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This chapter reviews the Boltzmann equation, which is a starting point for some of the key results in cosmology. We introduce a general version of the Boltzmann equation, then study its implications in the simple scenario of a few interacting particles. We introduce the concept of a freezeout of particle species, and illustrate it using a simple example. We end the chapter by discussing baryogenesis (the process that generated the excess of baryons over antibaryons), and Sakharov conditions for successful baryogenesis to take place.
We study the evolution of particle species throughout the history of the universe. We introduce the phase-space distribution function, and review basic concepts in statistical mechanics as applied to early-universe cosmology, including thermal equilibrium, entropy, and chemical potential. We calculate the effective number of relativistic species, and show how it varies as a function of time.
We give a broad-brush overview of cosmology, including a timeline of events starting from the Big Bang until the present day. We introduce the three pillars of the Big Bang cosmological model, the concepts of homogeneity and isotropy, as well as parsec as a unit of distance. We also introduce natural units, and develop intuition on how to adopt and use them.
Here we review dark energy, the component that causes accelerated expansion of the universe. We start by reviewing the history of this fascinating discovery, describing in detail how type Ia supernovae were used to measure the expansion rate and find that the expansion is speeding up. We then outline modern evidence for the existence of dark energy, how dark energy is parametrically described, and what its phenomenological properties are. We review the cosmological-constant problem that encapsulates the tiny size of dark energy relative to expectations from particle physics. Next we introduce physical candidates for dark energy, including scalar fields and modified gravity. We end by explaining the controversial anthropic principle, and describe the possible future expansion histories of the universe dominated by dark energy.
The incompressible motion of viscoplastic fluid between two semi-infinite rigid plates, hinged at their ends and rotating towards one another at constant angular velocity, generates self-similar flow fields because there is no externally imposed length scale in the absence of inertia. The magnitude of the strain rate scales with the angular velocity of the plates and the dimensionless deviatoric stresses are functions only of the polar angle and a dimensionless measure of the yield stress; they are independent of the radial distance from the corner. These flows feature unyielded regions adjacent to the boundaries for sufficiently large angles between the plates. Moreover, when the dimensionless yield stress is large, there are viscoplastic boundary layers that are attached to the boundary or the plug, the asymptotic structures of which are constructed.
Neutrinos have an important role in cosmology, and here we review them in some detail. We review the fascinating history of how neutrinos were first proposed then detected. We then mathematically describe neutrino oscillations. We describe decoupling of neutrinos from the thermal bath, point out the likely existence of the cosmic neutrino background, and discuss prospects for detecting it directly.
A droplet charged above the Rayleigh limit is unstable. In the resulting dynamical process, referred to as a Coulomb explosion, smaller droplets with higher charge-to-mass ratios are ejected, reducing the charge of the parent droplet below the Rayleigh limit. Furthermore, if the droplet is sufficiently small, the electric field on its surface can promote ion field emission. Ion emission can lower the charge of a spherical droplet below its Rayleigh limit, keeping it stable, or reduce the charge of a deforming droplet, changing its dynamics and potentially preventing the Coulomb explosion. This article develops a continuum phase field electrohydrodynamic model to study the interplay between Coulomb explosions and ion emission, using charged nanodroplets of the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMI-Im) as a case study. In small droplets (diameter $D \lesssim 20$ nm for EMI-Im), the electric field is strong enough to emit ions in the early phase of the droplet's evolution, suppressing the Coulomb explosion. For $20 \lesssim D \lesssim 45$ nm, the electric field on the EMI-Im droplet may not promote significant ion emission; however, as the unstable droplet becomes ellipsoidal, ions are emitted from its vertices, ultimately suppressing the Coulomb explosion while shedding $20\unicode{x2013}40\,\%$ of the initial charge. For larger EMI-Im droplets, $45 \lesssim D \lesssim 100$ nm, the evolution typical of a Coulomb explosion is observed, accompanied by ion emission which is however insufficient to prevent the Coulomb explosion. Ion emission and the smaller progeny droplets account for $24\,\%$ and $16\,\%$ of the initial charge, respectively.
Phosphorus nitride (PN) is believed to be one of the major reservoirs of phosphorus in the interstellar medium (ISM). For this reason, understanding which reactions produce PN in space and predicting their rate coefficients is important for modelling the relative abundances of P-bearing species and clarifying the role of phosphorus in astrochemistry. In this work, we explore the potential energy surfaces of the $\textrm{P}(^4\textrm{S}) + \textrm{NH}(^3\Sigma^-)$ and $\textrm{N}(^4\textrm{S}) + \textrm{PH}(^3\Sigma^-)$ reactions and the formation of $\textrm{H}(^2\textrm{S}) + \textrm{PN}(^1\Sigma^+)$ through high accuracy ab initio calculations and the variable reaction coordinate transition state theory (VRC-TST). We found that both reactions proceed without an activation barrier and with similar rate coefficients that can be described by a modified Arrhenius equation ($k(T)=\alpha\!\left( T/300 \right)^{\beta} \exp\!{(\!-\!\gamma/T)})$ with $\alpha=0.93\times 10^{-10}\rm cm^3\,s^{-1}$, $\beta=-0.18$ and $\gamma=0.24\, \rm K$ for the $\textrm{P} + \textrm{NH} \longrightarrow \textrm{H} + \textrm{PN}$ reaction and $\alpha=0.88\times 10^{-10}\rm cm^3\,s^{-1}$, $\beta=-0.18$ and $\gamma=1.01\, \rm K$ for the $\textrm{N} + \textrm{PH} \longrightarrow \textrm{H} + \textrm{PN}$ one. Both reactions are expected to be relevant for modelling PN abundances even in the cold environments of the ISM. Given the abundance of hydrogen in space, we have also predicted rate coefficients for the destruction of PN via H + PN collisions.
