Superluminous supernovae are beginning to be discovered at redshifts as early as the epoch of reionisation. A number of candidate mechanisms is reviewed, together with the discovery programmes.

The overall goal of the ESA Rosetta mission was to help decipher the origin and evolution of our solar system. Looking at the chemical composition of comet 67P/Churyumov-Gerasimenko is one way of doing this. The amount of very volatile species found and the insight into their isotopic abundances show that at least some presolar ice has survived the formation of the solar system. It shows that the solar nebula was not homogenized in the region where comets formed. The D/H ratio in water furthermore indicates that Jupiter family comets and Oort cloud comets probably formed in the same regions and their difference is then purely due to their different dynamical history. The organics found in 67P are very diverse, with abundant CH- and CHO- bearing species. Sulphur bearing species like S3 and S4 and others show evidence of dust grain chemistry in molecular clouds.

The chemical evolution of a star- and planet-forming system begins in the prestellar phase and proceeds across the subsequent evolutionary phases. The chemical trail from cores to protoplanetary disks to planetary embryos can be studied by comparing distant young protostars and comets in our Solar System. One particularly chemically rich system that is thought to be analogous to our own is the low-mass IRAS 16293-2422. ALMA-PILS observations have made the study of chemistry on the disk scales (<100 AU) of this system possible. Under the assumption that comets are pristine tracers of the outer parts of the innate protosolar disk, it is possible to compare the composition of our infant Solar System to that of IRAS 16293-2422. The Rosetta mission has yielded a wealth of unique in situ measurements on comet 67P/C-G, making it the best probe to date. Herein, the initial comparisons in terms of the chemical composition and isotopic ratios are summarized. Much work is still to be carried out in the future as the analysis of both of these data sets is still ongoing.

Phosphorus is a crucial element in prebiotic chemistry, especially the P−O bond, which is key for the formation of the backbone of the deoxyribonucleic acid. So far, PO had only been detected towards the envelope of evolved stars, and never towards star-forming regions. We report the first detection of PO towards two massive star-forming regions, W51 e1/e2 and W3(OH), using data from the IRAM 30m telescope. PN has also been detected towards the two regions. The abundance ratio PO/PN is 1.8 and 3 for W51 and W3(OH), respectively. Our chemical model indicates that the two molecules are chemically related and are formed via gas-phase ion-molecule and neutral-neutral reactions during the cold collapse. The molecules freeze out onto grains at the end of the collapse and desorb during the warm-up phase once the temperature reaches ~35 K. The observed molecular abundances of 10−10 are predicted by the model if a relatively high initial abundance of 5× 10−9 of initial phosphorus is assumed.

I review massive star formation in our Galaxy, focussing on initial conditions in Infrared Dark Clouds (IRDCs), including the search for massive pre-stellar cores (PSCs), and modeling of later stages of massive protostars, i.e., hot molecular cores (HMCs). I highlight how developments in astrochemistry, coupled with rapidly improving theoretical/computational and observational capabilities are helping to improve our understanding of the complex process of massive star formation.

Planets form in disks around young stars. The planet formation process may start when the protostar and disk are still deeply embedded within their infalling envelope. However, unlike more evolved protoplanetary disks, the physical and chemical structure of these young embedded disks are still poorly constrained. We have analyzed ALMA data for 13CO, C18O and N2D+ to constrain the temperature structure, one of the critical unknowns, in the disk around L1527. The spatial distribution of 13CO and C18O, together with the kinetic temperature derived from the optically thick 13CO emission and the non-detection of N2D+, suggest that this disk is warm enough (≳ 20 K) to prevent CO freeze-out.

The physical evolution of low-mass protostars is relatively well-established, however, there are many open questions on the chemical structure of protostars. The chemical fingerprint generated in the early embedded phase of star formation may be transmitted to the later stages of star, planet and comet formation. The factors that influence the chemical fingerprint are then of interest to study, and determine whether the chemical structure is inherited from the parent cloud or product of the physical processes during star formation. Results of observations and modelling of molecules that trace the cold and warm extended structures of embedded protostars are briefly presented here. Two multiple protostellar systems are studied, IRAS 16293-2422 and VLA 1623-2417, both located in ρ Ophiuchus. We find that the physical structure of the protostars, that is the disk(-like) strucutres, outflow cavity and different luminosities, are important factors in determining the chemical structure of these embedded protostars.

