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Molecular oxygen, O2, was recently detected in comet 67P by the ROSINA instrument on board the Rosetta spacecraft with a surprisingly high abundance of 4% relative to H2O, making O2 the fourth most abundant in comet 67P. Other volatile species with similar volatility, such as molecular nitrogen N2, were also detected by Rosetta, but with much lower abundances and much weaker correlations with water. Here, we investigate the chemical and physical origin of O2 and other volatile species using the new constraints provided by Rosetta. We follow the chemical evolution during star formation with state-of-the-art astrochemical models applied to dynamical physical models by considering three origins: i) in dark clouds, ii) during forming protostellar disks, and iii) during luminosity outbursts in disks. The models presented here favour a dark cloud (or “primordial”) grain surface chemistry origin for volatile species in comets, albeit for dark clouds which are slightly warmer and denser than those usually considered as solar system progenitors.
In this work, one intends to computationally simulate and investigate, via thermochemical calculations, how the chemical environment influences some molecular properties, such as IR spectra and absorption cross section, of individual species embedded in the solid phase employing the Polarized Continuum Model (PCM) approach. The trial molecules used here to check these effects are CO, CO2 and H2O. The solid phase (bulk ice) is simulated using different dielectric constant values representing different types of astrophysical ice at PCM approach. The effect of temperature is also investigated since it is known it affects the dielectric constant of the solvent medium.
C2H4O2 isomers, methyl formate (HCOOCH3), acetic acid (CH3COOH) and glycoaldehyde (HOCH2CHO), have been detected in a lot of sources in ISM. However, their abundances are very different, with methyl formate much more abundant than the other two isomers. This fact may be related to the different destruction by ionizing radiation of these molecules. The goal of this work is experimentally study the photodissociation processes of methyl formate and acetic acid ices when exposed to broadband soft X-ray from 6 up to 2000 eV. The experiments were performed coupled to the SGM beamline in the Brazilian Synchrotron Light Source (LNLS/CNPEM) at Campinas, Brazil. The simulated astrophysical ices (12K) were monitored throughout the experiment using infrared vibrational spectroscopy. The analysis of processed ices allowed the determination of the effective destruction cross sections of the parent molecules as well as the effective formation cross section of daughter molecular species. The relative abundance between acetic acid and methyl formate (NCH3COOH/NHCOOCH3) in different astronomical scenarios and their column density evolution in the presence of X-rays were calculated and our results suggests that such radiation field can be one of the factors that explain the difference in the isomers C2H4O2 abundances. We also quantified the daugther species after the establishment of a chemical equilibrium in the samples.
Methyl isocyanate (CH3NCO) belongs to a select group of peptide-like prebiotic molecules. In this paper we present its first detection toward the solar type low-mass protostar IRAS16293-2422 (hereafter IRAS16293). CH3NCO is detected towards IRAS16293 as a warm component with Tex > 100 K and HNCO/CH3NCO ∼4-12. Also, its grain surface formation route is investigated in the laboratory. VUV processing of CH4:HNCO mixtures, investigated by IR spectroscopy and mass spectrometry, revealed that it can be formed by reactions of CH3 and with (H)NCO. Observations and experiments strongly hint that methyl isocyanate is formed on interstellar dust grains.
An analysis of electrostatic waves in a hot unmagnetized plasma is presented. Two approaches are discussed. The first, based on the Vlasov equation and using the same Fourier normal-mode analysis presented in Chapter 4, fails because it does not adequately account for the interaction of the wave with particles moving at the phase velocity of the wave. This approach is replaced by an analysis that treats the problem as an initial-value problem using Laplace transforms. This method succeeds and shows that electrostatic waves decay via a completely new process called “Landau damping.” The existence of this damping is surprising because the Vlasov equation has no irreversible process that would lead to damping. The resolution of this paradox is discussed and involves a resonant transfer of the wave energy to particles with velocities near the phase velocity of the wave. Applications to various types of electrostatic instabilities are given, including waves driven by electron beams and other types of unstable velocity distribution functions.
A plasma is an ionized gas consisting of positively and negatively charged particles with approximately equal charge densities. Plasmas can be produced by heating an ordinary gas to such a high temperature that the random kinetic energy of the molecules exceeds the ionization energy. Collisions then strip some of the electrons from the atoms, forming a mixture of electrons and ions. Because the ionization process starts at a fairly well-defined temperature, usually a few thousand K, a plasma is often referred to as the “fourth” state of matter. Plasmas can also be produced by exposing an ordinary gas to energetic photons, such as ultraviolet light or X-rays. The steady-state ionization density depends on a balance between ionization and recombination. In order to maintain a high degree of ionization, either the ionization source must be very strong, or the plasma must be very tenuous so that the recombination rate is low.
