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Sustainability of the plastron on nano-grass-covered micro-trench superhydrophobic surfaces in high-speed flows of open water

Published online by Cambridge University Press:  27 April 2023

Ning Yu*
Affiliation:
Mechanical and Aerospace Engineering Department, University of California, Los Angeles (UCLA), Los Angeles, California 90095, USA
Zhaohui “Ray” Li
Affiliation:
Mechanical and Aerospace Engineering Department, University of California, Los Angeles (UCLA), Los Angeles, California 90095, USA
Alexander McClelland
Affiliation:
Mechanical and Aerospace Engineering Department, University of California, Los Angeles (UCLA), Los Angeles, California 90095, USA
Francisco Jose del Campo Melchor
Affiliation:
Mechanical and Aerospace Engineering Department, University of California, Los Angeles (UCLA), Los Angeles, California 90095, USA
Sun Youb Lee
Affiliation:
Department of Mechanical Engineering, UNIST, Ulsan 44919, Republic of Korea
Jae Hwa Lee
Affiliation:
Department of Mechanical Engineering, UNIST, Ulsan 44919, Republic of Korea
Chang-Jin “CJ” Kim
Affiliation:
Mechanical and Aerospace Engineering Department, University of California, Los Angeles (UCLA), Los Angeles, California 90095, USA Bioengineering Department, University of California, Los Angeles (UCLA), Los Angeles, California 90095, USA California NanoSystems Institute (CNSI), University of California, Los Angeles (UCLA), Los Angeles, California 90095, USA
*
Email address for correspondence: yuning@ucla.edu

Abstract

This paper studies the sustainability of plastrons on superhydrophobic (SHPo) surfaces made of longitudinal micro-trenches covered by nano-grass with the main interest on hydrodynamic friction drag reduction in high-speed flows of open water, which represent the operating conditions of common watercraft. After revising the shear-driven drainage model to address the air diffusion for SHPo surfaces, the existing theories are combined to reveal the trends of how the immersion depth, air saturation level and shear stress affect the maximum attainable plastron length. Deviations from the theories by the dynamic effect at the two ends of the trench, the interfacial contaminations and turbulent fluctuation are also discussed. A combinatorial series of well-defined SHPo trench surfaces (4 cm × 7 cm in size with varying trench widths, depths, lengths and roughnesses) is microfabricated and attached underneath a 4 m long motorboat on seawater in turbulent flows up to 7.2 m s−1 (shear rate ∼83 000 s−1 and friction Reynolds number ∼5500). Because the plastron can provide a substantial slip only while its air–water interfaces are pinned (or only slightly depinned) at the trench top, two underwater cameras are employed to differentiate the pinned (and slightly depinned) interfaces from the depinned (and no) interfaces. In addition to achieving pinned plastrons on 6 cm long trenches aligned to high-speed flows in open water, the experimental results corroborate the theoretical estimations, supporting the design of SHPo surfaces for field applications.

Information

Type
JFM Papers
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
Copyright
© The Author(s), 2023. Published by Cambridge University Press.
Figure 0

Figure 1. Schematic illustration of plastron being compromised on a SHPo surface made of micro-trenches with vertical sidewalls. (a) Since the water pressure is usually higher than the trapped air pressure, the air–water interface is concave when pinned (a-1). If the water pressure is large enough to make the contact angle of water on the trench sidewall exceed the advancing contact angle θa, the contact line is depinned from the top edges and slides into the trench (a-2) until the trench is fully wetted (a-3). ((b) Although not common, if the water pressure is lower than the trapped air pressure, the meniscus is convex when pinned (b-1). If the contact angle of water on the trench top decreases below the receding contact angle θr, the contact line is depinned from the top edges and lets the neighbouring air pockets merge (b-2). The merged air may form isolated bubbles off the surface, shrinking the plastron (b-3), which grows back to the pinned state (b-1).