Complex organic molecules (COMs) have been observed in comets, hot cores and cold dense regions of the interstellar medium. It is generally accepted that these COMs form on icy dust grain through the recombination reaction of radicals triggered by either energetic UV-photon or non-energetic H-atom addition processing. In this work, we present for the first time laboratory studies that allow for quantitative comparison of hydrogenation and UV-induced reactions as well as their cumulative effect in astronomically relevant CO:CH3OH=4:1 ice analogues. The formation of glycolaldehyde (GA) and ethylene glycol (EG) is confirmed in pure hydrogenation experiments at 14 K, except methyl formate (MF), which is only clearly observed in photolysis. The fractions for MF:GA:EG are 0 : (0.2-0.4) : (0.8-0.6) for pure hydrogenation, and 0.2 : 0.3 : 0.5 for UV involving experiments and can offer a diagnostic tool to derive the chemical origin of these species. The GA/EG ratios in the laboratory (0.3-1.5) compare well with observations toward different objects.

Core-accretion theory predicts that the formation of giant planets predominantly occurs at the dense mid-plane of the inner ∼50 AU of protoplanetary disks. However, due to observational limitation, this critical region remains to be the least charted area in protoplanetary disks. With its great sensitivity, ALMA recently started to image optically thin line emissions arisen from the mid-plane of the inner 50AU in nearby disks, which unlocks an exciting new path to directly constrain the physical properties of the giant planet formation zone through gas tracers. Here we present the first spatially resolved observations of the 13C18O J=3-2 line emission in the TW Hya disk. We show that this emission is optically thin even inside the CO mid-plane snowline. Combining it with the C18O J=3-2 images and the previously detected HD J=1-0 flux, we directly constrain the mid-plane temperature and optical depths of the CO gas and dust. We report a mid-plane CO snowline at 20.5 ± 1.3 AU, a mid-plane temperature distribution of 27+4−3×(R/20.5AU)-0.47+0.06−0.07 K, and a gas mass distribution of 13+8−5×(R/20.5AU)-0.9+0.4−0.3 g cm−2 between 5-20.5 AU in the TW Hya protoplanetary disk. We find a total gas/mm-sized dust mass ratio of 140 ± 40 in this region, suggesting that ∼2.4 earth mass of dust aggregates have grown to > cm sizes (and perhaps much larger).

Determining the locations of the major snowlines in protostellar environments is crucial to fully understand the planet formation process and its outcome. Despite being located far enough from the central star to be spatially resolved with ALMA, the CO snowline remains difficult to detect directly in protoplanetary disks. Instead, its location can be derived from N2H+ emission, when chemical effects like photodissociation of CO and N2 are taken into account. The water snowline is even harder to observe than that for CO, because in disks it is located only a few AU from the protostar, and from the ground only the less abundant isotopologue H218O can be observed. Therefore, using an indirect chemical tracer, as done for CO, may be the best way to locate the water snowline. A good candidate tracer is HCO+, which is expected to be particularly abundant when its main destructor, H2O, is frozen out. Comparison of H218O and H13CO+ emission toward the envelope of the Class 0 protostar IRAS2A shows that the emission from both molecules is spatially anticorrelated, providing a proof of concept that H13CO+ can indeed be used to trace the water snowline in systems where it cannot be imaged directly.

We present the results of a survey of several tens of dense high mass star forming (HMSF) cores in three transitions of the SO molecule at 30 and 100 GHz with the 100-m Effelsberg and 20-m Onsala radio telescopes. The physical parameters of the cores are estimated from the line ratios and column densities. Relative abundances are derived as well.

