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In the Schrödinger and Heisenberg representations, the time-evolution operator depends on the full time-dependent Hamiltonian, which includes an external time-dependent potential. Out of this full-time dependence, it is useful to isolate the time dependences due to either the full system Hamiltonian or its noninteracting part. These two cases, referred to as the Heisenberg and interaction pictures, respectively, are considered separately.
The t-matrix approximation applies to a low-density (or dilute) Fermi gas with a short-range interparticle interaction, either attractive or repulsive. This chapter considers the nonequilibrium (time-dependent) version of the t-matrix approximation for fermions in the normal phase, in the perspective of applying it to the BCS–BEC crossover.
This chapter first recalls the time-independent Bogoliubov–deGennes equations for the equilibrium case and shows their equivalence to the Gor’kov approach for inhomogeneous fermionic superfluidity at equilibrium. It then considers the extension of the Bogoliubov–deGennes approach to the nonequilibrium case in the framework of the Kadanoff–Baym equations, once implemented at the mean-field level. Properties of the solutions are considered in detail.
We investigate the interfacial fluid dynamics and heat transfer at nanoscales using an improved diffuse interface approach for liquid–vapour interfaces in non-equilibrium. Conventional Navier–Stokes–Korteweg (NSK) formulations often fail to accurately capture transport phenomena across extremely thin interfaces due to underestimation of interface resistances. In this work, we improve the NSK model by adding a production term in the momentum equation based on higher-order corrections. To enhance interface resistances, viscosity and thermal conductivity are made dependent on the density gradient, increasing resistance only within the interface region. The gradient-based coefficients are determined by fitting to solutions of the Enskog–Vlasov equation for Couette flow of Struchtrup & Frezzotti (2022 J. Fluid Mech., vol. 940, p. A40). Applying these fitted equations to pure heat conduction and planar evaporation problems shows that the model accurately captures interfacial transport, making it a useful tool for studying nanoscale evaporation, thermal management and the droplet dynamics on solid surfaces.
This chapter introduces the contour Schwinger–Keldysh method for time-dependent averages, in light of its relevance to nonequilibrium processes. A key feature of this approach is that it leaves open the possibility that no state of a system in the future can be identified with any of its states in the past. This method is here illustrated in detail with reference to time-dependent quantum averages, whereby for definiteness the system is initially prepared at the reference time t₀ in a definite quantum state.
This chapter considers the closed-time-path Green’s functions approach when specified to equilibrium situations and shows that it offers an alternative to the more standard Matsubara plus analytic continuation procedure for obtaining physical quantities directly in real frequency. In this case, the number of independent components of the single-particle Green’s function (as well as of the related self-energy) reduces considerably, thereby making it easier to solve the Kadanoff–Baym equations. The fluctuation–dissipation theorem and the single-particle spectral function (with its related sum rule) are also considered.
Similar to Chapter 20 of Part I and Chapter 31 of Part II, this chapter considers the treatment of a few topics, which are relevant to the general purposes of the book, but whose inclusion in previous chapters would have diverted the discussion of the main topics of interest therein. Specifically, it addresses a schematic derivation of the Lindblad Master equation (aimed at helping the reader in retracing and better identifying the essential steps made and approximations adopted in the more general derivation presented in Chapter 35), as well as the physical assumptions underlying the original Kadanoff–Baym ansatz.
Flexible substrates are effective in suppressing splashing, but they simultaneously lead to inhibition of spreading (Howland et al. 2016 Phys. Rev. Lett. vol. 117, 184502; Vasileiou et al. 2016 Proc. Natl Acad. Sci. USA vol. 113, pp. 13307−13312). In addition, there has been limited investigation and no established scaling law for the splashing threshold in the case of flexible substrates. To address these points, this paper proposes a lotus-leaf-like disk that can effectively suppress droplet splashing without inhibiting the maximum spreading of droplets. This situation is numerically studied in this paper. Five dynamic modes of the impacting droplet are identified with various Weber numbers (defined as the inertia force relative to the surface tension force) and different disk’s stiffnesses. The threshold Weber number of splashing is developed by considering the flexibility of substrates. Finally, the results demonstrate that the proposed method not only suppresses the splashing but also maintains the maximum spreading.
Three-dimensional total-flow visualization obtained by superposing the 2D mean flow with the resolvent-based standing-wave model at St = 0.01, using the spanwise wavelength corresponding to the leading SPOD mode found in the experimental data. The red u=0 iso-surface shows the separation bubble.
