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The colonial ascidian Didemnum vexillum (Carpet Sea Squirt) is globally established as a non-native species with diverse negative impacts. A second Didemnum species, D. pseudovexillum, was described in 2020, living alongside D. vexillum and virtually indistinguishable from it in external appearance. It is not known whether this second species has environmental and economic impacts similar to those of D. vexillum, nor whether it should be regarded as native or non-native in Europe. Early records were from four sites, all in or adjacent to marinas, in north-west France, the Mediterranean coast of Spain and the east coast of Italy. Here, an occurrence of D. pseudovexillum in a seagrass bed in south-west England is reported, identified by both sequencing of the cytochrome c oxidase subunit 1 gene (COI) and examination of internal morphology. Separate studies collected and identified specimens of D. vexillum/pseudovexillum from 11 marinas on the English and Welsh coasts, and D. pseudovexillum was not found amongst these. Only two pre-2020 didemnid COI sequences now referrable to D. pseudovexillum have been found in the BOLD System and GenBank databases (these records being from Mediterranean Spain in 2013); this suggests that the species is a relatively recent addition to the European fauna from an unrecognized existing range.
For the first time, an analytical solution has been derived for Stokes flow through a conical diffuser under the condition of partial slip. Recurrent relations are obtained that allow determination of the velocity, pressure and stream function for a certain slip length λ. The solution is analysed in the first order of decomposition with respect to a small dimensionless parameter ${\lambda }/{r}$. It is shown that the sliding of the liquid over the surface of the cone leads to a vorticity of the flow. At zero slip length, we obtain the well-known solution to the problem of a diffuser with a no-slip boundary condition corresponding to strictly radial streamlines. To solve that problem, we use an alternative form of the general solution of the linearised, stationary, axisymmetric Navier–Stokes equations for an incompressible fluid in spherical coordinates. A previously published solution to this problem, dating back to the paper by Sampson (1891 Phil. Trans. R. Soc. A, vol. 182, pp. 449–518), is given in terms of a stream function that leads to formulae that are difficult to apply in practice. By contrast, the new general solution is derived in the vector potential representation and is simpler to apply.
The study of Ordovician ostracods from eastern North America has been neglected for more than 40 years, prompting the need for taxonomic updates. Newly acquired silicified materials from the Late Ordovician Crown Point Formation of Valcour Island, northeastern New York State, are here systematically described. Fifty-two species of 42 genera are identified, including three new species: Vogdesella longidorsa n. sp., Eokloedenella duodepressa n. sp. and Aviacypris valcourensis n. sp. The combination of high diversity and dominance of both beyrichiocopids and podocopids indicates that the Valcour fauna existed in a stable, shallow-water carbonate environment. Biostratigraphical evidence supports an early Sandbian age designation for the Crown Point Formation. Comparison of the Valcour fauna with others in Laurentia as well as from adjacent paleocontinents shows shared composition at the genus level, especially with Baltica, but high endemicity at the species level. This suggests a history of frequent faunal exchange with a fast speciation rate during the early Late Ordovician in the southern region of Laurentia.
Here, we present a first assessment of the US Department of Agriculture’s (USDA) “Grass-Cast Southwest,” which is a forecasting tool for rangeland aboveground net primary productivity (ANPP) for the southwest region of the United States. Our results show that ANPP forecasts in early April were relatively close to the observation-based ANPP estimates in late May for all years evaluated (R = 0.6–0.9). The relatively high predictability of spring rangeland productivity in this region is likely because it is strongly driven by antecedent winter/early spring precipitation. Conversely, the first summer forecasts produced in June did not consistently predict the final observation-based ANPP estimates in late August (R = −0.5–0.7), likely because summer rangeland productivity in this region is highly dependent on variable, less predictable precipitation from the North American Monsoon (NAM). Antecedent El Niño Southern Oscillation (ENSO) indices could be used to improve Grass-Cast Southwest performance in both the spring and summer. The ENSOJFM (January–March) index was significantly positively correlated with rangeland productivity during the spring season, whereas ENSOMAM (March–May) was significantly negatively correlated with rangeland productivity during the summer season.
