New Zealand's ageing population and health inequities for Māori (Indigenous peoples) have prompted calls for innovative, culturally based approaches to improving health and wellbeing, and managing transitions in later life. This is particularly important for kaumātua (Māori elders) who, despite cultural strength and resilience, carry a significant burden in health, economic and social inequities. This paper describes the culture-centred development of a ‘tuakana‒teina’ (elder sibling‒younger sibling) peer support education programme designed to help kaumātua support other kaumātua experiencing transitions in later life. Taking a strengths-based approach that highlights ‘kaumātua mana motuhake’ (elder independence and autonomy), the study used kaupapa Māori (Māori approach, knowledge, skills, attitudes and values) and community-based participatory research methodology, to develop and pilot a culture-centred tuakana‒teina/peer education programme. Methods included establishing two advisory groups (one of kaumātua and one of sector experts); holding five focus groups with kaumātua; and running a pilot programme with 21 kaumātua. The findings demonstrate the value in a strengths-based approach that centralises Māori culture and kaumātua potential, capacity and ability, and recognises the continuing value and contribution of kaumātua to society. The study helps shift the focus from dominant stereotypes of ageing populations as a burden on society and shows the value of kaumātua supporting others during transitions in later life.

The end of the last Ice Age in Britain (c. 11500 BP) created major disruption to the biosphere. Open habitats were succeeded by more wooded landscapes, and changes occurred to the fauna following the abrupt disappearance of typical glacial herd species, such as reindeer and horse (Conneller & Higham 2015). Understanding the impact of these changes on humans and how quickly they were able to adapt may soon become clearer, due to recent discoveries in the Colne Valley on the western edge of Greater London, north of the River Thames. An exceptionally well-preserved open-air site was discovered in 2014 as part of a wider project of archaeological investigation and excavation carried out by Wessex Archaeology (2015), on behalf of CEMEX UK. The site, at Kingsmead Quarry in Horton, is unusual because it has good organic preservation and, in addition to worked flint artefacts, it has yielded groups of articulated horse bone. The extreme rarity of such sites of this period in Britain makes this discovery especially significant and re-emphasises the potential importance of the Colne Valley (Lacaille 1963; Lewis 2011; Morgi et al. 2011).

This paper describes the discovery of a massive, fan-shaped flint core from West Kennett Farm, near Avebury in Wiltshire, a site that is noted for two Late Neolithic palisaded enclosures. The discovery of the core has renewed focus on three similar artefacts from East Anglia, the importance of which has been overlooked. These cores arguably constitute some of the largest individual pieces of systematically worked flint from Britain. The paper considers the implications of the discovery at West Kennett Farm, where nodules of this size are absent, with the movement of flint across Britain, and concludes by discussing the role of these ‘mega-cores’ with current thinking on the function of stone in Neolithic Britain.

Calculations based on Poisson-Boltzmann theory are used to investigate the equilibrium properties of an electrolyte containing TcO4 − and SO4 2− ions near the surface of amorphous silica. The calculations show that the concentration of TcO4 − is greater than SO4 2− at distances less than 1 nm from the surface due to the negative charge density caused by deprotonation of the amorphous silica silanol groups. At lower pH, the surface becomes protonated and the magnitude of this effect is reduced. These results have implications for the potential use of oxyanion-SAMMS for the environmental remediation of water contaminated with 99Tc.

Mean fecundity of hemlock sawfly females emerging from cocoons collected on heavily defoliated western hemlock trees was significantly less than fecundity of females collected from lightly defoliated trees. Fecundity was highly correlated with female cocoon diameter and female forewing length, but was most highly correlated with both variables combined. Time-saving double sampling techniques are discussed for determining mean fecundities of new samples when mean cocoon diameter and forewing length are known.

Hemlock sawfly infestations occur most commonly in the warm southern half of southeast Alaska. Biotic factors that limit sawfly populations are a fungus, Entomophthora sphaerosperma, which kills disproportionately large numbers of female larvae; food quality as affected by host site and defoliation; and three ichneumonid parasitoid species, Delomerista japonica diprionis, Oresbius tsugae tsugae, and Itoplectis quadricingulatus, which attack prepupal larvae in cocoons. E. sphaerosperma was the most effective natural control in recent years, especially during wetter than normal summers. Parasites which attack after the fungus has decimated larval populations were most abundant during two dry summers. Parasitization and sawfly emergence were directly related, and both were highly inversely correlated with percentage fungus killed sawflies. Sawflies reared on lightly defoliated trees produced significantly more eggs than those reared on heavily defoliated trees, and fecundity was directly related to cumulative heat units during the summer. Between 1952 and 1974, most negative sawfly population trends south of Frederick Sound occurred when two wet summers occurred consecutively. Apparent widespread collapse of sawfly populations in 1974 was associated with low temperatures in 1973 which delayed sawfly development and reduced opportunities for successful oviposition.

