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Classical nucleation theory (CNT) models clusters of all sizes as structureless, spherical liquid droplets, having the same surface tension as a flat surface of the bulk liquid in equilibrium with its vapor at the same temperature – the “capillarity approximation.” The cluster free energy is divided into volume and surface contributions, and the rate of monomer addition to a cluster per unit area is equated to the flux of molecules to a plane in an ideal gas. Under these assumptions, together with several mathematical approximations, the summation expression for the steady-state nucleation rate is converted to a closed-form analytical expression for the nucleation rate as a function of temperature, saturation ratio, and substance properties. Comparing the nucleation rate predicted by CNT to experimental results for many substances, one finds considerable disagreement in terms of the magnitude of the nucleation rate as well as the qualitative dependence of nucleation rate on both temperature and saturation ratio. Analyzing the possible sources of this discrepancy, by far the major source of error is the liquid droplet model for the Gibbs free energy of cluster formation.
The economic, political, strategic and cultural dynamism in Southeast Asia has gained added relevance in recent years with the spectacular rise of giant economies in East and South Asia. This has drawn greater attention to the region and to the enhanced role it now plays in international relations and global economics.
The sustained effort made by Southeast Asian nations since 1967 towards a peaceful and gradual integration of their economies has had indubitable success, and perhaps as a consequence of this, most of these countries are undergoing deep political and social changes domestically and are constructing innovative solutions to meet new international challenges. Big Power tensions continue to be played out in the neighbourhood despite the tradition of neutrality exercised by the Association of Southeast Asian Nations (ASEAN).
The Trends in Southeast Asia series acts as a platform for serious analyses by selected authors who are experts in their fields. It is aimed at encouraging policymakers and scholars to contemplate the diversity and dynamism of this exciting region.
The momentum on methane reduction is picking up as governments and private sectors acknowledge its crucial role in meeting the Paris Agreement goals. The International Energy Agency (IEA) has called for fossil fuel methane emissions to be cut by 75 per cent by 2030 to keep the 1.5-degree goal in sight. Compared to carbon dioxide, methane (the second most abundant greenhouse gas) has a much stronger impact on warming temperatures. Within a 100-year time horizon, a tonne of methane in the atmosphere could cause about twenty-five times the warming as the same amount of carbon dioxide. So far, methane has accounted for about 30 per cent of global temperature rise since the Industrial Revolution.
Methane is emitted in a wide variety of human activities, especially in the agricultural, energy and waste sectors. 40 per cent of anthropogenic methane emissions are traced to the energy sector, including coal mining as well as multiple stages in the oil and gas supply chain. Fossil fuel production and usage contributed 118 Mt of global methane emissions (equivalent to 2,950 MtCO2e of emissions) in 2023. Methane emissions in the coal sector come from leakages in coal mines, while emissions in the oil and gas sector mostly come from leakages or routine flaring (burning) and venting of gases. Besides being the second-largest contributing sector to methane emissions, around 40 per cent of annual fossil fuel methane emissions can be avoided using current technologies at no net cost, giving it considerable methane abatement potential compared to other sectors like waste or agriculture. This has led some to describe methane abatement in the energy sector as a “low-hanging fruit” for climate action.
In Southeast Asia, the agriculture sector contributed the largest share of methane emissions (over 51 per cent) followed by the waste sector (25 per cent) and fugitive emissions from the coal mining, oil and gas sectors (18 per cent) in 219. Fugitive emissions make up a significant share of emissions for Brunei (88 per cent), Malaysia (31 per cent), Indonesia (25 per cent) and Singapore (23 per cent). While accounting for a smaller portion of Vietnam's (15 per cent) and Thailand's (16 per cent) overall methane emissions, they still amount to large quantities. For instance, Vietnam emitted 80.9 MtCO2e of methane overall, of which 48.1 MtCO2e were fugitive emissions—similar to that of Malaysia. As such, methane is an area of concern for all six countries.
