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The General Structure Analysis System (GSAS-II) package provides materials and crystallographic analysis for all types of diffraction data. It was initially made available with very limited capabilities, but over much of the last decade the features have been expanded, so that GSAS-II is now a comprehensive tool for nearly all types of structural and materials characterization studies. The need to provide materials to teach use of GSAS-II, while the software has been undergoing constant revision and expansion, has required new approaches for documentation. This has included providing tutorials, as each major new capability has been added, and context-sensitive help for each section of the program. Comments in the code are also expanded into a software reference guide. Most recently, video versions of more than half of the tutorials were created and others were provided with animated graphics. All GSAS-II documentation is web-based.
Usage of composite materials is ubiquitous in the modern world. While global tonnages are still well below those of steel, they now find a wider range of applications and their value is starting to become comparable to that of steel products. As low weight and energy efficiency become increasingly important, this trend is likely to accelerate. In this chapter, the objective is to identify some of the issues involved in commercial exploitation of composites. This is done by means of case studies drawn from various industrial sectors. The examples cover a range of composite type, engineering complexity, manufacturing route, market size and competitive position relative to more traditional materials.
An important aspect of composite materials concerns the technology by which they are produced. Depending on the nature of matrix and fibre, and the required architecture of fibre distribution, production at reasonable cost and with suitable microstructural quality can present a challenge. In most cases, manufacture of the final component and production of the composite material are carried out at the same time. This gives scope for optimal fibre placement and distribution of orientations, but also requires that the mechanical requirements of the application be well understood and that the processing route be tailored accordingly. Fabrication procedures for most commercially important (fibre-reinforced polymer) composites are technically mature, but there are some types of composite for which processing routes are still under development.
The usage of composite materials continues to expand rapidly. The current world-wide market value is not easy to estimate, but is certainly more than US$100 billion. Composites now constitute one of the broadest and most important classes of engineering materials – second only to steels in industrial significance and range of applications. There are several reasons for this. One is that they often offer highly attractive combinations of stiffness, strength, toughness, lightness and corrosion resistance. Another is that there is considerable scope for tailoring their structure to suit service conditions. This concept is well illustrated by biological materials such as wood, bone, teeth and hide, which are all composites with complex internal structures that have been designed (via evolutionary processes) to give mechanical properties well suited to the performance requirements. This versatility is, of course, attractive for many industrial purposes, although it also leads to complexity that needs to be well understood if they are to be used effectively. In fact, adaptation of manufactured composite structures for different engineering purposes requires input from several branches of science. In this introductory chapter, an overview is given of the types of composites that have been developed.
The previous three chapters cover the elastic behaviour of composites containing aligned fibres that are, in effect, infinitely long. Use of short fibres (or equiaxed particles) creates scope for using a wider range of reinforcements and more versatile processing and forming routes (see Chapter 15). There is thus interest in understanding the distribution of stresses and strains within such composites, and the consequences of this for the stiffness and other mechanical properties. In this chapter, brief outlines are given of two analytical models. In the shear lag treatment, a cylindrical (short fibre) reinforcement is assumed, with stress fields in fibre and matrix being simplified (leading to some straightforward analytical expressions). It introduces important concepts concerning load transfer mechanisms, although it is not very widely used for property prediction. The Eshelby method, on the other hand, is based on the reinforcement being ellipsoidal (anything from a sphere to a cylinder or a plate): the analysis is more rigorous, but with the penalty of greater mathematical complexity. The model is only briefly described here. Its use also introduces an important concept – that of a misfit strain, which is helpful in areas well beyond those of the mechanics of conventional composite materials.
In the previous chapter, it was shown that an aligned composite is usually stiff along the fibre axis, but much more compliant in the transverse directions. Sometimes, this is all that is required. For example, in a slender beam, such as a fishing rod, the loading is often predominantly axial and transverse or shear stiffness are not important. However, there are many applications in which loading is distributed within a plane: these range from panels of various types to cylindrical pressure vessels. Equal stiffness in all directions within a plane can be produced using a planar random assembly of fibres. This is the basis of chopped-strand mat. However, demanding applications require material with higher fibre volume fractions than can readily be achieved in a planar random (or woven) array. The approach adopted is to stack and bond together a sequence of thin ‘plies’ or ‘laminae’, each composed of long fibres aligned in a single direction, into a laminate. It is important to be able to predict how such a construction responds to an applied load. In this chapter, attention is concentrated on the stress distributions that are created and the elastic deformations that result. This involves consideration of how a single lamina deforms on loading at an arbitrary angle to the fibre direction. A summary is given first of some matrix algebra and analysis tools used in elasticity theory.
