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Using a welcoming and conversational style, this Student's Guide takes readers on a tour of the laws of thermodynamics, highlighting their importance for a wide range of disciplines. It will be a valuable resource for self-guided learners, students, and instructors working in physics, engineering, chemistry, meteorology, climatology, cosmology, biology, and other scientific fields. The book discusses thermodynamic properties such as temperature, internal energy, and entropy, and develops the laws through primarily observational means without extensive reference to atomic principles. This classical approach allows students to get a handle on thermodynamics as an experimental science and prepares them for more advanced study of statistical mechanics, which is introduced in the final chapter. Detailed practical examples are used to illustrate the theoretical concepts, with a selection of problems included at the end of each chapter to facilitate learning. Solutions to these problems can be found online along with additional supplemental materials.
Theatrical performance engages with the material consequences of rising hot temperatures and severe bush fires as it continues to reflect changing beliefs about the weather. Verbatim theatre outlines some of the contradictions surrounding fire, which both regenerates and destroys as it conveys the gradual realisation that fire changes weather. Theatre points to how temperature-reducing tree preservation paradoxically becomes blamed for increasing the bush fire risk. The discussion foregrounds the clash of values in a liberal democratic society between the ongoing exploitation of environmental resources for economic gain and the longstanding efforts of activists and protestors to protect forests that store carbon and counteract rising temperatures. As characters and personae confront the life and death dilemmas posed by hot weather and fire including those from the social risk of arson, theatrical performance must grapple with ethical constraints surrounding the depiction of these events that cause fatalities.
This chapter introduces the two main, and original, statements of the second law of thermodynamics: the Clausius statement and the Kelvin–Planck statement. In addition, this chapter discusses the idea of a perfect engine and its requirements. Then, a discussion of reversibility ensues. This leads to the introduction of the Carnot engine, which is considered a perfect engine. Then, Carnot’s propositions are put forth, which paves the way for the introduction of thermodynamic temperature, which is a temperature scale that does not rely on the material used for the temperature measurement. Using these concepts, a new thermodynamic property is deduced: entropy. Entropy and heat are related to each other for reversible processes, and the idea of a temperature–entropy diagram is introduced and discussed. Although this chapter does not quite follow the historical timeline, the discussion of the second law is still nevertheless motivated by the historical development.
In this chapter, the first law of thermodynamics is developed using a series of experimental setups. In doing so, some new terminology and concepts are introduced. The idea of specific heat is revisited, and it is discovered that there are two forms of specific heat: a specific heat at constant volume and a specific heat at constant pressure. The important concepts of pressure work and thermodynamic cycles are also introduced.
In this chapter, the equations that were defined in Chapters 1–3 are used to solve some problems. In addition, the existing equations are modified to make them more useful for finding various property values. Also, two new thermodynamic properties are very briefly introduced, Gibbs energy (or Gibbs free energy) and Helmholtz energy (or Helmholtz free energy), in order to provide a full set of equations often associated with the laws of thermodynamics.
This chapter focuses on the concepts of temperature and heat and also develops some initial ideas for both based on experimental observations. In doing so, the concept of equilibrium is discussed. The chapter then discusses the zeroth law of thermodynamics and finishes up on the concept of phase change (solidification, evaporation, etc.). The discussion on phase change leads to the idea that the current version of heat used in this chapter needs to be modified in order to account for situations that do not involve a temperature change.
Edited by
Rebecca Leslie, Royal United Hospitals NHS Foundation Trust, Bath,Emily Johnson, Worcester Acute Hospitals NHS Trust, Worcester,Alex Goodwin, Royal United Hospitals NHS Foundation Trust, Bath,Samuel Nava, Severn Deanery, Bristol
Chapter 3.6 covers heat, temperature and humidity. There is basic science material covering the physics of heat and temperature measurement, the different equipment available to use and how each has advantages and disadvantages. We then have a clinical focus on perioperative heat loss in theatre and how it can be managed and reduced, followed by management of severe hypothermia with rewarming. Humidity again covers the basic physics. its measurement and clinical relevance to anaesthesia practice.
Heat-related mortality risks are a substantial component of the looming costs of climate change in the United States and globally. This article presents the results from a risk-risk survey to test whether U.S. respondents place a valuation premium on mortality risks from heat relative to cancer and transportation risks. The questionnaire exploits exogenous shocks to temperatures during a heat wave and randomized elements to further test whether preferences vary with heat exposure or the age of individuals exposed to heat risks. The results provide strong evidence that there is no valuation premium in the U.S. for heat-related risks. Subjects valued cancer risks twice as highly as heat and transportation risks, the latter of which are a common benchmark for general traumatic fatalities. While there is some evidence that subjects value heat risks more when exposed to a heat shock of approximately 3–4 °C, the size of the differential is too small to establish a statistically significant heat risk premium. Finally, subjects’ responses demonstrate no differential valuation of mortality risks to seniors versus the general population based on the preferences of the general population or the senior subsample.
