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The crystal structure of iprodione has been solved and refined using synchrotron X-ray powder diffraction data and optimized using density functional theory techniques. Iprodione crystallizes in the space group P21/c (#14) with a = 15.6469(3), b = 22.8436(3), c = 8.67226(10) Å, β = 94.1303(7)°, V = 3,091.70(9) Å3, and Z = 8 at 298 K. The crystal structure contains clusters of four iprodione molecules. The only two classical N–H···O hydrogen bonds in the structure are both intramolecular. The powder pattern has been submitted to the International Centre for Diffraction Data for inclusion in the Powder Diffraction File™ (PDF®).
There are four forces in our universe. Two act only at the very smallest scales and one only at the very biggest. For everything inbetween, there is electromagnetism. The theory of electromagnetism is described by four gloriously simple and beautiful vector calculus equations known as the Maxwell equations. These are the first genuinely fundamental equations that we meet in our physics education and they survive, essentially unchanged, in our best modern theories of physics. They also serve as a blueprint for what subsequent laws of physics look like.
This textbook takes us on a tour of the Maxwell equations and their many solutions. It starts with the basics of electric and magnetic phenomena and explains how their unification results in waves that we call light. It then describes more advanced topics such as superconductors, monopoles, radiation, and electromagnetism in matter. The book concludes with a detailed review of the mathematics of vector calculus.
The fundamentals of electromagnetism are simple. Moving electric charges set up electric and magnetic fields. In turn, these fields make the charges move. This dance between charges and fields is described by the Maxwell equations. This brief chapter describes how this comes about. It is, in a sense, everything you need to know about electromagnetism, enshrined in these simple equations. The rest of the book is mere commentary.
To understand what the Maxwell equations are telling us, it’s useful to dissect them piece by piece. The simplest piece comes from looking at stationary electric charges and how they give rise to electric fields. A consequence of this is the Coulomb force law between charges. This, and much more, will be described in this chapter.
We report the lattice parameters and cell volume for cristobalite powder added at 35 wt% to Ba-Al-Silicate glass (CGI930) as reflowed bulk glass bars where the embedded cristobalite phase is constrained within the glass matrix. Analysis confirms that the room temperature lattice parameters and cell volume obtained for the bulk glass–ceramic are larger compared with single-phase cristobalite powders. The increased volume of the cristobalite phase in a glass matrix is driven by tensile stresses developed at the interface between the cristobalite and matrix glass phase, and this stress impacts the phase transition temperature and thermal hysteresis of the cristobalite phase. In situ high-temperature measurements confirm that the tetragonal to cubic α–β phase transformation of the cristobalite phase within the glass matrix is ~195 °C with complete suppression of hysteresis behavior. In contrast, bulk glass–ceramic material ground to a powder form displays the expected thermal hysteresis behavior and more comparable phase transition temperatures of 245 °C on heating and 220 °C on cooling. Isothermal holds at varying temperatures above or near the α–β phase transition suggest that the cristobalite phase does not undergo significant relaxation within the matrix phase to reduce accumulated stress imposed by the constraining matrix glassy phase.
Viscous fingering instabilities, common in confined environments such as porous media or Hele-Shaw cells, surprisingly also occur in unconfined, non-porous settings as revealed by recent experiments. These novel instabilities involve free-surface flows of dissimilar viscosity. We demonstrate that such a free-surface flow, involving a thin film of viscous fluid spreading over a substrate that is prewetted with a fluid of higher viscosity, is susceptible to a similar type of novel viscous fingering instability. Such flows are relevant to a range of geophysical, industrial and physiological applications from the small scales of thin-film coating applications and nasal drug delivery to the large scales of lava flows. In developing a theoretical framework, we assume that the intruding layer and the liquid film over which it flows are both long and thin, the effects of inertia and surface tension are negligible, and both layers are driven by gravity and resisted by viscous shear stress so that the principles of lubrication theory hold. We investigate the stability of axisymmetric similarity solutions, describing the base flow, by examining the growth of small-amplitude non-axisymmetric perturbations. We characterise regions of instability across parameter space and find that these instabilities emerge above a critical viscosity ratio. That is, a fluid of low viscosity intruding into another fluid of sufficiently high viscosity is susceptible to instability, akin to traditional viscous fingering in a porous medium. We identify the mechanism of instability, compare with other frontal instabilities and demonstrate that high enough density differences suppress the instability completely.
The crystal structure of palovarotene has been solved and refined using synchrotron X-ray powder diffraction data and optimized using density functional theory techniques. Palovarotene crystallizes in the space group P-1 (#2) with a = 10.2914(4), b = 11.8318(7), c = 11.9210(5) Å, α = 66.2327(11), β = 82.5032(9), γ = 65.3772(9)°, V = 1,206.442(28) Å3, and Z = 2 at 298 K. The crystal structure consists of chains of O–H···N hydrogen-bonded palovarotene molecules along the <0,−1,1 > axis; the graph set is C1,1(14). The powder pattern has been submitted to the International Centre for Diffraction Data® for inclusion in the Powder Diffraction File™ (PDF®).
