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Fragmentation of a fluid body into droplets underlies many contamination and disease transmission processes where pathogens are transported in a liquid phase. An important class of such processes involves formation of a fluid ligament and its destabilization into droplets. Inertial detachment (Gilet & Bourouiba, J. R. Soc. Interface, vol. 12, 2015, 20141092) is one of these modes: upon impact on a sufficiently compliant substrate, the substrate's motion can transfer its impulse to a contaminated sessile drop residing on it. The fragmentation of the sessile drop is efficient at producing contaminated ejected droplets with little dilution. Inertial detachment, particularly from substrates of intermediate wetting, is also interesting as a fundamental fragmentation process on its own merit, involving the asymmetric stretching of the sessile drop under impulsive axial forcing with one-sided pinning due to the substrate's intermediate wetting. Our experiments show that the radius, $R_{tip}$, of the tip drop ejected become insensitive to the Bond number value for $Bo>1$. Here, $Bo$ quantifies the inertial effects via the relative axial impulsive acceleration compared with capillarity. The time, $t_{tip}$, of tip-drop breakup is also insensitive to $Bo$. Combining experiments, theory and validated numerics, we decipher the selection of $R_{tip}$ and its sensitivity to the surface-wetting and substrate foot dynamics. Using asymptotic theory in the large $Bo$ limit for which the thin-film/slender-jet approximations hold, we derive a reduced physical model that predicts $R_{tip}$ consistent with our experiments. Finally, we discuss how pathogen physical properties (e.g. wetting and buoyancy) within the sessile drop determine their distribution in the tip and secondary fragmentation droplets.
An asymptotic matching modal model is established based on the singular perturbation method for predicting mode evolution in single- and dual-mode interfaces accelerated by a shock wave. The startup process is incorporated into the model to provide a complete description of the mode evolution after the shock impact. Through considering the feedback from high-order harmonic to the third-order harmonic, the model accuracy is improved and the model divergence is prevented. In addition, the model can evaluate the mutual-coupling effect on the amplitude variations of high-order harmonics besides the ‘beat modes’. To validate the model, experiments on both light–heavy and heavy–light interfaces subject to a shock wave are conducted, and both single- and dual-mode interfaces formed by the soap-film technique are involved. The interface profiles extracted from mode decomposition and predicted by the model show high consistency with the experimental counterparts. Good agreement of the mode amplitude growths between the experiments and theoretical predictions shows the superiority of the model, especially for the heavy–light interface.
In this paper, we simulate the process of two-dimensional axisymmetric fluid–structure coupling of a droplet impacting on a flexible disk. The effects of dimensionless disk stiffness (K = 0.1–1000), Weber number (We = 1–500) and contact angle (θ = 130° and 60°) on the dynamics of the droplet impacting on the flexible disk are analysed. The results indicate that there are five typical impact modes for a hydrophobic surface (θ = 130°) and four typical impact modes for a hydrophilic surface (θ = 60°) within the range of considered parameters. The analysis of spreading factor reveals that a part of the energy is transferred to the substrate, which is manifested as a weakening of the droplet spreading, when the substrate deforms downwards due to the droplet impact; the squeezing of the droplet causes a tendency to flow from the centre of the droplet to the edge, which is manifested as an enhancement of the droplet spreading, when the substrate recovers from the downward deformation. The effect of the substrate flexibility on the maximum spreading factor depends on the competition of the two mechanisms above. Based on this, a modified scaling law of βmax has been proposed by introducing the effective Weber number (Wem). The analysis of impact force demonstrates that the peak of the impact force is related to the deflection of the flexible substrate which is different from that of a rigid wall; and three typical processes of impact force variation have been summarised. In addition, unlike the rigid substrate scenario, there is an energy interaction between the droplet and the flexible substrate after impact occurs, which is classified as three typical energy transformation processes.