The definition of a plasma requires that any deviation from charge neutrality must be very small. For simplicity, unless stated otherwise, we will assume that the ions are singly charged. The charge neutrality condition is then equivalent to requiring that the electron and ion number densities be approximately the same. In the absence of a loss mechanism, the overall charge neutrality assumption is usually satisfied because all ionization processes produce equal amounts of positive and negative charge. However, deviations from local charge neutrality can occur. Usually these deviations are small, since as soon as a charge imbalance develops, large electric fields are produced that act to restore charge neutrality. Systems that display large deviations from charge neutrality, such as vacuum tubes and various electronic devices, are not plasmas, even though some aspects of their physics are similar.
In the most common type of plasma, the charged particles are in an unbound gaseous state. This requirement can be made more specific by requiring that the random kinetic energy be much greater than the average electrostatic energy, and is imposed to provide a distinction between a plasma, in which the particles move relatively freely, and condensed matter, such as metals, where electrostatic forces play a dominant role.
An extension of the Landau analysis method presented in Chapter 9 is given to waves propagating in hot magnetized plasmas. The analysis presented reveals an entirely new category of both electrostatic and electromagnetic waves that propagate near harmonics of the electron and ion cyclotron frequencies. These waves are called “Bernstein modes.” For certain types of velocity distribution functions these and other previously analyzed modes, such the whistler mode, can become unstable. Especially notable for being unstable are velocity distribution functions that are rotationally anisotropic with respect to the static magnetic field, such as the loss cone in a planetary radiation belt. Such waves often cause violations of the adiabatic invariants (as in Chapter 3), and cause pitch-angle scattering that leads to the loss of particles from planetary radiation belts. Similar processes also occur for magnetically confined laboratory plasmas.
An analysis is given of various types of nonlinear effects that can occur in plasmas. The topics covered are quasi-linear theory, wave-wave interactions, Langmuir wave solitons, and stationary nonlinear electrostatic potentials. Quasi-linear theory describes how an electrostatic wave driven by an unstable velocity distribution function causes the velocity distribution function to evolve in such a way that it eliminates the instability. The discussion of wave-wave interactions describes how a wave can nonlinearly interact with another wave to produce a third wave at either the sum or difference of the frequencies of the two interacting waves. The section on Langmuir wave solitons describes how a very intense single wave can alter the initial local plasma density in such a way as to form intense isolated wave structure known as a solitons. The section on stationary electrostatic potentials shows how highly nonlinear self-consistent electrostatic structures can form in otherwise time-stationary plasmas. Although there are many other nonlinear processes that can occur, these examples provide a good overview of the methods used to analyze these effects.
While galaxies with clockwise and counterclockwise handedness are visually different, they are expected to be symmetric in all of their other characteristics. Previous experiments using both manual analysis and machine vision have shown that the handedness of Sloan Digital Sky Survey galaxies can be predicted with accuracy significantly higher than mere chance using its photometric data alone. However, some of these previous experiments were based on manually classified galaxies, and the results may therefore be subjected to bias originated from the human perception. This paper describes an experiment based on a set of 162,514 galaxies classified automatically to clockwise and counterclockwise spiral galaxies, showing that the source of the asymmetry in Sloan Digital Sky Survey (SDSS) database is not the human perception bias. The results are compared to two smaller datasets, and confirm the observation that the handedness of SDSS galaxies can be predicted by their photometry. The experiment also shows statistically significant differences in the measured magnitude of SDSS galaxies, according which galaxies with clockwise patterns are brighter than galaxies with counterclockwise patterns. The magnitude of that difference changes across RA ranges, and exhibits a strong correlation with the cosine of the right ascension.
A complete mathematical model of a plasma requires three basic elements: first, the motion of all particles must be determined for some assumed electric and magnetic field configuration; second, the current and charge densities must be computed from the particle trajectories; and third, the electric and magnetic fields must be self-consistently determined from the currents and charges, taking into account both internal and external sources. To be self-consistent, the electric and magnetic fields obtained from the last step must correspond to the fields used in the first step. It is this self-consistency requirement that makes the analysis of a plasma difficult.
