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Heat-resistant Al–8.5Fe–1.3V–1.7Si (wt%) aluminum alloy components were fabricated using selective laser melting (SLM). The as-built samples were examined in terms of density, chemical composition, surface morphologies, microstructures, and mechanical behavior. The results show that nearly full dense samples with the relative density of 99.3% can be produced. The chemical composition of the deposited material is close to that of the powder, presenting a limited aluminum loss and a low oxygen pickup. The SLM specimens consist of three typical zones: the fusion zone (FZ), the remelting border zone (RBZ), and the heat-affected zone (HAZ). Ultrafine continuous cellular α-Al networks are observed in the FZ. The HAZ exhibits fine rounded Al12(Fe,V)3Si particles (10–70 nm) distributed homogeneously in the α-Al matrix, while the rectangle-like AlmFe-type phase (m = 4.0–4.4) with 100–500 nm in size is preferably formed in the RBZ. The microhardness of the parts shows directional independent, with a mean value of 246 HV0.1.
Monophasic Sn1−xCoxO2 (x = 0.05, 0.10, and 0.15) nanoparticles with tetragonal structure have been successfully synthesized by solvothermal method using oxalate precursor route. Powder x-ray diffraction and selected area electron diffraction studies confirmed highly crystalline cassiterite SnO2 structure. The contraction of lattice constants confirmed the incorporation of Co2+ in SnO2 host lattice. Hexagonal nanoparticles with average grain size of 8–13 nm have been formed. With the increasing Co content, the decreasing crystallite size of SnO2 with increasing surface areas from 194 to 219 m2/g was found. The percentage reflectance increases on increasing the cobalt concentration, and a noticeable blue shift appeared. The band gap was found to be 3.85, 3.91, and 4.09 eV, respectively. Co-doped SnO2 showed distinct magnetic behavior with different Co2+ concentration. For x = 0.05 and 0.10, nanoparticles showed paramagnetism with antiferromagnetic interaction, however, on further increasing x = 0.15, the nanoparticles showed canted antiferromagnetic coupling.
Hydrochlorothiazide (HCTZ) is a diuretic used for the treatment of blood pressure (hypertension). HCTZ has two anhydrous polymorphs denoted as Forms I and II. Aiming at solid-state characterization, X-ray powder diffraction (XRPD) is known to be a powerful technique which has been successfully applied in investigating polymorphism in medicines. In this work, three tablets of HCTZ (a reference and two generic) were analyzed. The data were collected using Rigaku RINT2000 diffractometer copper rotate anode. The Rietveld method (RM) was applied for the characterization of HCTZ polymorphic form. For the crystalline excipients where the crystal structure is known, their phases were identified by the RM either. The results showed that all the tablets exhibit Form I of HCTZ, while the excipient lactose monohydrate is found to exhibit the crystalline form. One of the generics is also found to exhibit the excipient sodium lauryl sulfate (SLS) in the crystalline form. Therefore, the RM and XRPD are an efficient methodology for characterization of the crystalline Form I of the active principle of HCTZ and crystalline excipients lactose monohydrate and SLS in solid formulations. It is also interesting to observe excipients not described in the package insert of the medicament.
In the present work, Cu–Al alloys were processed by surface mechanical attrition treatment (SMAT) under both room and liquid nitrogen temperature (LNT) conditions. In contrast to room temperature (RT) SMAT, dynamic recovery and recrystallization were largely suppressed during the LNT process. A gradient microstructure was obtained due to the gradient strain and strain rate impacted onto the sample. Microhardness measurement showed that the hardness values gradually decreased from the top surface to the central region. The local hardness of the top surface layer of the LNT and RT SMAT Cu–4.5% Al samples reached maximum values of 1.52 and 1.28 GPa, respectively. The Cu–4.5% Al alloy exhibited an improved yield strength of ∼496 MPa and a higher ductility (compared with literature data of Cu–Al alloys synthesized traditional severe plastic deformation methods) of 15.4% after the LNT SMAT process. A brittle-ductile failure pattern was easily distinguished after fracture. Moreover, the LNT SMAT is a low-cost process with high productivity and can be applied to various types of metallic production.
Greener technologies for more efficient power generation, distribution, and delivery in sectors ranging from transportation and generic energy supply to telecommunications are quickly expanding in response to the challenge of climate change. Power electronics is at the center of this fast development. As the efficiency and resiliency requirements for such technologies can no longer be met by silicon, the research, development, and industrial implementation of wide bandgap semiconductors such as gallium nitride (GaN) and silicon carbide (SiC) are progressing at an unprecedented pace. This issue of MRS Bulletin, although certainly not exhaustive, provides an overview of the pace and quality of research revolving around GaN and SiC power electronics, from the choice of substrates, film growth, devices, and circuits to examples of applications.