Satellite remote sensing is vital for monitoring anthropogenic changes and for alerting us to escalating environmental threats. With recent technological advances, a variety of satellite-based monitoring systems are available to aid conservation practitioners. Yet, documented knowledge of who uses near-real-time satellite-based monitoring and how these technologies are applied to inform conservation decisions is sparse. Through an online survey and semi-structured interviews, we explored how developers and users leverage conservation early-warning and alert systems (CEASs) for enhanced conservation decisions. Some 167 developers and users of near-real-time fire and forest monitoring systems from 40 countries participated in this study. Globally, respondents used 66 unique CEASs. The most common applications were for education and awareness, fire/disaster management and law enforcement. Respondents primarily used CEASs to enforce land-use policies and deter illegal activities, and they perceived these tools as underutilized for incentivizing policy compliance or conservation. Respondents experienced inequities regarding system access, exposure and ability to act upon alert information. More investments in capacity-building, resources and action plans are needed to better link information to action. Implementing recommendations from this research can help us to increase the accessibility and inclusivity of CEAS applications to unlock their powerful capabilities for achieving conservation goals.
We study experimentally the onset of Faraday waves near the end walls of a rectangular vessel containing two stably stratified fluid layers, subject to horizontal oscillations. These subharmonic waves (SWs) are excited, because the horizontal inertial forcing drives a harmonic propagating wave which displaces the interface in the vertical direction at the end walls. We find that the onset of SWs is regulated by a balance between capillary and viscous forces, where the rate of damping is set by the Stokes layer thickness at the wall rather than the wavelength of the SWs. We model the onset of SWs with a weakly damped Mathieu equation and find that the dimensional critical acceleration scales as $\nu _m^{1/2} \omega ^{3/2}$, where $\nu _m$ is the mean viscosity and $\omega$ is the frequency of forcing, in excellent agreement with the experiment over a wide range of parameters.
The aim of this paper is to characterise the internal structures and ice-flow history of representative valley glaciers in Svalbard and infer from them dynamic changes over centennial timescales. Three polythermal and one cold valley glacier are investigated using field- and laboratory-based techniques and remote sensing. Structures along flow-unit boundaries indicate that ice-flow configuration in three of the glaciers has remained stable spanning the residence time of the ice. Deformation of a flow-unit boundary in the fourth reveals an ice-flow instability, albeit one that has been maintained since its most recent advance. Macro-crystallographic, sedimentological and isotopic analyses indicate that basal ice is elevated to the glacier surface, as shown by entrained sediments and enrichment in heavy isotopes. In narrow zones of enhanced cumulative strain, new ice facies are generated through dynamic recrystallisation. The surface density of longitudinal foliation is shown to represent the relative magnitude of cumulative strain. Geometric similarities between flow-unit boundaries in Svalbard valley glaciers and larger scale longitudinal surface structures in ice sheets suggest that deformation mechanisms are common to both.
We explore the interaction of natural convection and mechanical ventilation in a room where fresh air is supplied at low level and stale air is extracted at high level. Turbulent buoyant plumes rising from heat sources interact with this upward airflow and establish a steady-state stratification with a warm upper layer above a layer of the cold supply air. Adapting the volume balance model used in natural ventilation (Linden et al., J. Fluid Mech., vol. 212, 1990, pp. 309–335) leads to the prediction that the upper layer will vent from the room when the ventilation volume flux exceeds the volume flux in the plumes at the ceiling. However, our new laboratory experiments establish that there is still a stable two-layer stratification beyond this point of critical ventilation. Motivated by our observations, we propose that the kinetic energy flux supplied by the plume leads to turbulent mixing in the upper layer. We propose a new model of this mixing which is consistent with our experiments in both the over- and under-ventilated regimes. This has important implications for air recirculation in buildings with large ventilation flows, particularly hospital operating theatres and clean rooms.
Liquid flowing down a fibre readily destabilises into a train of beads, commonly called a bead-on-fibre pattern. Bead formation results from capillary-driven instability and gives rise to patterns with constant velocity and time-invariant bead frequency $f$ whenever the instability is absolute. In this study, we develop a scaling law for $f$ that relates the Strouhal number $St$ and capillary number $Ca$ for Ostwaldian power-law liquids with Newtonian liquids recovered as a limiting case. We validate our proposed scaling law by comparing it with prior experimental data and new experimental data using xanthan gum solutions to produce a low capillary number $Ca \leq 10^{-2}$ regime. The experimental data encompasses both Ostwaldian and Newtonian flow, as well as symmetric and asymmetric patterns, and we find the data collapses along the predicted trend across seven orders of magnitude in $Ca$. Our proposed scaling law is a powerful tool for studying and applying bead-on-fibre flows where $f$ is critical, such as heat and mass transfer systems.
