For
$r\geq 3$ and
$g= \frac {r(r+1)}{2}$, we study the Prym-Brill-Noether variety
$V^r(C,\eta )$ associated to Prym curves
$[C,\eta ]$. The locus
$\mathcal {R}_g^r$ in
$\mathcal {R}_g$ parametrizing Prym curves
$(C, \eta )$ with nonempty
$V^r(C,\eta )$ is a divisor. We compute some key coefficients of the class
$[\overline {\mathcal {R}}_g^r]$ in
$\mathrm {Pic}_{\mathbb {Q}}(\overline {\mathcal {R}}_g)$. Furthermore, we examine a strongly Brill-Noether divisor in
$\overline {\mathcal {M}}_{g-1,2}$: we show its irreducibility and compute some of its coefficients in
$\mathrm {Pic}_{\mathbb {Q}}(\overline {\mathcal {M}}_{g-1,2})$. As a consequence of our results, the moduli space
$\mathcal {R}_{14,2}$ is of general type.