This article explores the intersection of carceral geographies and climate (in)justice in Brazil, home to one of the world’s largest incarcerated populations. Drawing on ethnographic fieldwork, interviews and an analysis of reports from monitoring organisations examining facilities across the country, we ask how thermal conditions are part of a national project of inflicting suffering within the prison system. Conductive building materials, a lack or excess of water and ventilation, as well as overcrowding, exacerbate exposure to scorching heat or bone-chilling cold, subjecting prisoners’ bodies to extreme temperatures. We argue that this constitutes a form of thermal violence, in which heat and cold are weaponised to harm and punish.
This research examines whether high temperatures and exposure to childhood rainfall and heat shocks are a cognitive drag on children in Uganda. First, it asks whether students perform worse on a test on hotter days. Second, it examines whether previous longer-term exposure to high temperatures and unusual rainfall influences current test scores and educational outcomes. The analysis shows that high temperatures on test dates harm test performance, especially for girls and children younger than ten, implying additional temperature control considerations for particular demographics. The analysis of childhood climate shocks, which employs within-parish distributions of rainfall and heat, shows that children who experience rain or heat above the $80^{th}$ percentile of the parish distribution from birth until age 4 have worse learning outcomes in math, English, or local language literacy.
Malaria remains a major health challenge in developing countries, with climate change intensifying its impact. Pakistan is among the most vulnerable nations. This study examines the relationship between temperature and malaria cases in two highly affected districts, Bannu and Lakki Marwat, to inform climate-adaptive interventions.
We analyzed monthly malaria cases (2014–2022) from the Integrated Vector Control/Malaria Control Program in Khyber Pakhtunkhwa, combined with gridded meteorological data from Copernicus ERA5-Land. Time-series analysis using distributed lag nonlinear models and quasi-Poisson regression was applied to assess the associations.
The findings suggest that as temperatures exceed 22.4°C, malaria transmission increases by 9 to 10% for every 1°C rise in both districts. In Bannu, up to 39.8% of reported malaria cases could be attributed to heat, while in Lakki Marwat, 54.1% of cases were attributable to heat. Under high emission scenarios, heat-related malaria cases could increase by 0.8 to 3.5% by the 2060s. Relationship between temperature and malaria transmission is complex and is influenced by environmental factors such as precipitation and humidity.
Given Pakistan’s limited healthcare infrastructure, addressing climate-driven malaria risks is urgent. Recent severe floods and malaria surges highlight the need for climate adaptation measures and strengthened healthcare systems to enhance community resilience.
Seeds rely on temperature to adjust their germination timing by modulating primary and secondary dormancy. The knowledge regarding an intraspecific variation in the germination responses to supra-optimal temperatures during imbibition within the Solanum lycopersicon species and its relation with pre- and post-harvest environments is limited. Here, we studied the impact of imbibition at 35°C in 17 genotypes selected from a multiparent advanced generation intercross (MAGIC) population. We discovered a high genetic variability in the germination responses to heat, leading to thermotolerance, thermoinhibition or thermodormancy with different depths. While thermodormancy appeared more profound than primary dormancy, there was no correlation between the deepness of primary and thermodormancy. Post-harvest treatments influenced considerably germination at supra-optimal temperatures. Dry storage beyond the apparent loss of primary dormancy led to an increased proportion of thermotolerant or thermoinhibited seeds at the expense of thermodormancy in a genotype-dependent manner, thereby revealing cryptic genetic variation. Prolonged cold imbibition also led to increased thermodormancy in genotypes that produced thermotolerant and thermoinhibited seeds. The thermal history before and after flowering influenced primary dormancy and the germination response to heat during imbibition in a genotype-dependent manner, with high temperatures leading to increased thermotolerance or thermoinhibition at the expense of thermodormancy, suggesting transgenerational plasticity despite the domestication of the species. The high potential of the MAGIC population for quantitative trait loci mapping and causal polymorphism identification will be helpful in deciphering the regulatory mechanisms that lead to the plasticity of thermoinhibition or thermodormancy, as well as their connection to the parental environment.
The ability to create, manage and transport fire transformed dark into light, cold into warmth, formed a focus for the camps of hunter-gatherer groups and allowed management of landscapes to encourage browsing animals, while cooking expanded available foodstuffs and provided more energy for the brain. The taming of fire brought dramatic and long-lasting changes to human society, with immense impacts on personal, social and economic life.
We live in an era of major technological developments, post-pandemic social adjustment, and dramatic climate change arising from human activity. Considering these phenomena within the long span of human history, we might ask: which innovations brought about truly significant and long-lasting transformations? Drawing on both historical sources and archaeological discoveries, Robin Derricourt explores the origins and earliest development of five major achievements in our deep history, and their impacts on multiple aspects of human lives. The topics presented are the taming and control of fire, the domestication of the horse,and its later association with the wheeled vehicle, the invention of writing in early civilisations, the creation of the printing press and the printed book, and the revolution of wireless communication with the harnessing of radio waves. Written in an engaging and accessible style, Derricourt's survey of key innovations makes us consider what we mean by long-term change, and how the modern world fits into the human story.