A calcium-silicate xenolith (no. 11) from the ignimbrite of the Upper Chegem Caldera in Kabardino-Balkaria, Russia, has revealed a diverse mineral assemblage with As- and B-bearing phases from the apatite supergroup such as the svabite and johnbaumite–hydroxylellestadite series, in addition to cahnite and datolite. Three distinct zones of variable arsenic content have been investigated. Notably, the outermost altered zone adjacent to the ignimbrite hosts the highest concentration of arsenic and arsenate minerals. A detailed structural analysis using Raman spectroscopy was carried out to investigate the distribution of boron and arsenic in tetrahedral coordination. This has provided the basis for describing a solid-solution system between hydroxylellestadite, svabite and johnbaumite and can be used as a novel technique for identifying apatite-supergroup minerals. One aim of the analysis was to elucidate the origin of various elements and content levels, particularly in relation to the distance from the xenolith–ignimbrite contact. The presence of boron and arsenic, probably derived from ignimbrites, highlights the important role of volcanic rocks as potential contributors of these elements in mineral formation processes.
Three metamict thorium orthosilicate samples from the syenite pegmatites of the Larvic Plutonic Complex, Norway, were thoroughly examined using Raman spectroscopy, electron probe microanalyses (EPMA), electron back-scatter diffraction (EBSD) and differential scanning calorimetry (DSC). Their thermal evolution upon heating was investigated using in situ powder X-ray diffraction (HTXRD) in the range of 25–1200°C. One of the samples is a colour-zoned metamict thorium silicate with a preserved tetragonal shape. The zonation is due to the increasing hydration and element distribution. The EBSD indicates that the ratio of huttonite to thorite after the crystallisation significantly varies from zone to zone within the same sample. The crystallisation of thorite starts in the range of 420–480°C (lower than reported previously for mineral samples), while the emergence of huttonite peaks in HTXRD patterns occurs at 870–930°C. In contrast to huttonite, no thorite crystallisation peak is observed in the DSC curve. A wide temperature range is observed where both thorite and huttonite can coexist. Several fluorite-type phases form upon heating. Thorianite exists in the range of 810–1140°C. After the cooling, except for huttonite and thorite, the minor crystallised phases vary and may be represented by Ca–Th oxides and rhombohedral CaUO4.
The thermal expansion of the crystalline huttonite and thorite was determined as $\overline\alpha$V = 20.66 × 10–6 deg–1 for huttonite and $\overline\alpha$V = 12.54 × 10–6 deg–1 for thorite in the temperature range 25–1200°C. These findings contribute to a more in-depth understanding of the behaviour of thorium orthosilicates with complex compositions, both metamict and crystalline, at elevated temperatures. They have potential applications in mineralogy, nuclear chemistry and high-level waste management.
This work presents the results of an investigation of an assemblage of secondary Sc-minerals from the intraplutonic metaluminous pegmatite Kožichovice II, Třebíč Pluton, Czech Republic. The assemblage was formed by hydrothermally-induced dissolution of primary Sc-enriched (≈1.6 wt.% Sc2O3) columbite-(Mn) followed by in situ reprecipitation of volumetrically dominant fersmite (≈0.16 wt.% Sc2O3) and minor nioboheftetjernite (ScNbO4). Subsequent hydrothermal processes resulted in the formation of fluorcalciomicrolite + Sc-minerals (thortveitite + kristiansenite) + titanite. The mass balance calculations (based on EPMA-derived mineral compositions, mineral proportions obtained from TIMA automated mineralogy and textural observations) revealed that the amount of Sc released from the replaced mass of columbite-(Mn) is significantly higher than the amount of Sc incorporated in the mass of the secondary minerals. This indicates that part of the Sc was mobilised and released to the host rocks (pegmatite and granite). The secondary mineral assemblages indicate elevated Ca activity in the alteration fluids. Other occurrences of Sc-minerals in pegmatites (Baveno Pluton and Heftetjern pegmatite) show remarkable similarities in the paragenetic position of Sc-minerals (late hydrothermal/replacement minerals), including the high activity of Ca in fluids during their formation. The high activity of Ca in fluids during the metasomatic replacement of Sc-enriched precursors causes the formation of the volumetrically dominant Sc incompatible phases, followed by a local supersaturation of Sc resulting in the crystallisation of secondary Sc-minerals.
