration in Cr-incorporated TiO2-loaded MCM-41 catalysts for visible light photocatalysis. Appl. Catal., B 57, 139 (2005)CrossRefGoogle Scholar
22.Huang, J., Wang, X., Hou, Y., Chen, X., Wu, L., Wang, X., Fu, X.Synthesis of functionalized mesoporous TiO2 molecular sieves and their application in photocatalysis. Microporous Mesoporous Mater. 110, 543 (2008)CrossRefGoogle Scholar
23.Portela, R., Canela, M.C., Sánchez, B., Marques, F.C., Stumbo, A.M., Tessinari, R.F., Coronado, J.M., Suárez, S.H2S photodegradation by TiO2/M–MCM-41 (M = Cr or Ce): Deactivation and by-product generation under UV-A and visible light. Appl. Catal., B 84, 643 (2008)CrossRefGoogle Scholar
24.Bhattacharya, K., Tripathi, A.K., Dey, G.K., Gupta, N.M.Vapor-phase photo-oxidation of methanol over nano-size titanium dioxide clusters dispersed in MCM-41 host material. Part 1: Synthesis and characterization. J. Nanosci. Nanotechnol. 5, 790 (2005)CrossRefGoogle Scholar
25.Bhattacharyya, K., Varma, S., Kumar, D., Tripathi, A.K., Gupta, N.M.Vapor-phase photo-oxidation of methanol over nano-size titanium dioxide clusters dispersed in MCM-41 host material. Part 2: Catalytic properties and surface transient species. J. Nanosci. Nanotechnol. 5, 797 (2005)CrossRefGoogle ScholarPubMed
26.Bhattacharyya, K., Varma, S., Tripathi, A.K., Bharadwaj, S.R., Tyagi, A.K.Effect of vanadia doping and its oxidation state on the photocatalytic activity of TiO2 for gas-phase oxidation of ethene. J. Phys. Chem. C 112, 19102 (2008)CrossRefGoogle Scholar
27.Chimentão, R.J., Herrera, J.E., Kwak, J.H., Medina, F., Wang, Y., Peden, C.H.F.Oxidation of ethanol to acetaldehyde over Na-promoted vanadium oxide catalysts. Appl. Catal., A 332, 263 (2007)CrossRefGoogle Scholar
28.Hsien, Y.H., Chang, C.F., Chen, Y.H., Cheng, S.Photodegradation of aromatic pollutants in water over TiO2 supported on molecular sieves. Appl. Catal., B 31, 241 (2001)CrossRefGoogle Scholar
29.Tuel, A., Hubert-Pfalzgraf, L.G.Nanometric monodispersed titanium oxide particles on mesoporous silica: Synthesis, characterization, and catalytic activity in oxidation reactions in the liquid phase. J. Catal. 217, 343 (2003)CrossRefGoogle Scholar
30.Gao, X., Wachs, I.E.Titania–silica as catalysts: Molecular structural characteristics and physico-chemical properties. Catal. Today 51, 233 (1999)CrossRefGoogle Scholar
31.Bhattacharyya, K., Varma, S., Tripathi, A.K., Bharadwaj, S.R., Tyagi, A.K.Mechanistic insight by in situ FTIR for the gas phase photo-oxidation of thylene by V-doped titania and nano-titania. J. Phys. Chem. B 113, 5917 (2009)CrossRefGoogle Scholar