This study investigates the low-frequency dynamics of a turbulent separation bubble (TSB) forming over a backward-facing ramp, with a focus on large-scale coherent structures associated with the so-called `breathing motion’. Using time-resolved particle image velocimetry (PIV) in both streamwise and spanwise planes, we examine the role of sidewall confinement, an aspect largely overlooked in previous research. Spectral proper orthogonal decomposition (SPOD) of the streamwise velocity field reveals a dominant low-rank mode at low Strouhal numbers ($St \lt 0.05$), consistent with prior observations of TSB breathing. Strikingly, the spanwise-oriented PIV data uncover a previously unreported standing-wave pattern, characterised by discrete spanwise wavenumbers and nodal/antinodal structures, suggesting the presence of spanwise resonance. To explain these observations, we construct a resolvent-based model that imposes free-slip conditions at the sidewall locations by superposing left- and right-travelling three-dimensional modes. The model accurately reproduces the spanwise structure and frequency content of the measured SPOD modes, demonstrating that sidewall reflections lead to the formation of standing-wave-like patterns. Global stability analysis reveals a zero-frequency eigenmode originating from a centrifugal instability, giving rise to the observed low-frequency breathing. Downstream, the associated coherent structures are further amplified through non-modal lift-up mechanisms. Our findings highlight the critical influence of spanwise boundary conditions on the selection and structure of low-frequency modes in TSBs. This has direct implications for both experimental and numerical studies relying on spanwise-periodic boundary conditions and offers a low-order framework for predicting sidewall-induced modal dynamics in separated flows.
A computational fluid dynamics simulation of subcooled flow boiling of water at 10.5 ${\rm bar}$, with an applied heat flux of $1\,{\rm MW}\,{\rm m}^{-2}$ and subcooling of 10 ${\rm K}$, was performed using an interface tracking method. The simulation replicated the conditions of an experiment conducted at MIT. The objectives are to elucidate heat-transfer mechanisms in moderate-pressure subcooled boiling and to validate the simulation method, with a focus on quantities that are difficult to measure experimentally, such as the distributions of velocity, temperature, bubble number density and heat-flux partitioning. Due to the small bubble size under high pressure, fine grids are required. Simulated bubble shapes, wall temperatures and vapour area fractions show good agreement with the experimental results. The simulations reveal that a very thin liquid layer (${\lt}4\,\unicode{x03BC}{\rm m}$) surrounding the bubbles is highly effective at removing heat from the surface. The local wall heat fluxes beneath medium and large bubbles, excluding the heat flux associated with seed-bubble generation, are approximately 0.9 and 0.4 ${\rm MW}\,{\rm m}^{-2}$, respectively; the latter is smaller because of the presence of thicker liquid films (14–70 $\unicode{x03BC}{\rm m}$) that thermally insulate the wall. In the single-phase liquid region, the heat transfer coefficient reaches $42\,{\rm kW}\,{\rm m}^{-2}\,{\rm K}^{-1}$ as a result of strong turbulent heat flux in the wall-normal direction; this turbulent heat flux is approximately eight times larger than in the equivalent single-phase liquid flow.
Thin liquid films play an instrumental role in the coating industry. In many cases, these films consist of multiple components and are applied in multiple layers. However, multilayer multicomponent coatings can readily develop thickness non-uniformities due to Marangoni flows driven by solute concentration gradients. Previous flow visualisation experiments have demonstrated that the addition of surfactant can suppress such non-uniformities, but the physical mechanisms underlying this suppression have not yet been definitively established. We investigate the growth of film-height non-uniformities in a two-layer multicomponent coating consisting of a solute-rich bottom layer, a solute-depleted top layer and surfactant. A lubrication-theory-based model that accounts for vertical and lateral gradients in solute and surfactant concentrations is developed. The resulting coupled nonlinear partial differential equations describing the film height, solute concentration and surfactant concentration are solved with a pseudospectral method. Our findings reveal that surfactant-induced Marangoni flows can significantly decrease film-height non-uniformities by competing with Marangoni flows due to solute concentration gradients. Several simplifications of the governing equations are explored to determine how well predictions from these simplified models compare with the full lubrication-theory-based model, thereby providing insight into dominant physical mechanisms in different parameter regimes. The role of surfactant solubility and sorption kinetics in controlling perturbation growth is also examined.