As a natural clay mineral, halloysite (Hal) possesses a distinctive nanotubular morphology and surface reactivity. Hal calcined at 750°C (Hal750°C; 0.0, 1.0, 2.0, 4.0, 6.0, 8.0 wt.%) was used to replace ground granulated blast furnace slag (GGBFS; 50.0, 49.5, 49.0, 48.0, 47.0, 46.0 wt.%) and fly ash (FA; 50.0, 49.5, 49.0, 48.0, 47.0, 46.0 wt.%) for the preparation of geopolymer in this study. The effects of the replacement ratio of Hal750°C on setting time, compressive strength, flexural strength, chemical composition and microstructure of the geopolymer were investigated. The results indicated that Hal750°C did not significantly alter the setting time. The active SiO2 and Al2O3 generated from Hal750°C participated in the geopolymerization, forming additional geopolymer gel phases (calcium (aluminate) silica hydrate and sodium aluminosilicate hydrate), improving the 28 day compressive strength of the geopolymers. When the amount of Hal750°C was 2.0 wt.%, the 28 day compressive strength of the ternary (GGBFS-FA-Hal750°C-based) geopolymer was 72.9 MPa, 34.8% higher than that of the geopolymer without the addition of Hal750°C. The special nanotubular morphology of residual Hal750°C mainly acted like reinforcing fibres, supplementing the flexural strength of the geopolymer. However, excessive Hal750°C addition (>4.0 wt.%) reduced compressive and flexural strength values due to the low degrees of geopolymerization and the porous microstructure in the ternary geopolymer. These findings demonstrate that the appropriate addition of Hal750°C improved the compressive strength of geopolymers prepared using GGBFS/FA, which provides essential data for future research and supports the utilization of low-value Hal-containing clays in geopolymer preparation.
The eddy-viscosity model, as initially used to model the mean Reynolds stress, has been widely used in the linear analysis of turbulence recently by direct extension. In this study, the mechanism of the eddy viscosity in improving the prediction of fluctuation structures with linear analysis is clarified by investigating the statistical properties of forcing, eddy-viscosity term and their correlations. From the direct numerical simulation (DNS) results of turbulent channel flows with $Re_{\tau }=186$–$2003$, the spatial correlation of forcing is partially cancelled due to its interaction with eddy-viscosity terms. The stochastic forcing after excluding the eddy-viscosity term is nearly uncorrelated spatially, which better matches the condition where the resolvent modes are consistent with the spectral proper orthogonal decomposition (SPOD) modes from DNS. With the above findings, an optimisation framework is developed by minimising the spatial correlations of the stochastic forcing. The optimised eddy-viscosity profiles nearly overlap with the mean-quantity-based model in the near-wall region, but have different maximum values. Compared with the mean-quantity-based model, the optimised results enhance the consistency between the resolvent and DNS results significantly. Based on the optimised results, a new modelling framework is further abstracted, leaving only one to-be-modelled parameter of the maximum value of the eddy-viscosity profile. This parameter follows distinctive rules with spanwise flow scales, based on which a simplified predictive model is constructed. The resolvent modes predicted by the new model exhibit high consistency with SPOD modes, which are essentially comparable to the optimised results for wide ranges of streamwise and spanwise scales.
Parisite-(Nd) (IMA2024-013), ideally CaNd2(CO3)3F2, as the Nd-dominant analogue of parisite-(Ce), occurs in dolomitic marble in the Bayan Obo Fe–Nb–REE deposit, Inner Mongolia, China. It is associated with calcite, aegirine, magnetite, hematite, fluorite, riebeckite, bastnäsite-(Ce), baryte, aeschynite-(Ce), aeschynite-(Nd), monazite and parisite-(Ce). Parisite-(Nd) occurs as subhedral to anhedral irregular grains from 0.02 mm to 1 mm. Parisite-(Nd) is transparent, yellowish-brown colour, with pale yellow streak and displays vitreous to resinous lustre. Cleavage is distinct on pseudo-{001}; fracture is uneven, or conchoidal. The Mohs hardness is 4 to 5, and it is brittle. The calculated density of parisite-(Nd) is 4.357 g/cm3. Parisite-(Nd) is pseudo-uniaxial (+), ω = (1.679) and ε = (1.754). The empirical formula is (Ca0.945Fe0.058Sr0.015Ba0.007)Σ1.025(Nd0.967Ce0.529La0.191Pr0.137Gd0.070Sm0.029Th0.022Y0.016Nb0.011Ho0.003)Σ1.975(CO3)3F1.893OH0.023. The Raman spectra of parisite-(Nd) show strong and sharp peaks at 1113, 1090, 825, 635 and 1608 cm–1 and moderate to weak bands centred at 255, 392, 739, 924, 1183, 1228, 1296, 1640, 2247, 2924 and 3065 cm–1. Powder X-ray diffraction and TEM studies give the following results: monoclinic, space group: Cc (# 9), a = 12.3283(13) Å, b = 7.1185(4) Å, c = 28.4633(37) Å, β = 98.529(14)°, V = 2470.28(42) Å3 and Z = 12.
