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This book is an authoritative and comprehensive account of the principles and practice of NMR spectroscopy of solids as applied to polymeric materials to determine their structure and dynamics at a molecular level. NMR spectroscopy has been applied to the characterization of polymers in solid state for over 40 years. The past few decades have seen the development of many new NMR capabilities, including high-resolution techniques for solids, multi-dimensional methods, deuterium NMR and others. All of these developments have contributed to a dramatic increase in the power and applicability of NMR for the characterization, at a molecular level, of the dynamics and structural organization of polymeric solids. The applications chapters emphasize the polymer types and properties. The authors have included an introduction to all the main principles of the technique involved in its application to solid polymers. Rigorous and detailed analytical treatment of all main areas is also available.
This is the first book presenting a coherent theoretical and experimental treatment of the rapidly developing field of macroscopic quantum tunneling of the magnetic moment. The theory is based on the concept of the magnetic instanton and its renormalization by the dissipative environment. The book includes discussions of the tunneling of magnetic moment in small ferromagnetic grains, tunneling of the Ne'el vector in antiferromagnetic grains, quantum nucleation of magnetic domains, and quantum depinning of domain walls. The experimental part collects the majority of recent data that are, or may be, relevant to spin tunneling. Among the topics described are low temperature magnetic relaxation and its interpretation in various systems, experiments on single particles and mesoscopic wires, and resonant spin tunneling in molecular magnets. This study of an important new field in condensed matter physics by two leading contributors to the subject will be of interest to theorists and experimentalists alike.
This book provides an assessment of the unique contribution Mössbauer spectroscopy can make to the study of the bonding, structural, magnetic, dynamical and time-dependent properties of various systems. It comprises an edited collection of chapters by an international body of distinguished scientists writing on their individual areas of specialisation. The editors and authors aim to give the reader an in-depth understanding of the technique of Mössbauer spectroscopy in terms of the types of information it can provide, together with an appreciation of how this information can be related to that obtained from complementary techniques. This book will be of value to postgraduate students and research workers with no previous knowledge of the technique, but also to those experienced in the use of Mössbauer spectroscopy in a particular area wishing to gain either a wider overview of the technique or information about its use in another area.
This 1997 book describes advances in the field of superplasticity. This is the ability of certain materials to undergo very large tensile strains, a phenomenon that has increasing commercial applications, but also presents a fascinating scientific challenge in attempts to understand the physical mechanisms that underpin it. The authors emphasise the materials aspects of superplasticity. They begin with a brief history of the phenomenon. This is followed by a description of the two major types of superplasticity - fine-structure and internal-stress superplasticity - together with a discussion of their operative mechanisms. In addition, microstructural factors controlling the ductility and fracture in superplastic materials are presented. The observations of superplasticity in metals (including aluminium, magnesium, iron, titanium and nickel), ceramics (including monoliths and composites), intermetallics (including iron, nickel, and titanium base), and laminates are thoroughly described. The technological and commercial applications of superplastic forming and diffusion bonding are presented and examples given.
This 1997 book is an introduction to the application of computer simulation and theory in the study of the interaction of energetic particles (< 1 eV to the MeV range) with solid surfaces. The authors describe methods which are applicable both to hard collisions between nuclear cores of atoms down to soft interactions, where chemical effects or long-range forces dominate. In surface science, potential applications include surface atomic structure determination using ion scattering spectroscopy or element analysis using SIMS or other techniques that involve depth profiling. Industrial applications include optical or hard coating deposition, ion implantation in semiconductor device manufacture or nanotechnology. Plasma-sidewall interaction in fusion devices may also be studied using the techniques described. This book will be of interest to graduate students and researchers, both academic and industrial, in surface science, semiconductor engineering, thin-film deposition and particle-surface interactions, in departments of physics, chemistry and electrical engineering.
This book is about the processing, microstructure and properties of materials in fibrous form. The range of fibrous materials covered spans natural polymeric fibres such as silk, synthetic polymeric fibres such as aramid and polyethylene, metallic fibres such as steel and tungsten, and ceramic fibres such as alumina and silicon carbide. The author explains the fundamentals in a clear and concise manner and describes important advances in the production and control of microstructure in high stiffness and high strength fibres. The text contains large numbers of diagrams and micrographs to bring home to the reader the important principles and concepts. The book will be of value to senior undergraduates, beginning graduate students and researchers in the fields of materials science and engineering, metallurgy, ceramics, textile physics and engineering, mechanical engineering and chemical engineering.
This book focuses on the theory of phonon interactions in nanoscale structures with particular emphasis on modern electronic and optoelectronic devices. The continuing progress in the fabrication of semiconductor nanostructures with lower dimensional features has led to devices with enhanced functionality and even novel devices with new operating principles. The critical role of phonon effects in such semiconductor devices is well known. There is therefore a great need for a greater awareness and understanding of confined phonon effects. A key goal of this book is to describe tractable models of confined phonons and how these are applied to calculations of basic properties and phenomena of semiconductor heterostructures. The level of presentation is appropriate for undergraduate and graduate students in physics and engineering with some background in quantum mechanics and solid state physics or devices. A basic understanding of electromagnetism and classical acoustics is assumed.
