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Historically, quantization of the motion of particles was developed first. The state was described by a wave function and observables by operators. When dealing with interactions between particles and fields, such as the electromagnetic field, the fields were treated classically. Classical field equations look like the quantum mechanical equations for the wave function of the field quanta. For example, the Klein–Gordon classical field equation is similar to the quantum mechanical wave equation for a relativistic spinless particle. Quantizing the fields, leading to quantum field theory, appears to be quantizing a theory that has already been quantized; hence the name “second quantization.” In reality, there is only one quantization and one quantum theory.
The method of second quantization is important in the study of many-particle systems. It enables us to express many-body operators in terms of creation and annihilation operators, thus rendering calculations less cumbersome. Moreover, the method makes it possible to treat systems with a variable number of particles; that is why the method initially emerged in the context of quantum field theory.
In Chapter 1 we indicated that any one-particle wave function may be expanded in a complete set of states. In this chapter, we show that products of single-particle states, when properly symmetrized, form an orthonormal basis for the expansion of the wave function of an N-particle system.
False friends are common. Yes, but where True nature links a friendly pair, The blessing is as rich as rare.
-From the Panchatantra Translated by Arthur W. Ryder
The magnet of their course is gone, or only points in vain The shore to which their shiver'd sail shall never stretch again.
-Lord Byron, Youth and Age
Superconductivity was discovered in 1911 by H. Kamerlingh Onnes soon after he succeeded in liquefying helium (Onnes, 1911). He observed that the resistivity of mercury dropped suddenly as its temperature was lowered below a certain critical value TC (for Hg, TC = 4.2 K). Over the years, it was found that many additional elements and compounds similarly transition to a superconducting state. In this state, materials exhibit properties that are strikingly different from the normal state. Below we discuss the most important features of superconductors.
Properties of superconductors
The first important property of a material that undergoes a superconducting transition is that its resistivity drops to zero belowa critical temperature (see Figure 12.1). In a superconducting ring, a persistent electric current flows without any observable attenuation for as long as one is willing to watch.
A concise introduction to Feynman diagram techniques, this book shows how they can be applied to the analysis of complex many-particle systems, and offers a review of the essential elements of quantum mechanics, solid state physics and statistical mechanics. Alongside a detailed account of the method of second quantization, the book covers topics such as Green's and correlation functions, diagrammatic techniques and superconductivity, and contains several case studies. Some background knowledge in quantum mechanics, solid state physics and mathematical methods of physics is assumed. Detailed derivations of formulas and in-depth examples and chapter exercises from various areas of condensed matter physics make this a valuable resource for both researchers and advanced undergraduate students in condensed matter theory, many-body physics and electrical engineering. Solutions to exercises are available online.