The relevance of education and outreach (E&O) activities about the Antarctic Treaty has been recognized at the Antarctic Treaty Consultative Meetings (ATCM) and at the Committee for Environmental Protection (CEP). This study examines the key topics and the target audiences detailed in papers submitted to the ATCM on E&O. Since the Antarctic Treaty entered into force in 1961, a total of 216 ATCM papers on E&O have been produced. The number of papers has increased substantially since the mid-1990s. ‘Science’ (76.9%) and ‘Wildlife/Biodiversity/Environment’ (75.5%) were the most addressed topics in these papers, while the ‘Public’ (81.0%) and those attending ‘Schools’ (69.0%) are the main target audiences. ‘Science’ in ATCM papers increased ~120-fold from 1961–1997 to 2015–2023, while ATCM papers discussing engagement with the ‘Public’ increased ~40-fold during the same period. ‘Climate change’ was first mentioned in 2006, and the number of papers per year increased fourfold by 2015–2023. This study shows the increasing interest in E&O through time, addressing key topics to relevant audiences related to the Antarctic region. From an educational perspective, attention should be paid to emerging topics (e.g. equity, diversity and inclusion), and the engagement of early-career professionals and educators should be made a priority.
The presence of dispersed-phase droplets can result in a notable increase in a system's drag. However, our understanding of the mechanism underlying this phenomenon remains limited. In this study, we use three-dimensional direct numerical simulations with a modified multi-marker volume-of-fluid method to investigate liquid–liquid two-phase turbulence in a Taylor–Couette geometry. The dispersed phase has the same density and viscosity as the continuous phase. The Reynolds number $Re\equiv r_i\omega _i d/\nu$ is fixed at 5200, the volume fraction of the dispersed phase is up to $40\,\%$, and the Weber number $We\equiv \rho u^2_\tau d/\sigma$ is approximately 8. It is found that the increase in the system's drag originates from the contribution of interfacial tension. Specifically, droplets experience significant deformation and stretching in the streamwise direction due to shear near the inner cylinder. Consequently, the rear end of the droplets lags behind the fore head. This causes opposing interfacial tension effects on the fore head and rear end of the droplets. For the fore head of the droplets, the effect of interfacial tension appears to act against the flow direction. For the rear end, the effect appears to act in the flow direction. The increase in the system's drag is attributed primarily to the effect of interfacial tension on the fore head of the droplets which leads to the hindering effect of the droplets on the surrounding continuous phase. This hindering effect disrupts the formation of high-speed streaks, favouring the formation of low-speed ones, which are generally associated with higher viscous stress and drag of the system. This study provides new insights into the mechanism of drag enhancement reported in our previous experiments.
In this paper, aerobreakup in the stagnation region of high-Mach-number flow over a bluff body is studied with experiments and computations. Water drops of diameter 0.51–2.30 mm were acoustically levitated at sea level along the flight path of a rectangular $100\ {\rm mm} \times 150\ {\rm mm}$ rail-gun launched projectile. This enabled the study of aerobreakup at high Mach (3.03–5.12), post-shock Mach (1.5–1.9), Weber $(5 \times 10^4\unicode{x2013}4 \times 10^5)$ and Reynolds $(6 \times 10^4\unicode{x2013}3 \times 10^5)$ numbers. High-speed backlit shadowgraphy is used to record the flow structure. Computations are made for two cases, and it was found that the drop behaviour is not dominated by viscous or surface-tension effects and can be adequately captured by treating the gas as calorically perfect with the ratio of specific heats set to 1.3 to account for thermochemical effects. To assess drop surface stability at early breakup times, results from Newton's inclination method are used to determine the flow along the drop surface and input to a linear-stability analysis; from this, it was found that viscosity and surface tension can be neglected. Moreover, the acceleration term dominates the shear term at the stagnation point, a point accentuated as a drop flattens; this relation inverts closer to the drop equator. Linear-stability analysis was insufficient for modelling late-stage aerobreakup because the predicted wavelengths were too small and the expected aerobreakup times were non-physically short. To address this discrepancy, a nonlinear instability model with constant-rate growth is used that treats the accelerated drop surface as analogous to bubbles rising through a liquid; agreement with computations is good.
