Solid-state systems, by their very nature, have a vast number of different possible quantum degrees of freedom. In Chapter 11, we saw that some of these degrees of freedom make good qubits. However, there are plenty more which are less suitable, since they cannot easily be localized and externally controlled. Once the qubit has been chosen, it is important to think about how it interacts with the other, uncontrolled quantum excitations in its environment. Such an interaction leads to unpredictable behaviour and can cause decoherence – the irretrievable loss of quantum information from the qubit – and this will be the topic of this chapter. The most obvious decoherence mechanism for any optical manipulation scheme is the spontaneous emission of photons. The theory behind this follows analogously from the theory we discussed in Chapter 7, with a suitable definition of a transition dipole for the relevant transitions. However, solid-state systems bring with them lattice vibrations, or phonons, which have no direct atomic analogue. We will therefore focus on phonons in this chapter, first discussing how we model them, and second how they interact with the electron-based qubit that we discussed in the last chapter. Later, we will see how this leads to a loss of coherence, and how optical methods can be used to slow the rate of coherence loss. Phonon interactions are complex and not easy to model exactly, but we will show that with certain approximations very successful theories can be developed.

We have so far spoken almost exclusively of photons and linear-optical elements, and seen just how powerful those two components can be for information processing. They provide unbreakable cryptographic tools, and allow for efficient quantum computing. However, many more possibilities become available when we allow photons to interact with atoms and solid matter in a quantum mechanical way. In particular, a quantum memory, the principal difficulty for linear-optical quantum computing, can be created. In this chapter we will take the first steps towards a full understanding of a photon's interaction with atoms. We will show how to describe the interactions within a system consisting of photons and few-level atoms and show how this interaction can be manipulated and exploited to provide quantum information processors based on both atomic and photonic qubits. We will also show that photon emission from atoms can degrade the quantum information contained within atoms, and we will present a formalism to model this effect. We begin with a general discussion of atom-photon interactions.

Atomic systems as qubits

Let us first consider an electron in an isolated atom. It is bound there by the Coulomb force due to the charge distribution of all the other electrons and the nucleus. The potential that describes this coupling is given by V(r).

In optical quantum information processing, two of the most basic elements are the sources of quantum mechanical states of light, and the devices that can detect these states. In this chapter, we narrow this down to photon sources and photodetectors. We will describe first how detectors work, starting from abstract ideal detectors, via a complete description of realistic detectors in terms of POVMS, to a brief overview of current photodetectors. Subsequently, we will define what is a single-photon source, and how we can determine experimentally whether a source produces single photons or something else. Having laid down the ground rules, we will survey some of the most popular ways photons are produced in the laboratory. Finally, we take a look at the production of entangled photon sources and quantum non-demolition measurements of photons.

A mathematical model of photodetectors

Photodetectors are devices that produce a macroscopic signal when triggered by one or more photons. In the ideal situation, every photon that hits the detector contributes to the macroscopic signal, and there are no ‘ghost’ signals, or so-called dark counts. In this situation we can define two types of detector, namely the ‘photon-number detector’, and ‘detectors without number resolution’.

First, the photon number detector is a (largely hypothetical) device that tells us how many photons there are in a given optical mode that is properly localized in space and time. This property is called ‘photon-number resolution’.