Laser-driven plasma wakefield acceleration (LWFA) offers exceptionally high acceleration gradients and can produce high-brightness electron beams. However, the laser-to-electron energy conversion efficiency typically remains limited to a few percent. Theoretically, the self-mode transition from LWFA to beam-driven plasma wakefield acceleration (PWFA) provides a pathway for fully utilizing the laser energy. Here, we demonstrate the single-stage LPWFA (hybrid LWFA–PWFA) scheme, validated through comparative experiments using a 300 TW tightly focused laser interacting with sub-critical density nitrogen gas targets. The experiments produce an electron beam with charge of approximately 31 nC above 6 MeV and approximately 116 nC above 2 MeV. The laser-to-electron energy conversion efficiency is approximately 6.1% (>6 MeV) and 16.4% (>2 MeV), respectively. Particle-in-cell simulations confirm that the single-stage LPWFA mechanism depletes the laser energy and enables continual electron injection. This high-charge, multi-MeV electron beam has great value in the generation of high-brightness
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