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Gaseous renewable fuel combustion is of primary interest for a range of applications including aircraft engines, ground power engines, reciprocating engines, and industrial furnaces, among others. While much of the combustion science and engineering that are needed to design and operate such devices is well developed and available in modern textbooks, the attainment of even higher efficiencies, greater performance, and reduced emissions for an ever-increasing array of new fuels and fuel blends requires an even deeper understanding of fundamental combustion concepts and the underlying physical and chemical phenomena. In many cases, these fundamental concepts are areas of much recent and ongoing research. This chapter describes the basic combustion and chemical kinetic properties of the fuels, namely hydrogen, syngas, ammonia, methane, natural gas, and ethanol, considering the flame temperature, ignition delay time, flammability limit, laminar flame speed, and fuel stretch sensitivity.
Gaseous renewable fuel combustion is of primary interest for a range of applications including aircraft engines, ground power engines, reciprocating engines, and industrial furnaces, among others. While much of the combustion science and engineering that are needed to design and operate such devices is well developed and available in modern textbooks, the attainment of even higher efficiencies, greater performance, and reduced emissions for an ever-increasing array of new fuels and fuel blends requires an even deeper understanding of fundamental combustion concepts and the underlying physical and chemical phenomena. In many cases, these fundamental concepts are areas of much recent and ongoing research. This chapter describes the basic combustion and chemical kinetic properties of the fuels, namely hydrogen, syngas, ammonia, methane, natural gas, and ethanol, considering the flame temperature, ignition delay time, flammability limit, laminar flame speed, and fuel stretch sensitivity.
We propose that pluralization of bare nouns in Western Armenian and Turkish is a two-step process. First, the noun is atomized giving a singular form (this is achieved via a null exponent of number under Num) and a new noun is created providing a brand new semi-lattice to serve as the underlying semantic domain. Second, the higher NumP operates morphosyntactically on the singular, and returns a set of atoms from the semi-lattice introduced by the higher n. This is a case of morphological compositionality where one number is built out of another. Our proposal gives a satisfying solution to the puzzle of how “indeterminate nouns” in these languages can express singularity and plurality, depending on the context.
A high-fidelity simulation of the shock/transitional boundary layer interaction caused by a $15^\circ$ axisymmetrical compression ramp is performed at a free stream Mach number of 5 and a transitional Reynolds number. The inlet of the computational domain is perturbed with a white noise in order to excite convective instabilities. Coherent structures are extracted using spectral proper orthogonal decomposition (SPOD), which gives a mathematically optimal decomposition of spatio-temporally correlated structures within the flow. The mean flow is used to perform a resolvent analysis in order to study non-normal linear amplification mechanisms. The comparison between the resolvent analysis and the SPOD results provides insight on both the linear and nonlinear mechanisms at play in the flow. To carry out the analysis, the flow is separated into three main regions of interest: the attached boundary layer, the mixing layer and the reattachment region. The observed transition process is dependent on the linear amplification of oblique modes in the boundary layer over a broad range of frequencies. These modes interact nonlinearly to create elongated streamwise structures which are then amplified by a linear mechanism in the rest of the domain until they break down in the reattachment region. The early nonlinear interaction is found to be essential for the transition process.
The determinants of quality of life (QoL) in schizophrenia are largely debated, mainly due to methodological discrepancies and divergence about the concepts concerned. As most studies have investigated bi- or tri-variate models, a multivariate model accounting for simultaneous potential mediations is necessary to have a comprehensive view of the determinants of QOL. We sought to estimate the associations between cognitive reserve, cognition, functioning, insight, depression, schizophrenic symptoms, and QoL in schizophrenia and their potential mediation relationships.
Methods
We used structural equation modeling with mediation analyses to test a model based on existing literature in a sample of 776 patients with schizophrenia from the FondaMental Foundation FACE-SZ cohort.
Results
Our model showed a good fit to the data. We found better functioning to be positively associated with a better QoL, whereas better cognition, better insight, higher levels of depression, and schizophrenic symptoms were associated with a lower QoL in our sample. Cognitive reserve is not directly linked to QoL, but indirectly in a negative manner via cognition. We confirm the negative relationship between cognition and subjective QoL which was previously evidenced by other studies; moreover, this relationship seems to be robust as it survived in our multivariate model. It was not explained by insight as some suggested, thus the mechanism at stake remains to be explained.
Conclusion
The pathways to subjective QoL in schizophrenia are complex and the determinants largely influence each other. Longitudinal studies are warranted to confirm these cross-sectional findings.
Direct dates of pottery obtained from food crusts or other organic residues on the vessel surfaces can be affected by a reservoir effect and/or an old wood effect and therefore be unreliable. Hence, there is a need for alternative ways to directly date pottery. Moss is used as temper by several cultural groups of the late 6th to early 4th millennium cal BC in northwestern Europe. After the pottery is fired, charred moss remains are often preserved in the clay, so that relatively short-lived plant material with a direct chronological link to the pottery and human occupation is available for radiocarbon (14C) dating. In this study, charred moss temper is extracted for accelerator mass spectrometry (AMS) 14C dating from pottery of the Swifterbant Culture and Spiere group in the Scheldt river valley (Belgium). The moss dates are then compared to reference dates of organic macro-remains from the same sites and food crust dates with or without a reservoir effect of the same pottery. Eleven out of 13 moss dates are in line with the expected pottery age. The paired dates of moss temper and food crusts from the same potsherds confirm a freshwater reservoir effect (FRE) for the latter. We conclude that moss temper has great potential as a sample material for direct pottery dating. However, more research on the extraction and pretreatment of moss temper as well as on the reliability of moss dates is necessary in the future.