This introduction to robotics offers a distinct and unified perspective of the mechanics, planning and control of robots. Ideal for self-learning, or for courses, as it assumes only freshman-level physics, ordinary differential equations, linear algebra and a little bit of computing background. Modern Robotics presents the state-of-the-art, screw-theoretic techniques capturing the most salient physical features of a robot in an intuitive geometrical way. With numerous exercises at the end of each chapter, accompanying software written to reinforce the concepts in the book and video lectures aimed at changing the classroom experience, this is the go-to textbook for learning about this fascinating subject.
The transition route and bifurcations of the buoyant flows developing on a heated horizontal circular surface are elaborated using direct numerical simulations and direct stability analysis. A series of bifurcations, as a function of Rayleigh numbers ($Ra$) ranging from $10^6$ to $6.0\times 10^7$, are found on the route to chaos of the flows at $Pr=7$. When $Ra<1.0\times 10^3$, the buoyant flows above the heated horizontal surface are dominated by conduction, because of which the distinct thermal boundary layer and plume are not present. At $Ra=1.1\times 10^6$, a Hopf bifurcation occurs, resulting in the flow transition from a steady state to a periodic puffing state. As $Ra$ increases further, the flow enters a periodic rotating state at $Ra=1.9\times 10^6$, which is a unique state that was rarely discussed in the literature. These critical transitions, leaving from a steady state and subsequently entering a series of periodic states (puffing, rotating, flapping and period-doubling) and finally leading to chaos, are diagnosed using two-dimensional Fourier transforms. Moreover, direct stability analysis is conducted by introducing random numerical perturbations into the boundary condition of the surface heating. We find that when the state of a flow is in the vicinity of critical values (e.g. $Ra=2.0\times 10^6$), the flow is conditionally unstable to perturbations, and it can bifurcate from the rotating state to the flapping state in advance. However, for relatively stable flow states, such as at $Ra=1.5\times 10^6$, the flow remains in its periodic puffing state even though it is being perturbed.
There are instances when an aircraft encounters a bird’s flock or faces a heavy hailstorm, causing the windshield to sustain consecutive impacts. Therefore, the investigation of windshield resistance against repeated impacts is crucial. In this research, various tests such as tensile, split Hopkinson pressure bar (SHPB), and three-point bending are conducted to extract the mechanical properties of the materials used in a five-layers windshield under high strain rates. Using this information, the bird impact on the windshield is simulated using the smooth particle hydrodynamics (SPH) method, and the results are compared with real bird impact test outcomes, and the validation of this simulation is confirmed. The simulation of two consecutive bird strikes indicates the current windshield lacks sufficient resistance against successive dual impacts; in such scenarios, the second bird penetrates the windshield after breaking it and tearing the interlayer. Considering new materials and thicknesses for each windshield layer, a Taguchi experimental design method is employed to examine various layer arrangements with different materials and thicknesses. The configurations in which the windshield can withstand a maximum of three bird impacts in succession are identified. Subsequently, using the “the smaller, the better” criterion in the Taguchi optimisation approach, the configuration that not only prevents bird penetration but also minimises the maximum strain in the inner layer is selected as the desired outcome. Thus, a new five-layer windshield with new materials and thicknesses is presented, which is resistant to the repeated collision of up to three birds, tearing in the interlayer and bird penetration does not happen.
X-ray diffraction (XRD) characterization of Si powder was carried out using synchrotron and laboratory sources. Microstructural (size-strain) analyses of XRD patterns were carried out using the Rietveld refinement method. Experimentally observed super-Lorentzian shapes of the XRD peaks of Si powder were examined using multimodal profile fitting and bimodal model was found to be adequate. The two components obtained using a bimodal approach are referred as narrow and broad profiles based on their estimated relative peak widths. Peak shapes of crystallite size-dependent parts of narrow and broad profiles were found to be almost Gaussian and Lorentzian in nature, respectively. The simultaneous presence of such peak shapes corresponding to a bimodal microstructure is uncommon in literature. Therefore, in order to explore the role of different natures of XRD peak shapes (size dependent) of the bimodal profiles of Si, detailed microstructural analysis was carried out using the complementary method of whole powder pattern modeling (WPPM) and found to be related to the variance of crystallites' size distribution. Additionally, the effect of instrument resolution (laboratory and synchrotron sources) on the microstructural parameters was also studied. Scanning and transmission electron microscopy were used to characterize the morphology of Si powder and correlate with the microstructural findings of XRD methods.
