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Competition of small targets in planar domains: from Dirichlet to Robin and Steklov boundary condition

Published online by Cambridge University Press:  12 January 2026

Denis S. Grebenkov
Affiliation:
CNRS – Université de Montréal CRM – CNRS, Montréal, QC, Canada Laboratoire de Physique de la Matière Condensée (UMR 7643), CNRS – Ecole Polytechnique, Institut Polytechnique de Paris, Palaiseau, France
Michael Jeffrey Ward*
Affiliation:
Department of Mathematics, University of British Columbia, Vancouver, BC, Canada
*
Corresponding author: Michael Jeffrey Ward; Email: ward@math.ubc.ca
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Abstract

We consider steady-state diffusion in a bounded planar domain with multiple small targets on a smooth boundary. Using the method of matched asymptotic expansions, we investigate the competition of these targets for a diffusing particle and the crucial role of surface reactions on the targets. We start from the classical problem of splitting probabilities for perfectly reactive targets with Dirichlet boundary conditions and improve some earlier results. We discuss how this approach can be generalised to partially reactive targets characterised by a Robin boundary condition. In particular, we show how partial reactivity reduces the effective size of the target. In addition, we consider more intricate surface reactions modelled by mixed Steklov-Neumann or Steklov-Neumann-Dirichlet problems. We provide the first derivation of the asymptotic behaviour of the eigenvalues and eigenfunctions for these spectral problems in the small-target limit. Finally, we show how our asymptotic approach can be extended to interior targets in the bulk and to exterior problems where diffusion occurs in an unbounded planar domain outside a compact set. Direct applications of these results to diffusion-controlled reactions are discussed.

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Papers
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
Copyright
© The Author(s), 2026. Published by Cambridge University Press
Figure 0

Figure 1. Illustration of a bounded domain $\Omega \subset {\mathbb{R}}^2$ with a smooth boundary $\partial \Omega$ split into three absorbing patches $\Gamma _{\varepsilon _i}$ of length $2\varepsilon _i$ (in red and blue), and the remaining reflecting part $\partial \Omega _0$ (grey dashed line). For a particle starting from a point ${{\boldsymbol{x}}}\in \Omega$, the splitting probability $S_1({{\boldsymbol{x}}})$ is the probability of hitting the blue patch $\Gamma _{\varepsilon _1}$ first.

Figure 1

Figure 2. Splitting probability $S_1({{\boldsymbol{x}}})$, given by Eq. (2.30), for the unit disk with two Dirichlet patches of length $2\varepsilon _1 = 0.2$ (red) and $2\varepsilon _2 = 0.4$ (blue). Note that $S_1({{\boldsymbol{x}}})$ was capped by $0$ and $1$, i.e., we plotted $\max \{0, \min \{1, S_1({{\boldsymbol{x}}})\}\}$.

Figure 2

Figure 3. (a) Function ${\mathcal{C}}(\mu )$ from Eq. (3.7), in which the infinite series is truncated either to 50 terms (solid line) or to 10 terms (crosses), to highlight the accuracy of both truncations. Filled circles indicate the values $-\mu _{2k}$, at which ${\mathcal{C}}(\mu )$ diverges. Dash-dotted line outlines the asymptotic limit $\ln (2)$ of ${\mathcal{C}}(\mu )$ as $\mu \to \infty$. (b) Comparison of ${\mathcal{C}}(\mu )$ and its approximation (3.10), which is accurate over a broad range of $\mu$.

Figure 3

Figure 4. The ratio of ${\mathcal{C}}(\mu )$ with its approximation (3.10) is very close to unity on the range $0\lt \mu \lt 1$.

Figure 4

Figure 5. Volume-averaged splitting probability $\overline {S}_1 = \chi _1$ for the unit disk, calculated from (3.17b), with two patches of equal length $2\varepsilon = 0.2$ located at boundary points $({\pm} 1,0)$. Three curves correspond to three values of the reactivity parameter $q_2$ of the second patch. Symbols present the numerical solution of the BVP (2.1b) with Robin boundary condition (3.1) by a finite-element method in Matlab PDEtool, with the maximal mesh size $0.02$.

Figure 5

Figure 6. Illustration for the unit disk with Steklov and Dirichlet patches. (a) One Steklov patch of length $2\varepsilon _1 = 0.4$ at ${{\boldsymbol{x}}}_1 = (1,0)$ (blue) and one Dirichlet patch of length $2\varepsilon _2 = 0.6$ (red), whose centre ${{\boldsymbol{x}}}_2$ is at angle $\theta = 2\pi /3$. (b) One Steklov patch of length $2\varepsilon _1 = 2\varepsilon = 0.2$ at ${{\boldsymbol{x}}}_1 = (1,0)$ (blue) and three Dirichlet patches of length $2\varepsilon _j = 0.4$ (red), whose centres ${{\boldsymbol{x}}}_j$ are equally spaced on the boundary of the unit disk.

Figure 6

Figure 7. Dependence of $1/(\varepsilon _1\sigma _0)$ on $\varepsilon _2$ for the unit disk with a Steklov patch of length $2\varepsilon _1$ (located at ${{\boldsymbol{x}}}_1 = (1,0)$), and one Dirichlet patch of length $2\varepsilon _2$, located at ${{\boldsymbol{x}}}_2$. Symbols present the numerical solution by a FEM with the maximal mesh size $h_{\textrm {max}} = 0.005$ and lines show Eq. (5.30). (a)${{\boldsymbol{x}}}_2 = (0,1)$ and three values of $\varepsilon _1$: $\varepsilon _1 = \pi /6$ (circles), $\varepsilon _1 = \pi /12$ (squares), and $\varepsilon _1 = \pi /24$ (triangles). (b)$\varepsilon _1 = \pi /12$ and two locations of the Dirichlet patch: ${{\boldsymbol{x}}}_2 = ({-}1,0)$ (circles, $\theta = \pi$), and ${{\boldsymbol{x}}}_2 = (0,1)$ (squares, angle $\theta = \pi /2$).