Bioregenerative life support systems (BLSS) designed to produce food crops in future crewed missions to the Moon or Mars consider in-situ resource utilisation (ISRU). Lunar regolith is, therefore, in focus for future technologies of farming on lunar bases. We tested germination and early growth of broccoli plants (Brassica oleracea var. botrytis italica) in Murashige-Skoog liquid medium with addition of leachate from a lunar regolith simulant. As the additions to growth, differently diluted water and acidic leachates were used. Physiological status of the germinating plants was evaluated by chlorophyll fluorescence parameters related to plant vitality (relative fluorescence decline – Rfd) and photosynthetic performance of photosystem II (1) potential (FV/FM) and (2) effective quantum yield of PSII (ΦPSII), photochemical quenching referring to number of open PSII reaction centres. Both water and acidic leachates inhibited plant growth, however, the extent of growth limitation was dilution-dependent. Full inhibition of germination was apparent when undiluted acidic leachate was added. However, 50% dilution (and higher) resulted in seed germination and the early growth. No negative effects of the water dilutions on FV/FM as well as ΦPSII, were apparent in 15 days old plants, their cotyledonary and the first primary leaves, in particular. Similarly, qP and Rfd showed no sign of either water or acidic leachate addition effect. Although photosystem II-related parameters exhibited no negative effect of the leachates addition, a growth of plants was found dilution-dependent: higher degree of dilution resulted in a more pronounced reduction in plant projection area. In spite of the growth rate reduction (compared to untreated control), properly diluted water and acidic leachates from lunar regolith and/or its simulants might be used in follow up studies focused on plant species prospective for future cultivation in Moon-based stations with temporary or permanent crew.
The coherent structures in supersonic turbulent boundary layers, particularly wall-attached Reynolds stress structures (RSS), exhibit significant correlations with skin-friction drag generation. However, the intrinsic coupling between streamwise motions, wall-normal motions, and evolutionary processes of RSS has obscured the precise mechanisms governing their scale-dependent interactions. This study investigates the generation mechanisms of high/low skin friction in a supersonic turbulent boundary layer via direct numerical simulations. A novel methodology combining a time-resolved clustering method and conditionally averaged skin-friction decomposition is employed, focusing on wall-attached RSS (Q2 ejections and Q4 sweeps) of varying wall-normal scales ($l_y^+$), which decomposes the skin-friction coefficient into contributions from streamwise ($C_{\kern-2.5pt f}^{M_x}$), wall-normal ($C_{\kern-2.5pt f}^{M_y}$) and spanwise ($C_{\kern-2.5pt f}^{M_z}$) motions, etc. Results show that $C_{\kern-2.5pt f}^{M_y}$ dominates friction generation, while $C_{\kern-2.5pt f}^{M_z}$ attenuates it. A significant scale dependence is revealed: $C_{\kern-2.5pt f}^{M_x}$ counteracts friction for large-scale structures, contrary to its effects at smaller scales. These three terms reflect the influence of momentum transport by RSS on skin friction, which is specifically manifested in the convective acceleration. The unsteady term ($C_{\kern-2.5pt f}^U$) partially offsets $C_{\kern-2.5pt f}^{M_x}$, linked to structural evolution phases: growth dominates for small scales, and decay for large scales. These findings elucidate the scale-dependent momentum transport mechanisms governing skin friction, providing insights for drag-reduction strategies in high-speed flows.
The transition between dripping and jetting regimes of capillary jets is crucial for applications such as ink-jet printing and drug release. A liquid jet emitting from a nozzle usually exhibits a non-uniform initial velocity profile, influencing the transition between regimes, with the role of velocity relaxation remaining largely unexplored. Here we investigate the dripping–jetting transition of a capillary jet with velocity relaxation through a combination of experiments and stability analysis. Experimental measurements show that velocity relaxation consistently lowers the critical transition Weber number, ${\textit{We}}_c$, contradicting predictions from the classic local spatio-temporal stability theory. To resolve this discrepancy, we developed a global stability model accounting for the velocity relaxation to calculate ${\textit{We}}_c$ at different Reynolds numbers (${\textit{Re}}$). Our model provides accurate predictions for jets both with and without velocity relaxation and reveals that the key to the discrepancy lies primarily in the non-parallel effects of jet disturbances caused by velocity relaxation. The velocity relaxation process upstream facilitates the non-uniformity and non-parallelism of the global disturbances and leads to stronger radial–axial coupling in the disturbance field at a higher ${\textit{Re}}$, showing a global dynamics beyond the ability of local analysis. Formulas of ${\textit{We}}_c$ for both Poiseuille- and uniform-velocity jets are proposed based on the results of global stability analysis. These findings elucidate the dynamics of the global instability for dripping–jetting transition under the influence of velocity relaxation and provide guidance for the precise control of jet behaviours in practical applications.