The stability of underwater bubbles is important to many natural phenomena and industrial applications. Since stability analyses are complex and influenced by numerous factors, they are often performed on a case-specific basis, with most being qualitative. In this work, we propose a unified and quantitative criterion for evaluating bubble stability by analysing its free energy. This criterion is broadly applicable across various bubble sizes (from nanometres to macroscale) and contact conditions (suspended, attached and trapped bubbles) on surfaces with diverse chemical (hydrophilic and hydrophobic) and morphological (flat and structured solid surfaces) features. This criterion not only applies to the classical stable bubble mode, which depends on contact line pinning at the tips of surface structures, but also predicts a new mode where the synergy between the geometry and wettability of the sidewalls maintains the bubble’s stable state. The contact line can spontaneously adjust its position on the solid surface to maintain pressure balance, which enhances bubble adaptability to environmental changes. A geometric standard for solid surfaces supporting this new stable state is raised, following which we realise the optimisation of solid surface geometries to control the stability of gas bubbles. This work not only provides a universal framework for understanding underwater bubble stability, but also opens avenues for applications.
The actuator line model (ALM) is an approach commonly used to represent lifting and dragging devices like wings and blades in large-eddy simulations (LES). The crux of the ALM is the projection of the actuator point forces onto the LES grid by means of a Gaussian regularisation kernel. The minimum width of the kernel is constrained by the grid size; however, for most practical applications like LES of wind turbines, this value is an order of magnitude larger than the optimal value that maximises accuracy. This discrepancy motivated the development of corrections for the actuator line, which, however, neglect the effect of unsteady spanwise shed vorticity. In this work we develop a model for the impact of spanwise shed vorticity on the unsteady loading of an aerofoil modelled as a Gaussian body force distribution, where the model is applicable within the regime of unsteady attached flow. The model solution is derived both in the time and frequency domain and features an explicit dependence on the Gaussian kernel width. We verify the model with ALM-LES for both pitch steps and periodic pitching. The model solution is compared withTheodorsen theory and validated with both computational fluid dynamics using body fitted grids and experiment. It is concluded that the optimal kernel width for unsteady aerodynamics is approximately $40\,\%$ of the chord. The ALM is able to predict the magnitude of the unsteady loading up to a reduced frequency of $k\approx 0.2$.
We report experiments in a long tank showing that transverse Benjamin–Feir instability of Stokes waves can lead to a significant energy transfer into oscillations across the tank. We observe frequency downshift in the long-term evolution of Stokes waves essentially when significant energy is transferred to narrow-banded transverse modes. Experiments with Stokes waves are often carried out with wavelengths that are not long compared with the width of the tank, permitting transverse instabilities to be excited. With insufficient resolution of measurements across the tank, transfer of energy to transverse modes can be misinterpreted as dissipation. Our experiments suggest that the frequency downshift depends as much on energy-preserving transverse modulations of type I as it does on damping or wave breaking. Broad-banded unstable modulations of type II do not imply downshift.
Lead contamination in water poses serious risks to ecosystems and human health, highlighting the need for low-cost and efficient treatment technologies. In this study, natural attapulgite clay was thermally treated at various temperatures to improve its capacity for removing lead ions from aqueous solutions. The adsorbent prepared at 400°C exhibited the best performance, with a maximum adsorption capacity of 32.63 mg g–1. Characterization results indicated that while heating caused partial changes in the crystal structure, the nanorod morphology and key structural features of attapulgite were largely preserved. The enhanced adsorption ability was attributed to an increase in surface reactivity and greater accessibility of active functional groups. These findings demonstrate a simple and effective modification route that broadens the potential use of attapulgite for heavy-metal wastewater treatment.
We present a Late Pleistocene paleoecological record from King Island in western Bass Strait, Tasmania, and compare this to existing records from the eastern Bass Strait islands to improve our understanding of the region’s paleoecology and paleoclimatology. Vegetation change across the region followed similar trajectories during the late glacial–Middle Holocene, characterized by homogeneous warming and wetting trends. Spatial divergence occurred during the Middle Holocene when sea level rose, and different drivers began influencing western and eastern Bass Strait islands. In eastern Bass Strait, Middle Holocene sea-level rise caused replacement of woodland by coastal heathland, while in the west, a drier period accompanied by fires transformed forests to forest–scrub. The comparative analysis suggests that Westerly driven climatic anti-phasing was pronounced at higher latitudes of Tasmania during the late glacial–Early Holocene. A combination of weak Leeuwin Current, positive Indian Ocean Dipole (IOD), and El Niño–Southern Oscillation (ENSO) intensification contributed to Middle Holocene aridity across Bass Strait. Strong Westerlies and negative IOD phases led to greater regionalization of rainfall across western Bass Strait during the Late Holocene, while ENSO intensification drove rainfall declines in eastern Bass Strait. These findings provide new insights into the complexity of Late Pleistocene environmental dynamics across southeast Australia.