Figure 7

Figure 8. The eigenfunctions $V_j$ restricted on the Steklov patch $\Gamma _{\varepsilon _1}$, for the unit disk with a Steklov patch of length $2\varepsilon _1 = \pi /12 \approx 0.26$ (located at ${{\boldsymbol{x}}}_1 = (1,0)$), and one Dirichlet patch of length $2\varepsilon _2 = \pi /6 \approx 0.52$, located at ${{\boldsymbol{x}}}_2 = ({-}1,0)$. Filled circles present the numerical solution by a FEM with the maximal meshsize $h_{\textrm {max}} = 0.005$, while solid lines show Eq. (5.19) for $j = 0$ and Eq. (5.24) for $j \gt 0$. Four panels present the cases $j = 0,1,2,3$.

Figure 8

Figure 9. Dependence of $1/(\varepsilon \sigma _0)$ on $\varepsilon$ for the unit disk with one Steklov patch of length $2\varepsilon$ (located at ${{\boldsymbol{x}}}_0 = (1,0)$), and $N-1$ Dirichlet patches of length $4\varepsilon$, equally spaced on the boundary of the unit disk. Symbols present the numerical solution by a FEM with the maximal meshsize $h_{\textrm {max}} = 0.005$ and lines show Eq. (5.38).

Figure 9

Figure 10. Dependence of $1/(\varepsilon _1 \sigma )$ on $\varepsilon$ for the unit disk with the Steklov patch of length $2\varepsilon _1 = 0.2$ and $63$ Dirichlet patches (each of length $2\varepsilon$) that are equally spaced on the boundary of the unit disk. Filled circles correspond to $\kappa _j$ obtained via the discrete sum (5.38), the solid line indicates its large-$N$ approximation (5.43), and the dashed line is the low-order approximation (5.44).

Figure 10

Figure 11. Illustration of a bounded domain $\Omega \subset {\mathbb{R}}^2$ with a smooth reflecting boundary $\partial \Omega _0$ (grey dashed line) and three interior targets $\Omega _{\varepsilon _j}$ (filled in grey), centred at ${{\boldsymbol{x}}}_j$, with reactive boundaries $\Gamma _{\varepsilon _j}$ (in red and blue). For a particle started from a point ${{\boldsymbol{x}}}\in \Omega$, the splitting probability $S_1({{\boldsymbol{x}}})$ is the probability of hitting the boundary $\Gamma _{\varepsilon _1}$ first.

Figure 11

Figure 12. The asymptotic behaviour of the principal eigenvalue of the mixed Steklov- Neumann-Dirichlet problem, plotted as $1/(\varepsilon _1\sigma _0)$ versus $\varepsilon _2$, for the unit disk with two interior circular targets of radii $\varepsilon _1 = 0.05$ and $\varepsilon _2$ (variable from $0.01$ to $0.1$), located at ${{\boldsymbol{x}}}_1 = ({-}0.5,0)$ and ${{\boldsymbol{x}}}_2 = (0.5,0)$. Filled circles present the numerical solution by a FEM with the maximal mesh size of $0.005$, solid line indicates Eq. (6.11).

Figure 12

Table B1. Comparison between the exact values of $\kappa _j$ from Eq. (2.41), their approximation (B.8), and its simpler asymptotic forms (B.11) and (B.12).

Figure 13

Figure B1. Exact values of $\kappa _j$ versus $j/N$ on $0.2 \lt {j/N}\lt 0.5$ for $N=64$ from Eq. (2.41), shown by filled circles, and their approximations (B.11, B.12, B.13) shown by lines.

Figure 14

Table C1. List of eigenvalues $\mu _{2k}$ and coefficients $[\Psi _{2k}(\infty )]^2$ of the first 10 contributing terms in the spectral expansion (C.10) for ${\mathcal{C}}(\mu )$ (in addition, one has $\mu _0 = 0$ and $\Psi _0(\infty ) = 1/\sqrt {2}$). The reported values were obtained numerically by using a matrix representation of the Steklov problem in elliptic coordinates (see Appendix D). The matrix was truncated to the size $100 \times 100$ and then diagonalised numerically. The shown values did not change when the truncation order was increased to $500 \times 500$. For comparison, the large-$k$ asymptotic approximations of $\mu _{2k}$ and $[\Psi _{2k}(\infty )]^2$ from Eqs. (C.11, C.12) are also present. For completeness, we also present the first ten eigenvalues $\mu _{2k-1}$ that correspond to antisymmetric eigenfunctions $\Psi _{2k-1}$ that vanish at infinity.

Figure 15

Figure D1. The Steklov eigenfunctions $\Psi _{2k}(y_1,0)$, restricted onto the interval $({-}1,1)$, are shown by thick lines. These eigenfunctions are obtained by truncating the series in Eq. (D.2) to $n \leq 100$, with the coefficients $c_{k,n}$ found by diagonalising the truncated matrix $\textbf{M}$ from Eq. (D.4). For comparison, functions $\cos (\pi k y_1)$ are plotted by thin lines.

Figure 16

Table F1. Summary of available formulas for various Neumann Green’s functions. Note that the surface Neumann Green’s function for rectangles can be derived from the results in [52, 61]. In turn, its extension to the exterior problem is not available.