We consider the two-dimensional minimisation problem for $\inf \{ E_a(\varphi ):\varphi \in H^1(\mathbb {R}^2)\ \text {and}\ \|\varphi \|_2^2=1\}$, where the energy functional $ E_a(\varphi )$ is a cubic-quintic Schrödinger functional defined by $E_a(\varphi ):=\tfrac 12\int _{\mathbb {R}^2}|\nabla \varphi |^2\,dx-\tfrac 14a\int _{\mathbb {R}^2}|\varphi |^4\,dx+\tfrac 16a^2\int _{\mathbb {R}^2}|\varphi |^6\,dx$. We study the existence and asymptotic behaviour of the ground state. The ground state $\varphi _{a}$ exists if and only if the $L^2$ mass a satisfies $a>a_*={\lVert Q\rVert }^2_2$, where Q is the unique positive radial solution of $-\Delta u+ u-u^3=0$ in $\mathbb {R}^2$. We show the optimal vanishing rate $\int _{\mathbb {R}^2}|\nabla \varphi _{a}|^2\,dx\sim (a-a_*)$ as $a\searrow a_*$ and obtain the limit profile.