In the previous chapter, procedures were described that allow prediction of the elastic response of a single lamina when loaded at an arbitrary angle to the fibre axis. It was shown that such uniaxial sheets tend to be highly anisotropic, with much greater stiffness when loaded parallel to the fibres than at significant angles to them. Moreover, other aspects of the elastic response are very different in different directions. For these reasons, it is common to stack laminae into bonded sets (laminates), making the elastic properties (and also the strength) more isotropic, and also opening up the possibility of tailoring the properties of a component to the loads that it will experience in service – potentially a major advantage of composites when compared with more conventional materials. In this chapter, the treatment of individual laminae is extended to the case of a laminate with an arbitrary stacking sequence, supplying an analytical tool of considerable value in the design of composite materials.
The previous chapter covered factors affecting strength, in terms of the stresses at which damage and failure occur in composites. In many situations, however, it is the energy that is absorbed within the material while fracture takes place that is of prime importance. A tough material is one for which large amounts of energy are required to cause fracture. Some loading configurations, such as a component being struck by a projectile, provide only a finite amount of energy that could cause failure. In fact, there are many situations in which toughness, rather than strength, is the key property determining whether the material is suitable. In this chapter, a brief outline is given of the basics of fracture mechanics, with particular reference to the energetics of interfacial damage. This is followed by an appraisal of the sources of energy absorption in composites. Finally, progressive crack growth in composites is examined under conditions for which fast fracture is not energetically favoured (sub-critical crack growth).
Nanoparticle-mediated drug delivery has the potential to overcome several limitations of cancer chemotherapy. Lipid polymer hybrid nanoparticles (LPHNPs) have been demonstrated to exhibit superior cellular delivery efficacy. Hence, doxorubicin (a chemotherapeutic drug)-loaded LPHNPs have been synthesized by three-dimensional (3D)-printed herringbone-patterned multi-inlet vortex mixer. This method offers rapid and efficient mixing of reactants yielding controllable and reproducible synthesis of LPHNPs. The cytotoxicity of LPHNPs is tested using two-dimensional (2D) and 3D microenvironments. Results obtained from 3D cell cultures showed major differences in cytotoxicity in comparison with 2D cultures. These results have broad implications in predicting in vitro LPHNP toxicology.
Pseudo-line tensions are used in a continuum approach to simulate contact angle hysteresis. A pair of pseudo-line tensions in the receding and advancing states, respectively, are utilized to represent contact line interactions with a substrate because of the nanoscale topological and/or chemical heterogeneity on the substrate. A water droplet sitting on a horizontal or inclined substrate, whose volume is 4–30 µL, has been studied experimentally and numerically. Our simulation model predicts consistent hysteresis at four different droplet sizes compared with experiments. Meanwhile, the critical roll-off angles captured in simulations match well with experiments.
The authors carried out matched experiments and molecular dynamics simulations of the compression of nanopillars prepared from Cu|Au nanolaminates with up to 25 nm layer thickness. The stress–strain behaviors obtained from both techniques are in excellent agreement. Variation in the layer thickness reveals an increase in the strength with a decreasing layer thickness. Pillars fail through the formation of shear bands whose nucleation they trace back to the existence of surface flaws. This combined approach demonstrates the crucial role of contact geometry in controlling the deformation mode and suggests that modulus-matched nanolaminates should be able to suppress strain localization while maintaining controllable strength.
Machine learning (ML) has revolutionized disciplines within materials science that have been able to generate sufficiently large datasets to utilize algorithms based on statistical inference, but for many important classes of materials the datasets remain small. However, a rapidly growing number of approaches to embedding domain knowledge of materials systems are reducing data requirements and allowing broader applications of ML. Furthermore, these hybrid approaches improve the interpretability of the predictions, allowing for greater physical insights into the factors that determine material properties. This review introduces a number of these strategies, providing examples of how they were implemented in ML algorithms and discussing the materials systems to which they were applied.
This fully expanded and updated edition provides both scientists and engineers with all the information they need to understand composite materials, covering their underlying science and technological usage. It includes four completely new chapters on surface coatings, highly porous materials, bio-composites and nano-composites, as well as thoroughly revised chapters on fibres and matrices, the design, fabrication and production of composites, mechanical and thermal properties, and industry applications. Extensively expanded referencing engages readers with the latest research and industrial developments in the field, and increased coverage of essential background science makes this a valuable self-contained text. A comprehensive set of homework questions, with model answers available online, explains how calculations associated with the properties of composite materials should be tackled, and educational software accompanying the book is available online. An invaluable text for final-year undergraduates in materials science and engineering, and graduate students and researchers in academia and industry.