Li[Lix/3Mn2x/3M1−x]O2 (M = Ni, Mn, Co) (HE-NMC) materials, which can be expressed as a combination of trigonal LiTMO2 (TM = transition metal) and monoclinic Li2MnO3 phases, are of great interest as high capacity cathodes for lithium-ion batteries. However, structural stability prevents their commercial adoption. To address this, Si doping was applied, resulting in improved stability. Raman and differential capacity analyses suggest that silicon doping improves the structural stability during electrochemical cycling. Furthermore, the doped material exhibits a 10% higher capacity relative to the control. The superior capacity likely results from the increased lattice parameters as determined by X-ray diffraction (XRD) and the lower resistance during the first cycle found by impedance and direct current resistance (DCR) measurements. Density functional theory (DFT) predictions suggest that the observed lattice expansion is an indication of increased oxygen vacancy concentration and may be due to the Si doping.

Doveweed is a problematic weed of lawns and sod production, as well as golf course roughs, fairways, and tees. End-user reports of selective POST control options are inconsistent and control is often short-lived. In addition, inconsistent control with non-selective herbicides such as glyphosate is common. The goals of this research were: (1) evaluate selective POST doveweed control options in ‘Tifway’ hybrid bermudagrass turf; (2) compare efficacy of single vs. sequential applications of selective POST herbicides; (3) quantify doveweed tolerance to glyphosate; and (4) quantify recovery of foliar applied glyphosate following treatment with a C14-glyphosate solution. A single application of sulfentrazone+metsulfuron; thiencarbazone+iodosulfuron+dicamba or 2,4-D+MCPP+dicamba+carfentrazone; or thiencarbazone+foramsulfuron+halosulfuron provided >60% control 2 weeks after initial treatment (WAIT). A second application of these treatments 3 WAIT improved control 6 WAIT. Two applications of 2,4-D+MCPP+dicamba+carfentrazone or thiencarbazone+foramsulfuron+halosulfuron provided ~80% control 6 WAIT. Doveweed was tolerant to glyphosate application up to 5.68 kgaeha-1. Absorption of 14C-glyphosate was compared between doveweed with cuticle intact, doveweed with a disturbed cuticle, and smooth crabgrass. 14C-glyphosate recovery from the leaf surface of doveweed plants with an intact cuticle was 93.6%. In comparison, 14C-glyphosate recovery from the leaf surface of doveweed plants with a disrupted cuticle and the leaf surface of crabgrass plants was 79.1 and 70.5%, respectively.

Glyphosate is used in the transition zone to control annual bluegrass in fully dormant warm-season grasses. A suspected resistant (R) biotype of annual bluegrass was identified on a golf course in South Carolina after at least 10 consecutive years of glyphosate application. Greenhouse bioassays revealed the R biotype was 4.4-fold resistant to glyphosate compared with a standard susceptible (S) biotype. Further studies were conducted to investigate the mechanism conferring glyphosate resistance in the R biotype. Leaf discs of both biotypes accumulated shikimate in response to increasing glyphosate concentration, but the glyphosate concentration resulting in 50% EPSP synthase inhibition as a result of shikimate accumulation (I 50) was 4.2-fold higher in the R biotype compared with the S biotype. At the whole plant level, similar levels of shikimate accumulation were observed between biotypes at 6 and 24 h after treatment (HAT) with glyphosate, but greater shikimate accumulation occurred in the S biotype at 72, 120, and 168 HAT. Shikimate levels decreased in the R biotype after 72 HAT. There were no differences in 14C-glyphosate absorption between biotypes. However, more 14C-glyphosate translocated out of the treated leaf in the R biotype and into root tissues over time compared with the S biotype. Partial sequencing of the EPSP synthase gene revealed a point mutation that resulted in an Ala substitution at Pro106. Although other mechanisms may contribute to glyphosate resistance, these results confirm a Pro106 to Ala substitution is associated with resistance to glyphosate in the R annual bluegrass biotype.

We examined the influence of temperature and release density on the root-boring moth, Agapeta zoegana L., a biological control agent of diffuse knapweed, Centaurea diffusa Lam., and spotted knapweed, Centaurea maculosa Lam. Moths were released at six densities (1, 2, 4, 8, 16, and 32 adult male–female pairs) in each of 2 years (1992 and 1993 cohorts) into outdoor, caged plots containing spotted knapweed. Air temperature, larval establishment and mass, and adult emergence, mass, and body dimensions were measured. Larval production increased linearly with adult release density in both cohorts. Larval survival ranged from 0 to 100% and was not correlated with release density or accumulated degree-days in either year. Date of first emergence occurred earlier as both release density and larvae per plant increased, but only for the 1992 cohort. Declining resources or increased contact among the larvae may induce early pupation. Peak emergence rate increased with release density in both cohorts. First emergence was related more closely to calendar date than accumulated degree-days. In contrast, peak emergence rates were more consistent with degree-day accumulations between cohorts than calendar date. Adult production increased with parental release density in both cohorts. Females were heavier, wider, and longer than males. Optimal A. zoegana production will be achieved with releases of greater than 1.6 male–female adult pairs per spotted knapweed plant.