We explore predictions of two models of one-dimensional capillary rise in rigid and partially saturated porous media. One is an existing one from the literature and the second is a free-boundary model based on Richards’ equation with two moving boundaries of the evolving partially saturated region. Both models involve the specification of saturation-dependent functions for local capillary pressure and permeability and connect to classical models for saturated porous media. Existing capillary-rise experiments show two notable regimes: (i) an early-time regime typically well-described by classical capillary-rise theory in a fully saturated porous media, and (ii) a long-time regime that has anomalous dynamics in which the capillary-rise height may scale with a non-classical power law in time or have more complicated dynamics. We demonstrate that the predictions of both models compare well with experimental capillary-rise data over early- and long-time regimes gathered from three independent studies in the literature. The model predictions also shed light on recent scaling laws that relate the capillary pressure and permeability of the partially saturated media to the capillary-rise height. We use these models to probe computationally observed permeability relationships to capillary-rise height. We demonstrate that a recently proposed permeability scaling for the anomalous capillary-rise regime is indeed realized and is particularly apparent in the lower portion of the partially saturated media. For our free-boundary model we also compute capillary pressure measures and show that these reveal the linear relation between the capillary pressure and capillary-rise height expected for a capillarity–gravity balance in the upper portion of the partially saturated porous media.
Utilizing the discrete element method and the pore network model, we numerically investigate the impact of compaction on the longitudinal dispersion coefficient of porous media. Notably, the dispersion coefficient exhibits a non-monotonic dependence on the degree of compaction, which is distinguished by the presence of three distinct regimes in the variation of dispersion coefficient. The non-monotonic variation of dispersion coefficient is attributed to the disparate effect of compaction on dispersion mechanisms. Specifically, the porous medium tightens with an increasing pressure load, reducing the effect of molecular diffusion that primarily governs at small Péclet numbers. On the other hand, heightened pressure loads enhance the heterogeneity of pore structures, resulting in increased disorder and a higher proportion of stagnant zones within porous media flow. These enhancements further strengthen mechanical dispersion and hold-up dispersion, respectively, both acting at higher Péclet numbers. It is crucial to highlight that hold-up dispersion is induced by the low-velocity regions in porous media flow, which differ fundamentally from zero-velocity regions (such as dead-ends or the interior of permeable grains) as described by the classical theory of dispersion. The competition between weakened molecular diffusion and enhanced hold-up dispersion and mechanical dispersion, together with the shift in the dominance of dispersion mechanisms across various Péclet numbers, results in multiple regimes in the variation of dispersion coefficients. Our study provides unique insights into structural design and modulation of the dispersion coefficient of porous materials.