Riblets are a well-known passive drag reduction technique with the potential for as much as $9\, \%$ reduction in the frictional drag force in laboratory settings, and proven benefits for large-scale aircraft. However, less information is available on the applicability of these textures for smaller air/waterborne vehicles where assumptions such as periodicity and/or the asymptotic nature of the boundary layer (BL) no longer apply and the shape of the bodies of these vehicles can give rise to moderate levels of pressure drag. Here, we explore the effect of riblets on both sides of a finite-size foil consisting of a streamlined leading edge and a flat body in the Reynolds number range of $12\,200$–$24\,200$. We use high-resolution two-dimensional, two-component particle image velocimetry, with a double illumination and a consecutive-overlapping imaging technique to capture the velocity field in both the BL and the far field. We find the local velocity profiles and shear stress distribution, as well as the frictional and pressure components of the drag force and show the possibility of achieving reduction in both the frictional and pressure components of the drag force and record a maximum cumulative drag reduction of up to $6.5\, \%$. We present the intertwined relationship between the distribution of the spanwise-averaged shear stress distribution, the characteristics of the velocity profiles and the pressure distribution around the body, and how the local distribution of these parameters work together or against each other in enhancing or diminishing the drag-reducing ability of the riblets for the entirety of the body of interest.
We investigate the dynamics, wake instabilities and regime transitions of inertial flow past a transversely rotating angular particle. We first study the transversely rotating cube with a four-fold rotational symmetry axis (RCF4), elucidating the mechanisms of vortex generation and the merging process on the cube surface during rotation. Our results identify novel vortex shedding structures and reveal that the rotation-enhanced merging of streamwise vortex pairs is the key mechanism driving vortex suppression. The flow inertia and particle rotation are demonstrated to be competing factors that influence wake instability. We further analyse the hydrodynamic forces on the rotating cube, with a focus on the Magnus effect, highlighting the influence of sharp edges on key parameters such as lift, drag, rotation coefficients and the shedding frequency. We note that the lift coefficient is independent of flow inertia at a specific rotation rate. We then examine more general angular particles with different numbers of rotational symmetry folds – RTF3 (three-fold tetrahedron), RCF3 (three-fold cube) and ROF4 (four-fold octahedron) – to explore how particle angularity and rotational symmetry affect wake stability, regime transitions and hydrodynamic forces. We show that the mechanisms of vortex generation and suppression observed in RCF4 apply effectively to other angular particles, with the number of rotational symmetry folds playing a crucial role in driving regime transitions. An increased rotational symmetry fold enhances vortex merging and suppression. Particle angularity has a pronounced influence on hydrodynamic forces, with increased angularity intensifying the Magnus effect. Furthermore, the number of effective faces is demonstrated to have a decisive impact on the shedding frequency of the wake structures. Based on the number of effective faces during rotation, we propose a generic model to predict the Strouhal number, applicable to all the angular particles studied. Our results demonstrate that the particle angularity and rotational symmetry can be effectively harnessed to stabilise the wake flow. These findings provide novel insights into the complex interactions between particle geometry, rotation and flow instability, advancing the understanding of the role sharp edges play in inertial flow past rotating angular particles.
This study proposes a machine-learning-based subgrid scale (SGS) model for very coarse-grid large-eddy simulations (vLES). An issue with SGS modelling for vLES is that, because the energy-containing eddies are not accurately resolved by the computational grid, the resolved turbulence deviates from the physically accurate turbulence. This limits the use of supervised machine-learning models commonly trained using pairs of direct numerical simulation (DNS) and filtered DNS data. The proposed methodology utilises both unsupervised learning (cycle-consistency generative adversarial network (GAN)) and supervised learning (conditional GAN) to construct a machine-learning pipeline. The unsupervised learning part of the proposed method first transforms the non-physical vLES flow field to resemble a physically accurate flow field. The second supervised learning part employs super-resolution of turbulence to predict the SGS stresses. The proposed pipeline is trained using a fully developed turbulent channel at the friction Reynolds number of approximately 1000. The a priori validation shows that the proposed unsupervised–supervised pipeline successfully learns to predict the accurate SGS stresses, while a typical supervised-only model shows significant discrepancies. In the a posteriori test, the proposed unsupervised–supervised-pipeline SGS model for vLES using a progressively coarse grid yields good agreement of the mean velocity and Reynolds shear stress with the reference data at both the trained Reynolds number 1000 and the untrained higher Reynolds number 2000, showing robustness against varying Reynolds numbers. A budget analysis of the Reynolds stresses reveals that the proposed unsupervised–supervised-pipeline SGS model predicts a significant amount of SGS backscatter, which results in the strengthened near-wall Reynolds shear stress and the accurate prediction of mean velocity.
The full beauty of Maxwell equations only becomes apparent when we realise that they are consistent with Einstein’s theory of special relativity. The purpose of this chapter is to make this relationship manifest. We rewrite the Maxwell equations in relativistic notation, where the four vector calculus equations are condensed into one, simple tensor equation. Viewed through the lens of relativity and gauge theory, the Maxwell equations are forced upon us: the world can’t be any other way.