The generation and growth of wind waves are re-examined using linear viscous shear flow instability theory by solving the coupled in-air and in-water Orr–Sommerfeld equations. To enable comparison with the available laboratory observations, model simulations are performed for a wide range of wavelengths spanning the gravity–capillary and gravity wave regimes typical of such experiments. The sensitivity of the results to key modelling assumptions is investigated, including the friction velocity, the surface drift velocity at the air–water interface as well as the shapes of velocity profiles in air and in water, which are modelled using the mixing-length approach. Airflows both over an initially smooth surface and over a surface modified by the emergence of fast-growing short ripples, and thus effectively rough, are considered. A detailed energy budget analysis, based on eigenfunctions of the coupled Orr–Sommerfeld equations across different wavelengths, provides further insight into the mechanisms governing energy transfer from wind to water waves under diverse flow conditions.
Concentrated wave beams are analysed both theoretically and numerically in a general rotating and stratified axisymmetric medium, where both the rotation rate and the Brunt–Väisälä frequency vary with position. The fluid is assumed to be incompressible, weakly diffusive and weakly viscous. The analysis is conducted within the Boussinesq approximation and a linear framework, with a prescribed frequency. An asymptotic solution is derived in the limit of weak viscosity and diffusivity, describing a harmonic beam of inertia gravity waves localised around a characteristic (or ray path), similar to those generated by boundary singularities or critical points. This solution is shown to break down when the characteristic reaches a turning point which corresponds to the transition from oscillatory to evanescent behaviour. A local asymptotic analysis near the turning point demonstrates that the wave beam reflects, preserving its transverse structure while acquiring a phase shift of $\pm \pi /2$. These theoretical predictions are validated through numerical simulations, which show that the wave beam structure, both near and far from the turning point, is accurately reproduced.
To investigate how polymers influence energy transfer in three-dimensional turbulence, we conduct experiments in homogeneous bulk turbulence generated by a von Kármán swirling flow, using tomographic particle image velocimetry. A filtering approach is applied to the measured three-dimensional velocity fields to extract subgrid-scale (SGS) statistics, focusing on the filtered strain-rate tensor and SGS stress tensor. We find that polymer additives induce significant changes in the tensorial geometry: the strain-rate tensor shows a tendency towards an eigenvalue ratio of $1 : 0 : -1$, while the SGS stress tensor favours a $2 : -1 : -1$ configuration. The local energy flux – quantified by the inner product of the strain-rate and SGS stress tensors – is systematically suppressed by polymers and becomes increasingly intermittent. This suppression is linked to a reduced energy transfer efficiency, associated with the misalignment between the principal eigendirections of the two tensors. Anisotropic effects are also observed in the energy flux components, indicating that polymers affect vertical and horizontal energy transfer differently. Finally, the obtained SGS statistics allow for an a priori assessment of SGS models. Our results reveal that the nonlinear gradient model significantly outperforms the Smagorinsky model, particularly in polymer-laden turbulence. The diminished alignment between the strain-rate and SGS stress tensors may underlie the limitations of the Smagorinsky model, which assumes a scalar eddy-viscosity closure. These results provide new experimental insights into the SGS dynamics of polymeric turbulence and highlight the potential of nonlinear models for large-eddy simulations of viscoelastic flows.
The propagation of high-energy X-rays or hot electrons have the potential to alter the initial conditions in experimental target designs, especially at material interfaces, for laser-driven inertial confinement fusion (ICF) and high-energy density (HED) experimental platforms. Hot-electron preheat can drastically modify the initial conditions of experimental targets used to study the deceleration-stage Rayleigh–Taylor instability (RTI) both with and without applied magnetic fields. Therefore, it is necessary to understand and quantify the impact of hot-electron preheat. The hydrodynamic (HD) capabilities in the Ares code are used to study the effects varying levels of preheat can have on RTI evolution. The experimental and computational studies presented in this work demonstrate that at high laser intensities of around or greater than $10^{15} \,\textrm {W}\, \textrm {cm}^{-2}$, there is hot-electron generation from laser plasma instabilities which induces substantial preheat and impacts the morphology of RTI evolution and even inhibits the intended RTI growth such that it is not observable experimentally. The necessity of better quantifying hot-electron induced preheat and mitigating its impact on such high-intensity direct-drive laser experiments in the future is discussed.