Near-surface ice layers in the lower accumulation zone of Arctic glaciers and ice sheets may significantly affect deep meltwater percolation and runoff availability. This study presents a framework to assess three methods for characterizing near-surface ice layer permeability and its influence on runoff and mass balance on the Devon Ice Cap using field data. In the most effective method, ice layer permeability depends on temperature and thickness: they remain permeable above a threshold temperature (Tth = −0.15°C) and become impermeable once exceed a critical thickness (Himp = 1 m). Our modelling replicates ice layers that are typically thinner in the upper accumulation zone and thicker in the lower accumulation zone. Additionally, we simulate an observed increase in the number of ice layers in the upper accumulation zone after 2007. The evolution of thicker (>1 m) ice layers (or ice slab) in the lower accumulation zone reduces meltwater retention through refreezing, making surface mass balance (SMB) and runoff sensitive to climate changes. Simulated mean SMB ranged from −0.09 to 0.26 m w.e. a−1 from 1999 to 2022. Our model can be applied to simulate the long-term evolution of ice slab and project its impact on ice sheet runoff.
Dry permafrost underlain by ice-cemented permafrost has been reported in several locations in Antarctica. Initially thought to be relic ice, it is now understood that this subsurface ice is in equilibrium with the surface conditions, although it is not in equilibrium with the atmosphere. We use year-round data from University Valley in the Dry Valleys and Elephant Head in the Ellsworth Mountains to investigate the seasonal variations in water vapour flux that control the depth to the ice table under dry permafrost. Our analysis shows that the mean annual water vapour density of the soil surface exceeds the atmospheric value by a factor of up to ~2 due to summer snow. The attenuation and phase shift of the annual temperature cycle with depth result in colder temperatures at the ice table than at the surface of the soil in summer. We conclude that this temperature gradient, combined with the summer snow, provides the flux of water to the ice table necessary to maintain the ice. In University Valley, reducing the snow days by 40% moves the stability depth of the ice table from 42 to 66 cm. Increasing the snow days by 60% shifts the ice table to 17 cm. These variations can explain the observed gradient in the depth to the ice table in University Valley.
To date, published studies have proven that the reactions at the iron/bentonite interface are complex and only partly understood. In the present study, mixtures of bentonite powder and iron powder were prepared, which allowed for varying individual parameters. The results confirmed some controversial previously reported conclusions and revealed new findings. More specifically, Na-exchanged samples showed a reduced extent of corrosion compared to Ca/Mg-exchanged ones, and the addition of reactive silica increased the extent of corrosion, which has not been reported to date. The negative temperature effect (less corrosion at higher temperatures), which was reported previously, could only be confirmed for Ca/Mg-bentonites. One Na-bentonite showed the opposite effect, but this sample also contained reactive silica in contrast to the others. The present study proves for the first time that the type of exchangeable cation can affect the type of corrosion product, which could be an explanation for why the 7 Å corrosion product was not reported in all corrosion tests (sometimes only magnetite was reported). In addition, experiments that ran for 36 months showed that the corrosion progress of six different bentonites was different. Three bentonite/iron mixtures did not show progress in corrosion after 12 months, whereas the other three showed ongoing corrosion. Using the former three bentonite/iron mixtures would significantly increase high-level radioactive waste canister lifetime, but future work should be devoted to the identification of the reason for this differing long-term performance, differing thermal behaviour and differing corrosion products resulting from different types of exchangeable cation.