We use $123$ three-dimensional direct numerical simulations to study fingering convection in non-rotating spherical shells. We investigate the scaling behaviour of the flow length scale, the non-dimensional heat and compositional fluxes $Nu$ and $Sh$ and the mean convective velocity over the fingering convection instability domain defined by $1 \leq R_\rho < Le$, $R_\rho$ being the ratio of density perturbations of thermal and compositional origins and $Le$ the Lewis number. We show that the chemical boundary layers are marginally unstable and adhere to the laminar Prandtl–Blasius model, hence explaining the asymmetry between the inner and outer spherical shell boundary layers. We develop scaling laws for two asymptotic regimes close to the two edges of the instability domain, namely $R_\rho \lesssim Le$ and $R_\rho \gtrsim 1$. For the former, we develop novel power laws of a small parameter $\epsilon$ measuring the distance to onset, which differ from theoretical laws published to date in Cartesian geometry. For the latter, we find that the Sherwood number $Sh$ gradually approaches a scaling $Sh\sim Ra_\xi ^{1/3}$ when $Ra_\xi \gg 1$; and that the Péclet number accordingly follows $Pe \sim Ra_\xi ^{2/3} |Ra_T|^{-1/4}$, $Ra_T$ and $Ra_{\xi}$ being the thermal and chemical Rayleigh numbers. When the Reynolds number exceeds a few tens, we report on a secondary instability which takes the form of large-scale toroidal jets which span the entire spherical domain. Jets distort the fingers, resulting in Reynolds stress correlations, which in turn feed the jet growth until saturation. This nonlinear phenomenon can yield relaxation oscillation cycles.
We investigate two-dimensional (2-D) axisymmetric flow in toroidal geometry, with a focus on a transition between 2-D three-component flow and 2-D two-component flow. This latter flow state allows a self-organization of the system to a quiescent dynamics, characterized by long-living coherent structures. When these large-scale structures orient in the azimuthal direction, the radial transport is reduced. Such a transition, if it can be triggered in toroidally confined fusion plasmas, is beneficial for the generation of zonal flows and should consequently result in a flow field beneficial for confinement.
We present experiments on oscillating hydrofoils undergoing combined heaving and pitching motions, paying particular attention to connections between propulsive efficiency and coherent wake features extracted using modal analysis. Time-averaged forces and particle image velocimetry measurements of the flow field downstream of the foil are presented for a Reynolds number of $Re=11\times 10^3$ and Strouhal numbers in the range $St=0.16\unicode{x2013}0.35$. These conditions produce 2S and 2P wake patterns, as well as a near-momentumless wake structure. A triple decomposition using the optimized dynamic mode decomposition method is employed to identify dominant modal components (or coherent structures) in the wake. These structures can be connected to wake instabilities predicted using spatial stability analyses. Examining the modal components of the wake provides insightful explanations into the transition from drag to thrust production, and conditions that lead to peak propulsive efficiency. In particular, we find modes that correspond to the primary vortex development in the wakes. Other modal components capture elements of bluff body shedding at Strouhal numbers below the optimum for peak propulsive efficiency and characteristics of separation for Strouhal numbers higher than the optimum.
Aging ships and offshore structures face harsh environmental and operational conditions in remote areas, leading to age-related damages such as corrosion wastage, fatigue cracking, and mechanical denting. These deteriorations, if left unattended, can escalate into catastrophic failures, causing casualties, property damage, and marine pollution. Hence, ensuring the safety and integrity of aging ships and offshore structures is paramount and achievable through innovative healthcare schemes. One such paradigm, digital healthcare engineering (DHE), initially introduced by the final coauthor, aims at providing lifetime healthcare for engineered structures, infrastructure, and individuals (e.g., seafarers) by harnessing advancements in digitalization and communication technologies. The DHE framework comprises five interconnected modules: on-site health parameter monitoring, data transmission to analytics centers, data analytics, simulation and visualization via digital twins, artificial intelligence-driven diagnosis and remedial planning using machine and deep learning, and predictive health condition analysis for future maintenance. This article surveys recent technological advancements pertinent to each DHE module, with a focus on its application to aging ships and offshore structures. The primary objectives include identifying cost-effective and accurate techniques to establish a DHE system for lifetime healthcare of aging ships and offshore structures—a project currently in progress by the authors.