Ice flow numerical models are essential for predicting the evolution of ice sheets in a warming climate. Recent research emphasizes the need for higher-order and even full-Stokes flow models, instead of the traditional shallow-ice approximation, whose assumptions are not valid in certain critical areas. These higher-order models are, however, computationally intensive and difficult to use at the continental scale. Here we present a new technique, the Tiling method, to couple ice flow models of varying orders of complexity. The goal of the method is to limit the spatial extent of where higherorder models are applied to reduce the computational cost, while maintaining the model precision. We apply this method on synthetic geometries to demonstrate its practical use. We first use a geometry for which all models yield the same results to check the consistency of the method. Then we apply our method to a geometry for which a full-Stokes model is required in the vicinity of the ice front. Our results show that the hybrid models present significant improvements over mono-model approaches and reduce computational times.
Predictions of marine ice-sheet behaviour require models able to simulate grounding-line migration. We present results of an intercomparison experiment for plan-view marine ice-sheet models. Verification is effected by comparison with approximate analytical solutions for flux across the grounding line using simplified geometrical configurations (no lateral variations, no buttressing effects from lateral drag). Perturbation experiments specifying spatial variation in basal sliding parameters permitted the evolution of curved grounding lines, generating buttressing effects. The experiments showed regions of compression and extensional flow across the grounding line, thereby invalidating the boundary layer theory. Steady-state grounding-line positions were found to be dependent on the level of physical model approximation. Resolving grounding lines requires inclusion of membrane stresses, a sufficiently small grid size (<500 m), or subgrid interpolation of the grounding line. The latter still requires nominal grid sizes of <5 km. For larger grid spacings, appropriate parameterizations for ice flux may be imposed at the grounding line, but the short-time transient behaviour is then incorrect and different from models that do not incorporate grounding-line parameterizations. The numerical error associated with predicting grounding-line motion can be reduced significantly below the errors associated with parameter ignorance and uncertainties in future scenarios.
This article discusses the morphological and syntactic structure of relative clauses in Ojibwe (Algonquian), in particular their status as wh-constructions. Relatives in this language are full clauses that bear special morphology, show evidence of A′-movement of a wh-operator, and consequently exhibit wh-agreement also found in interrogatives and certain types of focus constructions. Ojibwe shows the possibility of wh-agreement realized on T (in addition to C and v for other languages), as it appears on tense prefixes. We account for the realization of wh-agreement on T in Ojibwe via the mechanism of feature inheritance. We propose that while declarative matrix clauses are canonical in that C introduces φ-features in Ojibwe, the role of C in embedded or wh-contexts is to introduce δ-features (discourse features), such as [uwh], rather than φ-features. These δ-features can be introduced by C, but are transferred down to T where they spell out as wh-agreement.
The mechanical properties of glacier beds play a fundamental role in regulating the sensitivity of glaciers to environmental forcing across a wide range of timescales. Glaciers are commonly underlain by deformable till whose mechanical properties and influence on ice flow are not well understood but are critical for reliable projections of future glacier states. Using synoptic-scale observations of glacier motion in different seasons to constrain numerical ice flow models, we study the mechanics of the bed beneath Hofsjökull, a land-terminating ice cap in central Iceland. Our results indicate that the bed deforms plastically and weakens following incipient summertime surface melt. Combining the inferred basal shear traction fields with a Coulomb-plastic bed model, we estimate the spatially distributed effective basal water pressure and show that changes in basal water pressure and glacier accelerations are non-local and non-linear. These results motivate an idealized physical model relating mean basal water pressure and basal slip rate wherein the sensitivity of glacier flow to changes in basal water pressure is inversely related to the ice surface slope.
Some institutional arrangements may be undesirable for democracy by obscuring which political actors are to be held responsible for failed or successful policies and bad or good macroeconomic performances. Much of the work in the area has focused on whether institutions affect the ‘clarity of political responsibility’ and the ability of voters to punish or reward, in turn, governments and elected officials. Not much has been said, however, about the assignment of responsibility outside the electoral context, for a broad range of policy areas. This paper explores these questions in the context of French semi-presidentialism. It demonstrates that the French public is surprisingly quite responsive to the demands imposed by their political system by adjusting reasonably well their evaluations of both actors of the executive in light of major political events and changes in the economic conditions when the circumstances clearly indicate which of the two is ‘in charge’. At other times, however, this particular institutional arrangement obscures instead political responsibility.
With the aim of solving in a four dimensional phase space a multi-scale Vlasov-Poisson system, we propose in a Particle-In-Cell framework a robust time-stepping method that works uniformly when the small parameter vanishes. As an exponential integrator, the scheme is able to use large time steps with respect to the typical size of the solution’s fast oscillations. In addition, we show numerically that the method has accurate long time behaviour and that it is asymptotic preserving with respect to the limiting Guiding Center system.