The results of sequential large-scale molecular dynamics (MD) simulations of radiation damage cascades in Gd2Ti2O7 and Gd2Zr2O7 are presented. Twelve alpha recoil cascades, each due to a recoil atom with 40 keV of kinetic energy, are performed in both materials and a stark contrast in behaviour observed. Topological connectivity analysis is used to analyse the structural evolution of the two systems. Our results provide important insight into accumulation of disorder in pyrochlore-structured ceramics.

Nitridation is the process in which, during the initial growth of a-SiNx:H layers on Si surfaces, nitrogen (N) is incorporated into Si lattice near its surface. We show that this nitridation process affects the density of interface states (Dit ) and fixed charges (Qf ) at the interface. These parameters determine the effective surface passivation quality of the layers. The nitridation can be tuned independently of the growth of a-SiNx:H layers by using a plasma treatment prior to actual a-SiNx:H layer deposition. It is shown that the Qf can be varied from 2·1012 to 15·1012 cm-2 without changing the a-SiNx:H deposition process. It is demonstrated that in our case and processing window, Qf is the determining factor in surface passivation quality in the range of 2·1012 to 8·1012 cm-2. For higher values of Qf , Dit has increased significantly and has become dominant thereby reducing the passivation quality. It is shown that the passivation can be controlled independently of the a-SiNx:H deposition process. On completed solar cells this variation in Qf due to nitridation results in a change in open-circuit voltage, Voc, of almost 20mV.

This study investigates whether investors see through materially misstated earnings, and whether they anticipate earnings restatements. For firms that restate at least one annual report, we find that investors are misled by mistakes in reported earnings at the time of initial earnings announcements. Investors react positively to the component of the favorable earnings surprise that will subsequently be restated, and they attach the same valuation to it as to the true earnings surprise. We also find that investors anticipate the subsequent downward restatements and start marking stock prices down several months before a restatement announcement, so that the full impact of a restatement is about three times as large as the restatement announcement effect. Indeed, we show that investors punish restating firms because the stock price gains that shareholders enjoy when firms initially announce overstated earnings are more than reversed by the time of the restatement announcement.

Prompted by renewed interest in the crystalline oxides-on-semiconductors interface, periodic density functional theory and atomistic simulation techniques are used to examine the formation of a layer of CaO on a BaO substrate. We examine how CaO islands which form at coverages less than 100% adjust to the substrate in which the cation-anion separation is substantially larger than in CaO itself. All Ca-O bond lengths in the island are shorter than that in bulk CaO. Corner O atoms in the islands are associated with particularly short Ca-O bond lengths, and the shape of the islands is dominated by (100) edges. Once formed, islands with intact edges will remain intact. Interactions between islands at larger coverages are also investigated and we see the formation of characteristic elliptical gaps and loops.

Results of periodic ab initio density functional theory calculations on thin films of (i) wurtzite ZnO (hexagonal) which terminate with the non-polar (1010) surface, and with the polar (0001) and (0001) surfaces (ii) zinc blende (cubic) ZnO which terminate with the non-polar (110) and with the polar (111) surfaces. Thin (less than18 layer) films of wurtzite ZnO which terminate with the polar (0001) and (0001) surfaces are found to be higher in energy than corresponding films in which these polar surfaces flatten out forming a new planar ‘graphitic’-like structure in which the Zn and O atoms are coplanar and the dipole is removed. This is the lowest energy surface for ultra-thin films. For zinc-blende ZnO a graphitic-type solution, but with a different stacking of ZnO layers, is also comparable to energy to the non-polar (110) and polar (111) solutions. Consequences for crystal growth and the stabilization of thin films and nanostructures are discussed.

Laboratory and numerical experiments have been conducted to study the secular spin-up of both a homogeneous and a thermally stratified rotating fluid in a right cylinder. In these experiments, the angular velocity of the container increases linearly in time from some initial rotation rate at t = 0. A simple quasi-geostrophic model is developed to describe the adjustment of the fluid over the characteristic spin-up time scale to the constant angular acceleration of the basin. Good agreement is found between the observed interior temperature and azimuthal velocity fields and the theory in both the homogeneous and stratified secular experiments. This result is in contrast to the much faster adjustment observed in stratified instantaneous spin-up experiments reported earlier. The main difference between these experimental cases is the inability of secular forcing to excite energetic inertial–gravity-wave transients during the initial phases of secular spin-up. Thus, the asymptotic theory which has filtered out these initial higher-frequency transients is accurate even though the inertial period is not much smaller than the characteristic spin-up time scale.

We give an update of our ongoing survey for intracluster light (ICL), in a sample of distant Abell clusters. We find that the amount of intracluster starlight is comparable to that seen in nearby clusters, and that tidal debris appear to be common.