This book provides an in-depth treatment of the instrumentation, physical bases and applications of X-ray photoelectron spectroscopy (XPS) and static secondary ion mass spectroscopy (SSIMS) with a specific focus on the subject of polymeric materials. XPS and SSIMS are widely accepted as the two most powerful techniques for polymer surface chemical analysis, particularly in the context of industrial research and problem solving. In this book, the techniques of XPS and SSIMS are described and in each case the author explains what type of information may be obtained. The book also includes details of case studies emphasising the complementary and joint application of XPS and SSIMS in the investigation of polymer surface structure and its relationship to the properties of the material. This book will be of value to academic and industrial researchers interested in polymer surfaces and surface analysis.
This book, based on lectures given at the Polytechnic of Milan, gives a broad overview of the field of polymer dynamics. In these lectures the aim is to stress the fundamental concepts of the behaviour of polymers without drawing on the more advanced mathematical formalism which often obscures the natural elegance of the subject matter. Professor De Gennes is one of the most distinguished workers in the field of material science. Therefore this book will be welcomed by both the experienced researcher in the area and the interested layman. It will be of particular value to graduate students.
The discovery of Bose–Einstein condensation (BEC) in trapped ultracold atomic gases in 1995 has led to an explosion of theoretical and experimental research on the properties of Bose-condensed dilute gases. The first treatment of BEC at finite temperatures, this book presents a thorough account of the theory of two-component dynamics and nonequilibrium behaviour in superfluid Bose gases. It uses a simplified microscopic model to give a clear, explicit account of collective modes in both the collisionless and collision-dominated regions. Major topics such as kinetic equations, local equilibrium and two-fluid hydrodynamics are introduced at an elementary level. Explicit predictions are worked out and linked to experiments. Providing a platform for future experimental and theoretical studies on the finite temperature dynamics of trapped Bose gases, this book is ideal for researchers and graduate students in ultracold atom physics, atomic, molecular and optical physics and condensed matter physics.
This book provides an introduction to nonequilibrium statistical physics via lattice models. Beginning with an introduction to the basic driven lattice gas, the early chapters discuss the relevance of this lattice model to certain natural phenomena and examine simulation results in detail. Several possible theoretical approaches to the driven lattice gas are presented. In the next two chapters, absorbing-state transitions are discussed in detail. The later chapters examine a variety of systems subject to dynamic disorder before returning to look at the more surprising effects of multiparticle rules, nonunique absorbing-states and conservation laws. Examples are given throughout the book, the emphasis being on using simple representations of nature to describe ordering in real systems. The use of methods such as mean-field theory, Monte Carlo simulation, and the concept of universality to study and interpret these models is described. Detailed references are included.
This 1996 book summarises the state of knowledge on the microscopic behaviour of oxide surfaces. The first chapter of the book summarises classical approaches, introduces the concept of ionicity, and describes the mixed iono-covalent character of the oxygen cation bond in bulk materials. The next three chapters focus on the characteristics of the atomic structure (relaxation, rumpling and reconstruction effects), the electronic structure (band width, gap width, etc.) and the excitations of clean surfaces. Metal-oxide interfaces are considered in the fourth chapter with special emphasis on the microscopic interfacial interactions responsible for adhesion. The last chapter develops the concepts underlying acid-base reactions on oxide surfaces, which are used in catalysis, in adhesion science, and in colloid physics, and discusses their applicability to the adsorption of hydroxyl groups. A comprehensive list of references is included.
This book is concerned with the underlying science and design of laser materials. It emphasizes the principles of crystal–field engineering and discusses the basic physical concepts that determine laser gain and nonlinear frequency conversion in optical crystals. A concise review of the essential underlying science is presented, and the predictive capabilities of crystal-field engineering are developed to show how modification of the symmetry and composition of optical centres can improve laser performance. Applications of the principles of crystal-field engineering to a variety of optical crystals are also discussed in relation to the performances of laser devices. This book will be of considerable interest to physical, chemical and material scientists and to engineers involved in the science and technology of solid state lasers. It will be used by senior undergraduate and postgraduate students as well as by established scientists.
This volume gives an up-to-date, systematic account of the microscopic theory of Bose-condensed fluids developed since the late 1950s. In contrast to the usual phenomenological discussions of superfluid 4He, the present treatment is built on the pivotal role of the Bose broken symmetry and a Bose condensate. The many-body formalism is developed, with emphasis on the one- and two-particle Green's functions and their relation to the density response function. These are all coupled together by the Bose broken symmetry, which provides the basis for understanding the elementary excitations and response functions in the hydrodynamic and collisionless regions. It also explains the difference between excitations in the superfluid and normal phases. Chapter 4 gives the first critical assessment of the experimental evidence for a Bose condensate in liquid 4He, based on high-momentum neutron scattering data.