We numerically study the impact of a droplet on superhydrophobic flexible plates, aiming to understand how the flexible substrate influences the maximum spreading of the droplet. Compared with the rigid case, the vertical movement of the flexible substrate due to droplet impact reduces the maximum spreading. Besides, the average acceleration $a$ during droplet spreading changes significantly. Arising from energy conservation, we rescale the acceleration $a$ for cases with different bending stiffness $K_B$ and mass ratio $M_r$. Moreover, through theoretical analysis, we propose a scaling for the droplet's maximum spreading diameter ratio $\beta _{max}$. In the scaling, based on the derived $a$, an effective Weber number $We_m$ is well defined, which accounts for the substrate properties without any adjustable parameters. In the ($\beta _{max}, We_m$) plane, the two-dimensional numerical results of different $K_B$, $M_r$ and rigid cases all collapse into a single curve, as do the experimental and three-dimensional (3-D) results. In particular, the collapsed 3-D data can be well represented by the universal rescaling of $\beta _{max}$ proposed by Lee et al. (J. Fluid Mech., vol. 786, 2016, R4). Furthermore, an a posteriori energy analysis confirms the validation of our a priori scaling law.
For each central essential hyperplane arrangement $\mathcal{A}$ over an algebraically closed field, let $Z_\mathcal{A}^{\hat\mu}(T)$ denote the Denef–Loeser motivic zeta function of $\mathcal{A}$. We prove a formula expressing $Z_\mathcal{A}^{\hat\mu}(T)$ in terms of the Milnor fibers of related hyperplane arrangements. This formula shows that, in a precise sense, the degree to which $Z_{\mathcal{A}}^{\hat\mu}(T)$ fails to be a combinatorial invariant is completely controlled by these Milnor fibers. As one application, we use this formula to show that the map taking each complex arrangement $\mathcal{A}$ to the Hodge–Deligne specialization of $Z_{\mathcal{A}}^{\hat\mu}(T)$ is locally constant on the realization space of any loop-free matroid. We also prove a combinatorial formula expressing the motivic Igusa zeta function of $\mathcal{A}$ in terms of the characteristic polynomials of related arrangements.
Marangoni spreading on thin films is widely observed in nature and applied in industry. It has serious implications for airway drug delivery, especially in surfactant displacement therapy. This paper reports the results of experimental investigations of a surfactant-laden droplet spreading on films made of more viscous Newtonian fluids as well as on films made of viscoelastic fluids. The experiments used particle seeding, the transmission-speckle method and particle tracking velocimetry (PTV) to determine the deformation of the film–droplet interface and to measure velocity fields. Radially aligned patterns were observed on Newtonian films. Similar patterns, but with much smaller wavenumber, were observed on viscoelastic films in combination with rapid azimuthal variations of the film thickness. The Saffman–Taylor instability at the film–droplet interface explains the formation of patterns on a more viscous Newtonian film, and their onset requires exceeding the critical capillary number. The pattern formation on viscoelastic films is correlated with an instability at the film–droplet–air contact line when the liquid is expelled radially by the spreading droplet. PTV revealed azimuthal variations of the velocity field in the vicinity of the contact line. The observed contact line instability is different from previously reported fingering instabilities of Newtonian thin films. A simple scaling law accounting for the Marangoni-stress-induced elastic shear deformation is proposed to describe the flow field in the patterns formed in the viscoelastic films.
This study presents the spreading of a single filament of a yield stress (viscoplastic) fluid extruded onto a pre-wetted solid surface. The filaments spread laterally under surface tension forces until they reach a final equilibrium shape when the yield stress dominates. We use a simple experimental set-up to print the filaments on a moving surface and measure their final width using optical coherence tomography. Additionally, we present a scaling law for the final width and determine the corresponding prefactor using asymptotic analysis. We then analyse the level of agreement between the theory and experiments, and discuss the possible origins of discrepancies. The process studied here has applications in extrusion-based thermoplastic and bio-three-dimensional printing.
When a liquid drop falls on a solid substrate, the air layer between them delays the occurrence of liquid–solid contact. For impacts on smooth substrates, the air film can even prevent wetting, allowing the drop to bounce off with dynamics identical to that observed for impacts on superamphiphobic materials. In this paper, we investigate similar bouncing phenomena, occurring on viscous liquid films, that mimic atomically smooth substrates, with the goal to probe their effective repellency. We elucidate the mechanisms associated with the bouncing to non-bouncing (floating) transition using experiments, simulations, and a minimal model that predicts the main characteristics of drop impact, the contact time and the coefficient of restitution. In the case of highly viscous or very thin films, the impact dynamics is not affected by the presence of the viscous film. Within this substrate-independent limit, bouncing is suppressed once the drop viscosity exceeds a critical value, as on superamphiphobic substrates. For thicker or less viscous films, both the drop and film properties influence the rebound dynamics and conspire to inhibit bouncing above a critical film thickness. This substrate-dependent regime also admits a limit, for low-viscosity drops, in which the film properties alone determine the limits of repellency.