Modern fluvial sediments provide important information about source-to-sink process and regional tectono-magmatic events in the source area, but many factors, e.g., chemical weathering, sedimentary cycles and source-rock types, can interfere with the establishment of the source-sink system. The Lalin River (LR) and the Jilin Songhua River (JSR) are two important tributaries of the Songhua River in the Songnen Plain in NE China. They have similar flow direction, topography and identical climate backgrounds, but have notably different parent-rock types in the headwater, which provides an opportunity to explore the influencing factors of river sediment composition. To this end, the point bar sediments in the two rivers were sampled for an analysis of geochemistry (including element and Sr-Nd isotopic ratios), heavy mineral and detrital zircon U-Pb dating. The results are indicative of the fact that the two rivers have the similar geochemical composition (e.g., elements and Sr isotopes) as well as chemical weathering (CIA = 51.41–57.60, CIW = 59.68–66.11, PIA = 51.95–60.23, WIP = 56.00–65.47, Rb/Sr = 0.38–0.42) and recycling (SiO2/Al2O3 = 5.79 and 5.03, ICV = 1.0 and 1.2, CIA/WIP = 0.81–1.03) characteristics, showing a major control of climate on the low-level weathering and recycling of the river sediments. However, there are significant differences in the detrital zircon U-Pb age (a significant Mesozoic age peak for the LR but an additional Precambrian peak for the JSR), Nd isotope ratio (−6.2812–8.5830 and −8.1149–10.2411 for the LR and the JSR, respectively) and to a certain extent heavy mineral composition (e.g., for the < 63 μm fraction, a dominance of hornblende and magnetite in the LR, but haematite-limonite in the JSR) in the two river sediments, indicating that source rocks largely control the composition of the river sediments. Some of the major tectono-magmatic events (e.g., crustal growth and cratonisation of the North China Craton, closure of the Paleo-Asian Ocean, subduction and rollback of the Paleo-Pacific plate) occurring in the eastern Songnen Plain are well documented in the JSR sediments but not in the LR, the difference of which is largely regulated by the source rocks in the source area.
Different two-dimensional structural units of layered silicate minerals have different chemical and reaction properties. Sulfuric acid solution mineral-leaching systems with pH of 2.0, 4.0 and 6.0 were constructed to investigate the differential dissolution properties of lizardite (1:1 type), chlorite and talc (2:1 type minerals) and the chemical kinetic mechanism of the mineral–water interface reaction. The results showed that the dissolution efficiency of Mg in lizardite is higher than that of chlorite and talc in acidic environments (pH of 2.0, 4.0 and 6.0). The dissolution efficiency of Mg in chlorite is greater than that of talc for acidic environments when pH is 2.0 and 4.0, but chlorite and talc have nearly identical Mg dissolution efficiencies at a pH of 6.0. This phenomenon is related to the defect site on the tetrahedral sheet of chlorite and is controlled by the change of the dissolution efficiency of Al. The dissolution rates of Mg and Si in lizardite, chlorite and talc decreased with the increase of reaction time in the acidic medium for pH = 2.0, 4.0 and 6.0, and there are two linear dissolution trends at different pH values. The dissolution efficiencies of Mg and Si in lizardite, chlorite and talc were simulated and predicted by establishing a logistic model. It was found that the maximum dissolution efficiency of 2:1 type minerals chlorite and talc are only 4.72% and 1.58%, which is much lower than that of 1:1 type lizardite. This research on the reaction mechanism and dissolution kinetics of lizardite, chlorite and talc not only helps to deepen the understanding of the mineral–water interface interaction, but also reveals the different rules for Mg, Si and Al dissolution in different types of trioctahedral mineral–water interface reactions, and provides a crystal chemical basis for the ion migration and action mechanism of minerals.