Tropical Andean glaciers provide an important flux of freshwater to communities living both in high-altitude Cordillera and population centres downstream in countries such as Peru and Bolivia. Glacier recession threatens the sustainability of these water resources, and accurate modelling of future glacier behaviour is required to manage water stress in the region. These models must capture all processes contributing significantly to overall glacier mass budgets. Here we examine supraglacial pond and ice cliff development on three clean-ice glaciers in the Cordillera Vilcanota, Peru and their overall contribution to glacier mass balance. Whilst such features are common and well-studied on debris-covered glaciers, their development on debris-free glaciers has not been examined in detail. We use high-resolution contemporary and historical satellite imagery and repeat drone surveys to examine surface structure and geometry change over three glaciers during 1977–2024. We show how cliff and pond formation is driven by aspect-dependent surface melt of crevasse walls. These features act as ice loss hotspots, which enhance glacier net mass loss by ∼10% despite accounting for <5% glacier surface area. Incorporation of such amplified ice loss processes should be a priority for glacier model advances to achieve more accurate projections of future tropical glacier recession.
Patagonia and Tierra del Fuego (Austral Andes) are the most glacierised regions in the Southern Hemisphere, where glaciers have experienced significant mass changes in recent decades. Understanding glacier–climate–water interactions is crucial for addressing future climate challenges. Open-access data play a key role in advancing geoscience research, improving models and assessing the impacts of hazards and sea-level rise impacts. Here, we present QFuego-Patagonia, a free glacier-related GIS dataset and web portal covering Patagonia and Tierra del Fuego, which provides essential geospatial information across four scientific topics: Glaciology, Atmosphere, Terrain Models, and Glacial Geology and Geomorphology. This initiative aims to foster interdisciplinary research and collaboration, synthesise current knowledge and establish an advanced glacier data repository that will be continuously updated as new data and insights become available.
Reproductive synchrony is common in populations that inhabit seasonal environments where reproductive timing is important to offspring survival. Weddell seals (Leptonychotes weddellii) reproduce in strongly seasonal Antarctic environments and are known to exhibit reproductive synchrony that varies by latitude, whereby more southerly populations give birth later. The Erebus Bay population of Weddell seals is the southernmost mammal population in the world, and birth-date synchrony has been demonstrated in this population. Various life history correlates including sex, maternal age and reproductive status have been identified as predictors of birth timing, but all prior work has been done on pups born to locally born mothers. Immigrant females originating from unknown sites in more northerly locations also produce pups in Erebus Bay and may have different birth timing due to the earlier average birth dates in their natal colonies. Using 22 years of capture-mark-recapture data for Weddell seals in Erebus Bay, we aimed to assess whether the timing of birth dates for pups born to immigrant mothers differs from that of pups born to locally born mothers. To our knowledge, this is the first time that such a comparison has been studied in a wild population. Birth dates were examined using Bayesian linear regression. We analysed birth dates from 7539 pups (4932 from locally born mothers, 2607 from immigrant mothers) born to 2210 mothers (1254 locally born, 956 immigrant) and found that there were no biologically impactful differences in the birth dates of pups born to locally born or immigrant mothers. Additionally, birth-date patterns for immigrant mothers were similar to those for locally born mothers with respect to various traits. Our results demonstrate that immigrant Weddell seal mothers can synchronize birth timing with locally born mothers. More research is required to understand the underlying mechanisms that allow for immigrant seals to achieve birth-date synchrony.
Magnets have been utilised widely for their ability to induce rapid contact – such as snapping between magnets and ferromagnetic materials. Yet, how such interactions proceed under immersion in a viscous fluid remains poorly understood. Here, we study this problem using the classical configuration of a smooth solid sphere approaching a plane in a quiescent fluid. Induced magnetic attraction, a spatially varying force analogous to short-range dispersion forces, offers a plausible route to overcome the constraint of a diverging hydrodynamic drag, which is well understood using the framework of classical lubrication theory. Instinctively, one might expect it to enable finite-time contact. However, our experiments reveal a counterintuitive result: while magnetic forces accelerate the sphere towards the surface, reducing the approach time by two orders of magnitude compared with gravity, they ultimately fail to effectuate contact in finite time, as induced magnetic interactions are unable to mitigate lubrication drag, which is singular at the thin gap limit, and transitions to an exponential descent characteristic of constant forcing. We support these findings with a simple theoretical model that accurately predicts the magnetic force law from purely kinematic observations. Finally, we outline the conditions under which spatially varying forces can enable true finite-time contact and discuss future experimental directions.