To develop an understanding of the processes occurring in a plasma, a useful first step is to forget about the self-consistency requirement and concentrate on the motion of a single particle in a specified field configuration. This approach can be useful in a variety of situations. If the external fields are very strong and the plasma is sufficiently tenuous, the internally generated fields are sometimes small and can be safely ignored. This situation arises, for example, in radiation belts at high energies and in various electronic devices such as vacuum tubes and traveling wave amplifiers. In other situations, the self-consistent electric and magnetic fields may be known from direct measurement. In this case, it is often useful to follow the motion of individual tracer particles in the known electric and magnetic fields in order to gain insight into the physical processes involved, such as particle transport and energization. Finally, in some cases it is possible to use the general solution for the particle motion in an assumed field geometry to determine a fully self-consistent solution in which the currents and charges produce the assumed fields.
Motion in a Static Uniform Magnetic Field
The simplest field configuration of importance in plasma physics is a static uniform magnetic field. The equation of motion for a particle moving at non-relativistic velocities in a static uniform magnetic field is given by
This textbook is intended for a full year introductory course in plasma physics at the senior undergraduate or first-year graduate level. It is based on lecture notes from courses taught by the authors for more than three decades at the University of Iowa, Columbia University, University of New Hampshire, and Princeton University. During these years, plasma physics has grown increasingly interdisciplinary, and there is a growing realization that diverse applications in laboratory, space, and astrophysical plasmas can be viewed from a common perspective. Since the students who take a course in plasma physics often have a wide range of interests, typically involving some combination of laboratory, space, and astrophysical plasmas, a special effort has been made to discuss applications from these areas of research. The emphasis of the book is on physical principles, less so on mathematical sophistication. An effort has been made to show all relevant steps in the derivations, and to match the level of presentation to the knowledge of students at the advanced undergraduate and early graduate level. The main requirements for students taking this course are that they have taken an advanced undergraduate course in electricity and magnetism and that they are knowledgeable about using the basic principles of vector calculus, i.e., gradient, divergence, and curl, and the various identities involving these vector operators. Although extensive use is made of complex variables, no special background is required in this subject beyond what is covered in an advanced calculus course. Relatively advanced mathematical concepts that are not typically covered in an undergraduate sequence, such as Fourier transforms, Laplace transforms, the Cauchy integral theorem, and the residue theorem, are discussed in sufficient detail that no additional preparation is required. Although this approach has undoubtedly added to the length of the book, we believe that the material covered provides an effective and self-contained textbook for teaching plasma physics. MKS units are used throughout.
The basic parameters of a plasma are introduced. Typically a plasma consists of electrons and one or more species of positively charged ions. The first and most important characteristics a plasma are of the number density and temperature of each species present in the plasma. From these basic characteristics a number of fundamental parameters of a plasma are derived. These consist of the Debye length, the electron and ion plasma frequencies, the electron and ion cyclotron frequencies, and the number of electrons per Debye cube. The number of particles per Debye cube, ND, provides the basic distinction between plasmas and metals, for example. Plasmas always have ND >> 1, whereas metals always have ND << 1. Quantum effects are also briefly discussed, which mainly occur at very low temperatures and high densities.
To analyze plasmas that have a finite temperature it is necessary to use a statistical approach called “kinetic theory” which describes the distribution of particle velocities in a plasma. In this chapter a famous equation, called the “Vlasov equation,” is derived. This equation describes the evolution of the number of particles in a six-dimensional (velocity-position) coordinate system called “phase space.” The Vlasov equation assumes that there are no collisions. The only forces considered are due to long-range electromagnetic and electrostatic forces. By taking velocity moments of the Vlasov equation, a series of equations called the moment equations are developed that allows one to take into account the evolution of the average density, velocity, and pressure of plasma. Unfortunately, the moment equations do not consist of a closed set of equations and always require additional assumptions, specifically an equation of state. By assuming an adiabatic equation of state, two new electrostatic wave modes, the Langmuir mode and the ion acoustic mode, are revealed that do not exist in a cold plasma.
When a wave propagates through a plasma with a finite temperature the forces acting on a charged particle are Doppler-shifted from their rest-frame frequency by the thermal motion of the particle. Since these Doppler shifts greatly complicate the analysis, in this chapter the temperature is assumed to be zero, so that there are no thermal motions. Hence the term “cold plasma.” Two types of plasmas are analyzed, those with no background magnetic field, and those with a background magnetic field. To further simplify the analysis, the wave amplitudes are assumed to be small, so that the equations of motion can be linearized. The result is a very general solution can for all of the electromagnetic wave modes that can propagate in a cold plasma, plus one purely electrostatic mode, called the electron plasma oscillation. This analysis reveals almost all of the electromagnetic waves that can propagate in a plasma.