Cowl-induced incident shock wave/boundary layer interactions (ISWBLIs) under the influence of shoulder expansion represent one of the dominant phenomena in supersonic inlets. To provide a more comprehensive understanding of how an expansion corner affects the ISWBLI, a detailed experimental and analytical study is performed in a Mach 2.73 flow in this work. Pressure measurement, schlieren photography and surface oil-flow visualisation are used to record flow features, including the pressure distribution, separation extent and surface-flow topological structures. Our results reveal three types of ISWBLIs influenced by the expansion corner. When the shock intensity is weak, the separation is small scale with the expansion waves emanating from the expansion corner. This is the first type of expansion-corner-affected ISWBLI (EC-ISWBLI). When the incident shock wave is strong, large-scale separation occurs, accompanied by the disappearance of expansion waves, forming the second type of EC-SWBLI. The expansion corner induces a ‘lock-in’ effect in which the separation onset is consistently locked near the expansion corner regardless of the incident shock intensity and impingement position. The third type of EC-ISWBLI occurs when the shock is sufficiently strong and the impingement point is close to the expansion corner. In this interaction, the ‘lock-in’ effect ceases to manifest. Moreover, a shock polar-incorporating inviscid model is employed to elucidate the shock patterns. Two criteria are established by combining free interaction theory with this model. The first criterion provides valuable insights into the evolution of separations with a minimal overall pressure rise and the second criterion determines the threshold for the occurrence of the ‘lock-in’ effect.
Axial fans are vital accessories in aircraft ventilation systems, but, they may experience erosion from particulate flows, causing a decline in effectiveness over time. This study investigated the trajectories of two types of sand particles and erosion in an axial fan stage, considering the relative position of the blades facing the inlet guide vanes.
The movement of particles was simulated using an in-house code that implements a Lagrangian approach along with a stochastic particle-eddy interaction model. The flow field was solved separately and the flow data was transferred to the particle trajectory code. The finite element method allowed for the tracking of particles through the computational cells and accurate determination of their impact positions. A semi-empirical erosion correlation was used to evaluate the local erosion rates, mass removal, and geometry deterioration.
As a result, the rotor exhibits a high frequency of impacts and significant erosion on the leading edge of the blade, extending to the upper corner of the pressure side and blade tip, as well as the front of the suction side. In the inlet guide vane, the erosion is spread out along the entire pressure side but at lower erosion rates compared to the rotor blade. The erosion patterns obtained at different pitch-wise positions were cumulated to get better representation of erosion patterns. After being exposed to MIL-E5007E sand (0–1000 $\unicode{x03BC}$m) at the highest concentration for 10 hours, the blade experienced a reduction of a 0.29% in mass, a 0.45% decrease in tip chord, and a 0.23% increase in tip clearance. On the other hand, AC-coarse sand (0–200 μm) resulted in a 0.23% decrease in blade mass, a 0.4% reduction in tip chord, and a 0.16% increase in tip clearance.
The data that is available can be used to monitor the lifespan of axial fans of similar design and select appropriate coatings to protect against erosion.
The turbulent boundary layer (TBL) is a widely existing flow phenomenon in nature and engineering applications. Its strong mixing effect can achieve more sufficient material mixing, heat transport, etc. The understanding of the entrainment process and mechanism of irrotational fluids entering the turbulent region can be promoted by studying the geometric and dynamic characteristics of turbulent${/}$non-turbulent interfaces (TNTI). In compressible flow, it is unclear whether the properties of TNTI will change and whether the entrainment will show different features due to the influence of compressibility. Based on the direct numerical simulation results of supersonic compressible plate TBLs with Mach number of 2.9, the geometric and dynamic characteristics of TNTI are investigated in this paper. The interface is identified by the enstrophy method, and the height, thickness, fractal dimension, enstrophy transportation and entrainment characteristics of the interface are investigated. It is found that for the enstrophy transportation in a TBL, the contribution of compressibility-related terms accounts for approximately 13.4 % of the total enstrophy transportation, which tends to transfer the enstrophy of turbulence near the interface to both directions vertical to the interface. This promotes the expansion of the turbulent region towards the non-turbulent region, and the mean height, thickness and entrainment velocity are increased by approximately 3.7 %, 7.0 % and 8.5 %, respectively, while the fractal dimension is basically unaffected. Different from the incompressible flow, the contribution of the compressibility-related terms to the entrainment velocity is independent of the local curvature, and the intense entrainment process is more likely to occur on a highly curved concave surface.
