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Silicon integrated circuits (ICs) are pervasive in our world, and the global semiconductor industry today exceeds $500 billion in annual sales. The devices and chips this industry produces support global industries, including consumer electronics, transportation, avionics and many others, that collectively represent a major part of global markets. Devices and chips built with other semiconductor materials such as GaAs, SiC and GaN provide critical components for specific application areas, including high-frequency communications systems, solid-state lighting and power management. It is not incorrect to say that the technical foundation of our modern world is based on semiconductors. The critical role that chips play has led to global competition to design, fabricate and build into advanced systems these remarkable components. Their importance to our world is unlikely to change in the foreseeable future.
In this chapter, we discuss the fabrication of a modern complementary metal-oxide–semiconductor (CMOS) integrated circuit using the individual process steps that are combined in a complete process flow sequence to make the chips. Such an ordered process flow from the sandbox of tools available in different combinations would be used to make any kind of device, such as a biosensor, a microfluidic device or a micro-electromechanical systems (MEMS) device. The wafer’s past history and the future process steps can greatly influence how one chooses to order the individual steps. For example, high-temperature steps at the end of a process could disturb delicate doping profiles introduced early in the process. For this reason, we believe it is worth understanding the choices made in assembling a modern CMOS process flow. Seeing the “big picture” of a complete process flow should also help to put the individual process steps we discuss in subsequent chapters into perspective.
One of the main challenges in designing a front-end process for building a device is accurate control of the placement of the active doping regions. Understanding and controlling diffusion and annealing behavior are essential to obtaining the desired electrical characteristics. Consider a cross-section of a state-of-the-art MOS transistor and imagine what happens when it gets scaled down to smaller dimensions (Figure 7.1). In “ideal” or Dennard scaling, as described in Chapter 1, everything shrinks down linearly from one generation to the next. This means that not only do the lateral dimensions scale, but the vertical dimensions, such as the deep source/drain contacting junctions and the shallower tip or extension junctions, also scale. This maintains the same electric field patterns (assuming the operating voltage also scales proportionally). With the same ℰ-field patterns, the device operates in the same manner as before, except that the shorter channel length allows for faster switching speeds [1].
Ion implantation has been the dominant doping technique for silicon integrated circuits (ICs) and most other semiconductors for the past 45 years. It is expected to retain this position of dominance for the foreseeable future. In this process, dopant ions are accelerated to 0.1–1000 keV of energy and smashed into a crystalline semiconductor substrate, creating a cascade of damage that may displace hundreds or thousands of lattice atoms for each implanted ion. In this chapter, we will seek to understand how such an energetic and violent technique has become the dominant and preferred method of doping semiconductor wafers in manufacturing. At first glance, it seems that the technique would not be of much use in the precise art of fabricating integrated circuits. Indeed, although the original patent for ion implantation was issued to William Shockley in 1954, it was not until the late 1970s that ion implantation was used in manufacturing.
If workers from one of today’s multi-billion-dollar integrated circuit (IC) manufacturing plants were suddenly transported to a 1960s semiconductor plant, they would likely be amazed that chips could be successfully manufactured in such a place. Such factories were “dirty” by today’s standards, and wafer cleaning procedures were poorly understood. Of course, chips were manufacturable even in those days, but they were very small and contained very few components by today’s standards. Since defects on a chip tend to reduce yields (fraction of good chips on a wafer) exponentially as chip size increases, small chips can be manufactured with a yield greater than zero even in quite dirty environments. However, all of the progress that has been made in the past six decades in shrinking device sizes and designing very complex chips would have been for naught if similar advances had not been made in manufacturing capability, especially in defect density.