Cyphocleonus achates (Fahraeus) is a weevil used for the biological control of diffuse knapweed, Centaurea diffusa Monnet Del La Marck, and spotted knapweed, Centaurea maculosa Monnet Del La Marck, in North America. This research provided specific information on the biology of this insect in British Columbia. Adult weevils were released at six densities (1, 2, 4, 8, 16, and 32 male–female pairs) in each of 2 years into plots containing spotted knapweed. Larvae per plant, larval mass, larval survival, adult emergence, and air temperature were measured. Larval production increased with the release density of weevils in both the 1992 cohort and the 1993 cohort. Larval mass did not differ between years. Larval mass also did not vary with the release density of adults or the number of larvae per root. Larval survival of the 1993 cohort ranged from 17 to 48%, whereas that of the 1994 cohort ranged from 0 to 91%. Adult emergence began after the accumulation of 726–1144 degree-days. For both cohorts the date of first emergence occurred earlier, as the average number of larvae per plant increased for both cohorts. Increasing competition for food or space in the roots can induce early emergence. Sex ratios did not vary with date of emergence or release density of adult weevils. Adult emergence increased with the release density in the 1992 cohort, suggesting the average larval densities did not exceed the carrying capacity of the roots. The peak emergence rate increased with the release density in the 1992 cohort, but not in the 1993 cohort because of lower larval survival.

ABSTRACT: In this paper, I raise the following question: can the ethical thought of Jurgen Habermas and Karl-Otto Apel provide us with a way of showing that morality is a rational requirement? The answer I give is that (unfortunately) it cannot. I argue for this claim by showing that a decisive objection to Alan Gewirth’s line of thought in Reason and Morality also applies to discourse ethical arguments that try to show an inescapable commitment to a moral principle.

Since the principal objectives of the CTI Centre for Modem Languages (CTICML) and of the other CTI Centres are to increase awareness of the potential of computers and other forms of IT in teaching and learning and to stimulate their actual use, it seemed a reasonable first step after the establishment of the CTICML in April 1989 to try to establish the current range of attitudes and practices in the field of lan- guages in higher education in the United Kingdom. We considered that this would both help us to gain a view of what had to be done and give us one yard- stick against which to measure the effect which our activities over the next few years will have had.

This paper describes observations made on visits to Beechey Island in 1999, 2002, and 2005. These visits were made in order to examine the memorials on this very important site for Arctic exploration and to make an extensive photographic record of them. Their history and present condition are described. There are some inconsistencies and confusion in the scattered literature concerning their history and this paper seeks to resolve these matters. It is hoped that further investigations to resolve the few remaining problems, will be conducted and that a systematic nomenclature, which is suggested in the paper, will be adopted for the memorials. Restoration, repair, and regular maintenance of the memorials are becoming necessary and appropriate funding for this is required before it is too late. Close regulation of the erection of more modern memorials and burials, some of which, in the author's view, detract from the significance, solemnity, and appearance of the island is desirable. With the growing number of airborne and ship borne travellers and tourists visiting Beechey Island, a degree of supervision may become necessary in order to ensure that the memorials remain intact. Beechey Island is one of the most important heritage locations in Canada and in the history of Arctic exploration by the Royal Navy in the nineteenth century.

Batch adsorption/dissolution experiments were conducted to examine the interactions between 233U(VI) and a synthetic aluminum oxyhydroxide (boehmite, γ-AlOOH) in 1.0M NaCl suspensions containing 1-hydroxyethane-1,1-diphosphonic acid (HEDPA). In the pH range 4 to 9, complexation of Al(III) by HEDPA significantly enhanced dissolution of boehmite. This phenomenon was especially pronounced in the neutral pH region where the solubility of aluminum, in the absence of complexants, is limited by the formation of sparsely soluble aluminum hydroxides. At high pH levels, dissolution of synthetic boehmite was inhibited by HEDPA, likely due to sorption of Al(III)/HEDPA complexes. Addition of HEDPA to equilibrated U(VI)-synthetic boehmite suspensions yielded an increase in the aqueous phase uranium concentration. The concentration of uranium continually increased over 59 days. Partitioning of uranium between the solid and aqueous phase was found to correlate well with HEDPA partitioning.