In the present study, we performed direct numerical simulations for a hypersonic turbulent boundary layer over the windward side of a lifting body, the HyTRV model, at Mach number $6$ and attack angle 2$^{\circ }$ to investigate the global and local turbulent features, and evaluate its difference from canonical turbulent boundary layers. By scrutinizing the instantaneous and averaged flow fields, we found that the transverse curvature on the windward side of the HyTRV model induces the transverse opposing pressure gradients that push the flow on both sides towards the windward symmetry plane, yielding significant effects of the azimuthal inhomogeneity and large-scale cross-stream circulations, moderate and azimuthal independent influences of adverse pressure gradient, and negligible impact of the mean flow three-dimensionality. Further inspecting the local turbulent statistics, we identified that the mean and fluctuating velocity become increasingly similar to the highly decelerated turbulent boundary layers over flat plates in that the mean velocity deficit is enhanced, and the outer layer Reynolds stresses are amplified as it approaches the windward symmetry plane, and prove to be self-similar under the scaling of Wei & Knopp (J. Fluid Mech., vol. 958, 2023, A9) for adverse-pressure-gradient turbulent boundary layers. Conditionally averaged Reynolds stresses based on strong sweeping and ejection events demonstrated that the Kelvin–Helmholtz instability of the strong embedded shear layer induced by the large-scale cross-stream circulations is responsible for the turbulence amplification in the outer layer. The strong Reynolds analogy that relates the mean velocity and temperature was refined to incorporate the non-canonical effects, showing considerable improvements in the accuracy of such a formula. On the other hand, the temperature fluctuations are still transported passively, as indicated by their resemblance to the velocity. The conclusions obtained in the present study provide potentially profitable information for turbulent modelling modification for the accurate predictions of skin friction and wall heat transfer.
In the double-cone ignition scheme of inertial confinement fusion, the head-on collision of two compressed fuel jets from the cone-tips forms an isochoric plasma, which is then heated suddenly by a MeV relativistic electron beam produced by ultra-intense picosecond laser pulses. This fast-heating process was studied experimentally at the Shenguang II upgrade laser facility. By observing temporal-resolved X-ray emission and the spatial-resolved X-ray spectrum, the colliding process and heating process are carefully studied. The colliding plasma was imaged to have dimensions of approximately 86 μm in the implosion direction and approximately 120 μm in the heating direction. By comparing the simulated plasma X-ray spectrum with experimental data, the electron temperature of the heated plasma was found to rapidly increase to 600 ± 50 eV, almost doubling the temperature achieved before the heating laser incidence.
This paper systematically investigated the impact mechanisms of proton irradiation, atomic oxygen irradiation and space debris collision, both individually and in combination, on the laser damage threshold and damage evolution characteristics of HfO2/SiO2 triple-band high-reflection films and fused silica substrates using a simulated near-Earth space radiation experimental system. For the high-reflection film samples, the damage thresholds decreased by 15.38%, 13.12% and 46.80% after proton, atomic oxygen and simulated space debris (penetration) irradiation, respectively. The coupling irradiation of the first two factors resulted in a decrease of 26.93%, while the combined effect of all the three factors led to a reduction of 63.19%. Similarly, the fused silica substrates exhibited the same pattern of laser damage performance degradation. Notably, the study employed high-precision fixed-point in situ measurement techniques to track in detail the microstructural changes, surface roughness and optical-thermal absorption intensity before and after proton and atomic oxygen irradiation at the same location, thus providing a more accurate and comprehensive analysis of the damage mechanisms. In addition, simulations were conducted to quantitatively analyze the transmission trajectories and concentration distribution lines of protons and atomic oxygen incident at specific angles into the target material. The research findings contribute to elucidating the laser damage performance degradation mechanism of transmissive elements in near-Earth space environments and provide technical support for the development of high-damage-threshold optical components resistant to space radiation.