Figure 1

Figure 2. Pressure distributions along the trench. For the air–water interface to stay pinned on the trench top at x, the pressure difference between the water and the plastron, $\Delta P(x) = {P_{water}}(x)-{P_{air}}(x)$ (blue vertical arrows), should be sustainable by the Laplace pressure of meniscus ΔPσ or $\Delta {P_{\sigma ,min}} < \Delta P(x) < \Delta {P_{\sigma ,max}}$. (a) The effect of immersion depth H and air saturation level s. In static water, the water pressure on the trench surface (thick green line) is ${P_{water,st}} = {P_{atm}} + {P_H}$. The partial pressure of air dissolved in water Pair,st is sPatm (thick red line), which equals Patm if the water at the free surface (in contact with ambient air) is saturated with the atmospheric air. (b) The effect of shear stress by water τw. In flowing water, the shear stress τw makes the air pressure in the plastron Pair(x) (thick red line) increase linearly with x, decreasing the pressure difference ΔP(x) along the trench. (c) When immersed in flowing water, the two trends of (a) and (b) are combined to suggest a more general trend. (d) The above trend may be deviated by the dynamic effects of water flow near the front and rear end of trench.

Figure 2

Figure 3. A hydrophobic micro-trench submerged in longitudinally flowing water with the contact lines pinned on top. (a) An exemplary illustration of plastron morphology. The arrow in the trench shows the air circulation inside the plastron. (b) Profiles of the x-direction air flow inside plastron. The net air flow profile consists of three different flow profiles: shear driven, Laplace pressure driven and air diffusion driven. The first two profiles follow Wexler et al. (2015) developed for LIS, and the third profile is newly introduced to account for the air diffusion across the air–water interface, which varies along the x-direction. The air flux (in the x-direction) induced by the air diffusion varying along x turns out to be small for the flow conditions of this study.

Figure 3

Figure 4. Experimental set-up. (a) Schematic cross-section view of boat set-up. (b) Schematic cross-section view of the testing unit, including shear sensor and camera set-up. (c) Picture of the boat. (d) Picture of the bottom of testing well, taken by looking up from below in air.

Figure 4

Figure 5. The SHPo samples prepared for the experimental verification. (a) Illustration of 3 different trench types depending on the edge shape and surface roughness. The SEM pictures reveal the top edges of the cross-cleaved trenches as well as the nano-grass. (b) Each sample carries 10 parallel sections each containing 30 or 42 trenches. All trenches in this study have a gas fraction w/p = 0.9. The 40 mm × 70 mm sample has a 30 mm × 60 mm micromachined surface surrounded by a smooth surface. The micromachined region has repeated sections of longitudinal trenches with p = 75 μm (drawn blue) and p = 100 μm (drawn red) combined with L = 2.5, 5, 10, 30, 60 mm. The inset SEM picture shows a spanwise divider which partitions a 60 mm trench into shorter trenches. The same arrangement was used for all the 12 samples (3 roughness types × 4 trench depths), providing 120 different trench geometries with one photomask. The SEM pictures of cleaved samples show the trenches of two different pitches and one depth d = 67.5 μm.

Figure 5

Table 1. Contact angles of water on FDTS-coated nano-grass and smooth surface.

Figure 6

Figure 6. Sample images for key trends. Some regions are colour-outlined to help identify the plastron states, which were determined using the corresponding image pairs in Appendix E. Blue, yellow and red indicate the pinned or slightly depinned interface (i.e. h/w ≤ 0.17), depinned interface (i.e. 0.17 < h/w < d/w) and no interface (i.e. h/w = d/w), respectively. (a) The effect of trench width w shown by the side camera. Narrower trenches maintained the plastron better. (b) The effect of shear stress τw shown by the side camera. Slower flows maintained the plastron better. (c) The effect of trench depth d shown by the side camera. Deeper trenches maintained the plastron better. (d) The effect of nano-grass shown by the two cameras. For each pair of images, the top image was taken by the side camera, and the bottom image was taken by the rear camera. While the plastron was lost significantly on RE at this high flow speed (U = 6.4–6.7 m s−1), a pinned or slightly degraded plastron was found for all trenches on NG and RE + NG, demonstrating the effectiveness of adding nano-grass. (e) Effects of dynamic water pressure and interfacial contamination shown by the rear camera. Regions with trench length L = 2.5 mm, 10 mm, and 60 mm are outlined. The inset picture shows the pinned or slightly depinned interfaces at the front end of the 60 mm trenches.