Effects of acute thermal exposures on appetite appear hypothetical in reason of very heterogeneous methodologies. The aim of this study was therefore to clearly define the effects of passive 24-h cold (16°C) and heat (32°C) exposures on appetitive responses compared with a thermoneutral condition (24°C). Twenty-three healthy, young and active male participants realised three sessions (from 13.00) in a laboratory conceived like an apartment dressed with the same outfit (Clo = 1). Three meals composed of three or four cold or warm dishes were served ad libitum to assess energy intake (EI). Leeds Food Preference Questionnaires were used before each meal to assess food reward. Subjective appetite was regularly assessed, and levels of appetitive hormones (acylated ghrelin, glucagon-like peptite-1, leptin and peptide YY) were assessed before and after the last meal (lunch). Contrary to the literature, total EI was not modified by cold or heat exposure (P = 0·120). Accordingly, hunger scores (P = 0·554) were not altered. Levels of acylated ghrelin and leptin were marginally higher during the 16 (P = 0·032) and 32°C (P < 0·023) sessions, respectively. Interestingly, implicit wanting for cold and low-fat foods at 32°C and for warm and high-fat foods at 16°C were increased during the whole exposure (P < 0·024). Moreover, cold entrées were more consumed at 32°C (P < 0·062) and warm main dishes more consumed at 16°C (P < 0·025). Thus, passive cold and hot exposures had limited effects on appetite, and it seems that offering some choice based on food temperature may help individuals to express their specific food preferences and maintain EI.
Measurements of the differential heats of K-Ca exchange are used to show that 6 groups of sites (ranging from −13.8 to −5.1 kJ/eq and with as many as 4 in any one sample) exist in kaolins that range from 0 to 15% in their 2:1 phyllosillicate content. These heat values, coupled with entropies of exchange, suggest that 0.1−10% vermiculitic, micaceous, and smectitic layers are present, presumably interstratified with kaolinitic layers which are assumed to have no permanent charge. Changes in the activity coefficients of adsorbed K with K saturation confirm these conclusions qualitatively. Thus, fK values at x ↑ 0 correlate inversely (r2 = 0.655) with the content of vermiculite + partially expanding micas, and x values at maximum fK indicate the content of vermiculite + nonexpanding mica + partially expanding micas (r2 = 0.732).
Indoor climate interventions are often motivated from a worker comfort and productivity perspective. However, the relationship between indoor climate and human performance remains unclear. We assess the effect of indoor climate factors on human performance, focusing on the impact of indoor temperature on decision processes. Specifically, we expect heat to negatively influence higher cognitive rational processes, forcing people to rely more on intuitive shortcuts. In a laboratory setting, participants (N=257) were exposed to a controlled physical environment with either a hot temperature (28° C) or a neutral temperature (22° C) over a two-hour period, in which a battery of validated tests were conducted. We find that heat exposure did not lead to a difference in decision quality. We did find evidence for a strong gender difference in self-report, such that only men expect that high temperature leads to a significant decline in performance, which does in fact not materialize. These results cast doubt on the validity of self-report as a proxy for performance under different indoor climate conditions.
Fire stimulates the germination of most seeds in fire-prone vegetation. Fruits of Leucadendron (Proteaceae) are winged achenes or nutlets that correlate with their requirements for smoke and/or heat in promoting germination. We describe five possible smoke–heat dormancy-release/germination syndromes among plants, of which Leucadendron displays three (no response, smoke only, smoke and heat). As seed-coat thickness varies with seed-storage location (plant or soil) and morphology (winged or wingless), we tested its possible role in water uptake and germination. Species with winged seeds achieved 100% germination in the absence of smoke/heat, seed coats were an order of magnitude thinner, and their permeability greatly exceeded that of nutlets. As seed-coat thickness increased (1) imbibitional water uptake declined at a decreasing rate, and (2) the response to smoke, and to a lesser extent heat, increased linearly to reach levels of germination approaching those of winged seeds. For species responsive to smoke and heat, there was no additive effect when applied together, suggesting that they may have promoted the same physiological process. We conclude that seed-coat thickness holds the key to germination requirements in this genus, independent of seed-storage location or morphology. By what mechanisms (1) the smoke response is greater the thicker the seed coat and (2) smoke chemicals might increase water permeability to explain the non-additive effect of smoke and heat, warrant further investigation.
same as chapter 5. For land-based passenger mobility, the book analyses four parallel systems (auto-mobility, railways, bus, cycling) and six niche-innovations (electric vehicles, biofuels, tele-working, car sharing, intermodal transport, self-driving personal cars).
The basic quantitative tools to study the hydrodynamics, and any suspended and dissolved matter in water, of semi-enclosed basins are the conservation equations. Conservation of momentum and conservation of mass are used for water motion, while conservation of salt and conservation of heat address their distribution in space and time. An equation of state, the Thermodynamic Equation of Seawater, relates temperature (heat content in the water column), salinity, and pressure to water density, which plays a dynamic role in the conservation of momentum. The conservation of suspended or dissolved matter has an advective contribution that depends on water motion, a diffusive contribution, and a source/sink contribution. The source/sink contribution represents the greatest uncertainty in water-related studies.