High-temperature electronic applications are presently limited to a maximum operational temperature of 225°C for commercial integrated circuits (ICs) using silicon. One promise of silicon carbide (SiC) is high-temperature operation, although most commercial efforts have targeted high-voltage discrete devices. Depending on the technology choice, several processing challenges are involved in making ICs using SiC. Bipolar, metal oxide semiconductor field-effect transistors, and junction field-effect transistor technologies have been demonstrated in operating temperatures of up to 600°C. Current technology performance and processing challenges relating to making ICs in SiC are reviewed in this article.
Transistors with 600 V blocking capability and low switching losses are needed for converting one-phase 230 V mains voltage to lower voltage levels in switch-mode power supplies. The transistors operate as a switch and have to block the system voltage with minimized leakage currents in the OFF-state and have to conduct the current in the ON-state with minimized ON-state resistance. Additionally, any switching losses inside the transistor during the transitions in-between OFF and ON-states need to be minimized for efficient power-converting systems. Efficient high-voltage switching using gallium nitride (GaN)-based power transistors requires excellent material properties in the GaN/AlGaN epitaxial layers in conjunction with optimized process modules and device layout. In the example presented here, GaN buffer compositions and device geometry have been optimized to obtain very low vertical and lateral OFF-state leakage currents at 600 V drain bias and to enable a fast device turn-on with only a minor increase in dynamic ON-state resistance. The developed technology was applied to GaN layers grown on SiC and Si substrates to allow a direct comparison of both static and dynamic device parameters. By implementing a p-type GaN gate, normally OFF operation was realized for 70 mΩ/600 V transistors on both substrates. The new GaN-based devices outperform established Si-based superjunction metal oxide semiconductor field-effect transistors in terms of gate charge and switching energy.
Innovations in materials for next-generation displays and rechargeable batteries are proposed based on the device technology roadmap. With this future perspective, technical concepts and recent achievements at Samsung Electronics for organic semiconductors, inorganic nanomaterials, and optical film materials for display devices as well as energy storage, conversion, and ion transport materials for rechargeable batteries are described. New materials for future devices such as wearable, stretchable, and sensitivity devices are also discussed.
Energy savings and efficient usage of electric power are some of the most urgent issues for future sustainable development of human society. Power electronics is recognized as a key technology in this regard, and the innovation of power electronics is increasingly required. The important role of power electronics innovations in the future human society and a technology roadmap of power electronics utilizing wide bandgap semiconductors, which are typically represented by silicon carbide, are presented. This roadmap consists of several different domains in technology, from the materials side to the applications side. On this roadmap, three generations are defined as technological streams. Based on this roadmap, recent progress in silicon carbide power electronics is reviewed, and future prospects are discussed.
Recent successes with the fabrication of high-performance GaN-based heterostructures on silicon substrates have made this technology very promising. However, epitaxial growth of GaN on Si is challenging. This article presents some of the challenges of epitaxial growth of GaN-on-Si substrates focusing on basic aspects that are pertinent to consider for power electronics.
The methodologies, results, and status of investigations for the development of solvothermal, vapor-phase transport, and solution techniques for bulk crystal growth of large diameter GaN and AlN crystals are presented. This work is being driven by (1) the anticipated need for the initial homoepitaxy of ever-thicker GaN films having very low densities of both threading dislocations and unintentionally introduced, electronically important impurities for devices operating at high and very high load levels; (2) the desire to move from lateral to vertical device structures; and (3) recent results of near theoretical breakdown behavior and near system-level performance in vertical GaN diodes grown on GaN substrates. The choice of the substrate dictates the technique and process routes for the growth of Group III-nitride-based thin films and material device structures. Organometallic vapor-phase epitaxy is the commercial process route of choice for the growth of Group III-nitride films. A review of the precursor gases used in this technique, their stability in the growth reactor and reactivity with nitrogen-containing gases, and the choice of diluent for the growth of films of different nitrides is also presented.
This article reviews the development of SiC and GaN devices for power-switching applications in the context of four specifically identified application requirements: (1) high-blocking voltage, (2) high-power efficiency, (3) high-switching speed, and (4) normally OFF operation. Specific device and material characteristics, such as ON resistance, parasitic capacitances, and energy-gap values, are compared and discussed in relation to the identified application requirements. Following a review of the fundamental limitations of silicon as a material, this article describes the material advantages that motivated the development of commercially available Schottky diodes and transistors using SiC. The last section analyzes the potential of GaN to enable further technical progress beyond the theoretical limit of Si and to significantly reduce the cost of power-electronic switches.