Figure 7

Figure 7. Experimentally obtained plastron length Lp and theoretically estimated ranges of steady-state plastron length Lss as function of boat speed U for the experimental conditions in this study. (a) RE: trench with the re-entrant top edge and smooth surface, drawn blue. (b) NG: trench without the re-entrant top edge and nano-grass surface, drawn orange. (c) RE + NG: trench with re-entrant top edge and nano-grass surface, drawn red. The boat speed varied between ∼2 m s−1 < U < ∼7 m s−1. On each graph, the area above Lp = 60 mm was made dark to indicate an impossible range. Considering the numerous factors that were uncontrollable during the boat tests over several months, the experimental results match the theoretical estimations quite well.

Figure 8

Table 2. Approximation for parameters on boat tests. Here, U and x were measured from experiments, and other parameters were estimated from theoretical equations.

Figure 9

Figure 8. Three-dimensional simulation for a turbulent flow of water over a micro-trench filled with air, assuming a flat air–water interface. (a) Schematic of the computational domain and boundary conditions. (b) Velocity vector superimposed with the volume fraction contour (the axes are not scaled). The blue and red contours on the $\hat{x}\hat{y}$-plane indicate the water and the air phases, respectively. (c) Mean pressure and (d) root mean square of the turbulent pressure fluctuations for the water and air right above and below the interface $(\hat{y} = {\hat{y}_{interface}} \pm 1.0 \times {10^{ - 6}}\;\textrm{m)}$, respectively, or at the wall ($\hat{y}$ = 0). The water and air pressure variations along the trench corroborate figure 2(d).

Figure 10

Figure 9. Wall shear stress on a smooth surface τw0 at different boat speeds. The experimental data fit the power regression line.

Figure 11

Figure 10. Sample images at speeds in the range 3.3–3.8 m s−1. Blue indicates a pinned or slightly depinned interface (i.e. h/w ≤ 0.17); yellow indicates a depinned interface (i.e. 0.17 < h/w < d/w); and red indicates no interface (i.e. h/w = d/w).

Figure 12

Figure 11. Sample images at speeds in the range 4.4–5 m s−1. Blue indicates a pinned or slightly depinned interface (i.e. h/w ≤ 0.17); yellow indicates a depinned interface (i.e. 0.17 < h/w < d/w); and red indicates no interface (i.e. h/w = d/w).

Figure 13

Figure 12. Sample images at speeds in the range 5.2–5.7 m s−1. Blue indicates a pinned or slightly depinned interface (i.e. h/w ≤ 0.17); yellow indicates a depinned interface (i.e. 0.17 < h/w < d/w); and red indicates no interface (i.e. h/w = d/w).

Figure 14

Figure 13. Sample images at speeds in the range 6.3–6.7 m s−1. Blue indicates a pinned or slightly depinned interface (i.e. h/w ≤ 0.17); yellow indicates a depinned interface (i.e. 0.17 < h/w < d/w); and red indicates no interface (i.e. h/w = d/w).

Figure 15

Table 3. Experimental parameters. The Reynolds number based on boundary layer thickness is $R{e_{\delta 0}} = U{\delta _0}/\nu$. The Weber number is defined as $W{e_{\tau 0}} = {\mu _{water}}{u_{\tau 0}}/\sigma$. The friction Reynolds number is $R{e_{\tau 0}} = {u_{\tau 0}}{\delta _{v0}}/\nu$. The trench length ${L^{ + 0}}$ is based on the longest trenches. The range of $L_{ss}^{ + 0}$ is determined from the range of air saturation measured during the experiments (i.e. 100%-101% in this study). For the plastron length, $L_p^{ + 0} = L_{ss}^{ + 0}$ if $L_{ss}^{ + 0} < {L^{ + 0}}$, and $L_p^{ + 0} = {L^{ + 0}}$ if $L_{ss}^{ + 0} > {L^{ + 0}}$.

Yu et al. Supplementary Movie

Plastron loss at high-speed flows

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