The crystal structure of L-5-methyltetrahydrofolate calcium trihydrate has been solved and refined using synchrotron X-ray powder diffraction data and optimized using density functional techniques. Calcium levomefolate trihydrate crystallizes in space group P212121 (#19) with a = 7.1706(6), b = 6.5371(5), c = 53.8357(41) Å, V = 2523.58(26) Å3, and Z = 4. The structure is characterized by alternating hydrophobic and hydrophilic layers along the c-axis. The Ca cations are 7-coordinate, and share edges to form chains along the b-axis. Each of the water molecules acts as a donor in two hydrogen bonds. The coordinated water molecule makes two strong intermolecular O–H⋯O hydrogen bonds to carboxyl and carbonyl groups. The two zeolitic water molecules form weaker hydrogen bonds, to carbonyl O atoms, ring N atoms, and aromatic C atoms. Several N–H⋯O/N hydrogen bonds, as well as C–H⋯O hydrogen bonds, also contribute to the lattice energy.
In this paper, we design and fabricate dual-tunable waveguides in a two-dimensional periodic plate with threaded holes. Dual tunability is realized by using rods held with nuts as well as assembly prestress of the nuts. A straight waveguide, a bent waveguide, and a wave splitter are designed by changing the distribution of rods and nuts in different circuits. The experimental and numerical results show that the frequencies of guided waves can be tuned by the assembly prestress. By increasing the amount of prestress, the frequency range of the passing band can be shifted upward. Confinements, guiding, and splitting of Lamb waves are clearly observed in both experimental measurements and numerical simulations. This work is essential for the practical design of reconfigurable phononic devices.
X-ray powder diffraction data, unit-cell parameters, and space group for the Lumateperone tosylate, C24H29FN3O⋅C7H7O3S, are reported [a = 15.5848(10) Å, b = 6.0700(4) Å, c = 31.3201(14) Å, β = 96.544(5)°, V = 2943.58 Å3, Z = 4, and space group C2]. In each case, all measured lines were indexed and were consistent with the corresponding space group. The single-crystal data of Lumateperone tosylate is also reported, respectively [a = 15.626(3) Å, b = 6.0806(10) Å, c = 31.415(5) Å, β = 96.609(7)°, V = 2965.1(8) Å3, Z = 4, and space group C2]. The experimental powder diffraction pattern has been well matched with the simulated pattern derived from the single-crystal data with preferred orientation in the [002] direction (orientation coefficient = 0.75).
In this chapter, 2D Computational Grains (CGs) with elastic inclusions or voids and 3D CGs with spherical/ellipsoidal inclusions/voids or without inclusions/voids are developed for micromechanical modeling of composite and porous materials. A compatible displacement field is assumed along the outer boundary of each CG. Independent displacement fields in the CG are assumed as characteristic-length-scaled T-Trefftz trial functions. Muskhelishvili’s complex functions are used for 2D CGs, and Papkovich-Neuber solutions are used for 3D CGs to construct the T-Trefftz trial displacement fields. The Papkovich-Neuber potentials are linear combinations of spherical/ellipsoidal harmonics. To develop CG stiffness matrices, multi-field boundary variational principles are used to enforce all the conditions in a variational sense. Through numerical examples, we demonstrate that the CGs developed in this chapter can estimate the overall material properties of heterogeneous materials, and compute the microscopic stress distributions quite accurately, and the time needed for computing each SERVE is far less than that for the finite element method.
The preprocessing of Computational Grains (CGs) is introduced in Chapter 3, and several types of CGs have been developed for the micromechanical modeling of different kinds of composites with particulates, fibers, and so on in Chapters 5–11. A multi-scale analysis framework of composite structures by using the CGs and the standard FEM is developed in this chapter, based on the homogenization of composite materials at the microlevel, and slender or shell structures at the meso- and macro-levels. The specific process of the multi-scale algorithm is illustrated with an example of a stiffened composite panel. The results show the multi-scale analysis method is an accurate and efficient tool for large composite structures, not only simulating the overall structural responses in a bottom-up fashion, but also obtaining the detailed stresses at multiple scales in the dehomogenization process.