The formation of molecules in the interstellar medium is significantly driven by grain chemistry, ranging from simple (e.g. H2) to relatively complex (e.g. CH3OH) products. The movement of atoms and molecules on amorphous ice surfaces is not well constrained, and this is a quintessential component of surface chemistry. We show that ice structure created by utilizing an off-lattice Monte Carlo kinetics model is highly dependent on deposition parameters (i.e. angle, rate, and temperature). The model, thus far, successfully predicts the densities of deposition rate- and temperature-dependent laboratory experiments. The simulations indicate, when angle and deposition rate increase, the density decreases. On the other hand, temperature has the opposite effect and will increase the density. We can make ices with desired densities and monitor how molecules, like CO, percolate through H2O ice pores. The strength of this model lies in the ability to replicate TPD-like experiments by monitoring molecules diffusing on and desorbing from user-defined surfaces.

In 2005 we suggested a relation between the optimal locus of gas giant planet formation, prior to migration, and the metallicity of the host star, based on the core accretion model, and radial profiles of dust surface density and gas temperature. At that time, less than 200 extrasolar planets were known, limiting the scope of our analysis. Here, we take into account the expanded statistics allowed by new discoveries, in order to check the validity of some premises. We compare predictions with the present available data and results for different stellar mass ranges. We find that the zero age planetary orbit (ZAPO) hypothesis continues to hold after a two order of magnitude increase in discovered planets, as well as the prediction that planets around metal poor stars would have shorter orbits.

The youngest low-mass protostars are known to be chemically rich, accreting matter most vigorously, and producing the most powerful outflows. Molecules are unique tracers of these phenomena. We use ALMA to study several outflow sources in the Serpens Main region. The most luminous source, Ser-SMM1, shows the richest chemical composition, but some complex molecules are also present in S68N. No emission from complex organics is detected toward Ser-emb 8N, which is the least luminous in the sample. We discuss whether these differences reflect an evolutionary effect or whether they are due to different physical structures. We also analyze the outflow structure from these young protostars by comparing emission of CO and SiO. EHV molecular jets originating from SMM1-a,b and Ser-emb 8N contrast with no such activity from S68N, which on the other hand presents a complex outflow structure.

CN emission lines are among the brightest, and have been observed in the last 20 years with single dish observations. With modern interferometers, we are now able to spatially resolve CN emission, which often shows ring-like structures. We investigate whether such structures trace the morphology of the disks, or if they have a chemical origin. By using the thermochemical code DALI, we conclude that CN formation is triggered by the existence of vibrationally excited H2*, produced by FUV pumping of H2. Herbig stars therefore generally have larger rings and higher CN fluxes than TTauri. Disks with higher masses and flaring also show stronger CN emission and larger rings. CN observations could in the future provide important constraints on some important disk physical parameters. The results of the models are well consistent with the spatially resolved CN observations to-date available.

Nitrogen, one of the most abundant elements in the Universe is a fundamental element of molecules which are crucial for life. We present here the modelling of the emission of two of the simplest nitrogen-bearing molecules, CN and NO, with a non-LTE radiative transfer code in IRAS16293-2422, a class 0 low-mass protostar. In this model, we assumed IRAS16293-2422 is formed by 2 compact, hot and dense sources embedded in a three layers of envelope.

We present preliminary results of the high resolution (0.10″ × 0.15″) observations of the high mass star forming region S255IR with ALMA in several spectral windows from ∼335 GHz to ∼350 GHz. The main target lines were C34S(7–6), CH3CN(19K − 18K), CO(3–2) and SiO(8–7), however many other lines of various molecules have been detected, too. We present sample spectra and maps, discuss briefly the source structure and kinematics. A new, never predicted methanol maser line has been discovered.

During the first few ~Myr of a young stars life, it is encircled by a disk made up of molecular gas, dust, and ice – the building blocks for future planetary systems. How/when these disks form planets and what sets the planets initial compositions remain key outstanding questions in disk science. In recent years, major leaps in sensitivity and spatial resolution afforded by the Atacama Large Millimeter/Submillimeter Array (ALMA) have revolutionized our understanding of protoplanetary disks chemical composition and physical properties, revealing in some cases complex radial, vertical, and azimuthal structure in the dust and gas. In this contribution, I review recent observational results and new theoretical puzzles, and how these fit into a newly emerging picture of the disk environment.