The text is a self-contained, comprehensive introduction to the theory of hydrodynamic lattice gases. Lattice-gas cellular automata are discrete models of fluids. Identical particles hop from site to site on a regular lattice, obeying simple conservative scattering rules when they collide. Remarkably, at a scale larger than the lattice spacing, these discrete models simulate the Navier-Stokes equations of fluid mechanics. This book addresses three important aspects of lattice gases. First, it shows how such simple idealised microscopic dynamics give rise to isotropic macroscopic hydrodynamics. Second, it details how the simplicity of the lattice gas provides for equally simple models of fluid phase separation, hydrodynamic interfaces, and multiphase flow. Lastly, it illustrates how lattice-gas models and related lattice-Boltzmann methods have been used to solve problems in applications as diverse as flow through porous media, phase separation, and interface dynamics. Many exercises and references are included.
The behaviour of magnetic impurities in metals has posed problems to challenge the condensed matter theorist over the past 30 years. This book deals with the concepts and techniques which have been developed to meet this challenge, and with their application to the interpretation of experiments. This book will be of interest to condensed matter physicists, particularly those interested in strong correlation problems. The detailed discussions of advanced many-body techniques should make it of interest to theoretical physicists in general.
This book is devoted to the main aspects of the physics of recombination in semiconductors. It is the first book to deal exclusively and comprehensively with the subject, and as such is a self-contained volume, introducing the concepts and mechanisms of recombination from a fundamental point of view. Professor Landsberg is an internationally acknowledged expert in this field, and while not neglecting the occasional historical insights, he takes the reader to the frontiers of current research. Following initial chapters on semiconductor statistics and recombination statistics, the text moves on to examine the main recombination mechanisms: Auger effects, impact ionisation, radiative recombination, defect and multiphonon recombination. The final chapter deals with the topical subject of quantum wells and low-dimensional structures. Altogether the book covers a remarkably wide area of semiconductor physics. The book will be of importance to physicists, electronic engineers and applied mathematicians who are studying or researching the physics and applications of semiconductors. Some parts of the book will be accessible to final-year undergraduates.
This book describes the various methods currently used to deposit highly ordered organic films, and the physical techniques employed in characterising their properties. Such films are the subject of a great deal of research, motivated by their potential application in micro-electronics. Beginning with a discussion of the necessary basic physics and chemistry, the book proceeds to a description of the main topics of current research in this field. The Langmuir–Blodgett technique, self-assembly, and methods of film deposition exploiting the ordered structure of mesophases are described in detail. Liquid crystals, films at the air/water interface and biomembranes are also discussed. The book is aimed at those graduate students and established research workers with an interest in the physics and chemistry of these fascinating structures.
Nonlinear transport phenomena are an increasingly important aspect of modern semiconductor research. Nonlinear Spatio-Temporal Dynamics and Chaos in Semiconductors deals with complex nonlinear dynamics, pattern formation, and chaotic behaviour in such systems. In doing so it bridges the gap between two well-established fields: the theory of dynamic systems, and nonlinear charge transport in semiconductors. This unified approach is used to consider important electronic transport instabilities. The initial chapters lay a general framework for the theoretical description of nonlinear self-organized spatio-temporal patterns, like current filaments, field domains, fronts, and analysis of their stability. Later chapters consider important model systems in detail: impact ionization induced impurity breakdown, Hall instabilities, superlattices, and low-dimensional structures. State-of-the-art results include chaos control, spatio-temporal chaos, multistability, pattern selection, activator-inhibitor kinetics, and global coupling, linking fundamental issues to electronic device applications. This book will be of great value to semiconductor physicists and nonlinear scientists alike.
Historically physics was first known as ‘natural philosophy’ and research was carried out by purely theoretical (or philosophical) investigation. True progress was obviously limited by the lack of real knowledge of whether or not a given theory really applied to nature. Eventually experimental investigation became an accepted form of research although it was always limited by the physicist's ability to prepare a sample for study or to devise techniques to probe for the desired properties. With the advent of computers it became possible to carry out simulations of models which were intractable using ‘classical’ theoretical techniques. In many cases computers have, for the first time in history, enabled physicists not only to invent new models for various aspects of nature but also to solve those same models without substantial simplification. In recent years computer power has increased quite dramatically, with access to computers becoming both easier and more common (e.g. with personal computers and workstations), and computer simulation methods have also been steadily refined. As a result computer simulations have become another way of doing physics research. They provide another perspective; in some cases simulations provide a theoretical basis for understanding experimental results, and in other instances simulations provide ‘experimental’ data with which theory may be compared. There are numerous situations in which direct comparison between analytical theory and experiment is inconclusive. For example, the theory of phase transitions in condensed matter must begin with the choice of a Hamiltonian, and it is seldom clear to what extent a particular model actually represents real material on which experiments are done.