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Nonlinear dynamical systems often allow for multiple statistically stationary states for the same values of the control parameters. Herein, we introduce a framework that selectively eliminates specific nonlinear triad interactions, thereby suppressing emergence of a particular state, and enabling the emergence of another. The methodology is applied to yield the multiple convection-roll states in two-dimensional planar Rayleigh–Bénard convection (e.g. Wang et al., 2020, Phys. Rev. Lett., vol. 125, 074501) in the turbulent regime. The intrusive framework presented here is based on the observation that the characteristic wavenumber associated with the mean horizontal size of the convection rolls mediates triadic scale interactions resulting in both kinetic energy and temperature variance cascades that are dominant energy transfer processes in a statistically stationary state. Suppression of these cascades mediated by a candidate wavenumber hinders the formation of the convection rolls at that wavenumber. Consequently, convection rolls are formed at another candidate wavenumber which is allowed to mediate energy to establish the cascade processes. In case no stable convection-roll states are possible, this technique does not tend to yield any convection rolls, making it a suitable method for discovering multiple states. Whereas in previous investigations the signature of different states in the initial condition in simulations yielded the multiple states, the present method alleviates such dependence of the emergence of multiple states on initial conditions. It is also demonstrated that accurate predictions of statistical quantities, such as Nusselt number and volume-averaged Reynolds numbers, can also be obtained using this method. The convection-roll states yielded using this technique may be used as initial conditions for direct simulations quickly converging to the target roll state without taking long convergence routes involving state transitions. Additionally, because only one state can possibly emerge in each simulation, this technique can empirically designate each of the multiple states with respect to their stability.
This study is the first to investigate the intra- and interspecific differences in otolith’s length (Lo), width (Wo), perimeter (Po), area (Ao), and mass asymmetry (OMA) in the pelagic Ethmalosa fimbriata, demersal Galeoides decadactylus, and benthic Cynoglossus monodi collected from the Lebe fishing site located along the Komo Estuary, central-western Gabon. The objectives were to (1) verify whether or not otolith morphometry differs in relation to living depth levels of the three species, (2) examine fluctuating asymmetry (FA) in the otolith morphometry, and (3) assess the relationship between OMA and total length (TL). A significant asymmetry was found in Lo, Wo, Po, and Ao between the left and right otoliths within and among males and females at the intraspecific level and only in Wo and Ao at the interspecific level due to FA. At the intraspecies level, a significant OMA was only observed within females of G. decadactylus and C. monodi and males and females of E. fimbriata and C. monodi. Moreover, a significant relationship between OMA and TL was detected only among males and females within the pelagic E. fimbriata and the demersal G. decadactylus, and no significant relationship was found at the interspecific level. As a result, significant differences in Wo and Ao and non-significant differences in OMA were recorded between the three species based on variations in living depth levels. These results highlight the importance of using otolith morphometry and OMA analyses to address the relationship between fish species and their living depth levels.
The transient dynamics of a wake vortex, modelled as a strong swirling $q$-vortex, is investigated with a focus on optimal transient growth driven by continuous eigenmodes associated with continuous spectra. The pivotal contribution of viscous critical-layer eigenmodes (Lee and Marcus, J. Fluid Mech. vol. 967, 2023, p. A2) amongst the entire eigenmode families to optimal perturbations is numerically confirmed, using a spectral collocation method for a radially unbounded domain that ensures correct analyticity and far-field behaviour. The consistency of the numerical method across different sensitivity tests supports the reliability of the results and provides flexibility for tuning. Both axisymmetric and helical perturbations with axial wavenumbers of order unity or less are examined through linearised theory and nonlinear simulations, yielding results that align with existing literature on energy growth curves and optimal perturbation structures. The initiation process of transient growth is also explored, highlighting its practical relevance. Inspired by ice crystals in contrails, the backward influence of inertial particles on the vortex flow, particularly through particle drag, is emphasised. In the pursuit of optimal transient growth, particles are initially distributed at the periphery of the vortex core to disturb the flow. Two-way coupled vortex–particle simulations reveal clear evidence of optimal transient growth during ongoing vortex–particle interactions, reinforcing the robustness and significance of transient growth in the original nonlinear vortex system over finite time periods.
Supersonic free jets are extensively employed across a range of applications, especially in high-tech industries such as semiconductor processing and aerospace propulsion. Due to the difficulties involved in flow measurement, previous research on supersonic free jets has primarily focused on investigating near-field shockwave structures, with quantitative experimental analysis of the far-field zone being relatively scarce. However, physical understanding of the far-field flow, particularly post-shockwave energy dissipation, holds significant importance for the application and utilisation of these jets in vacuum environments. Therefore, this study aims to provide a robust experimental foundation for a rarefied supersonic free jet through the analysis of the flow field in both the near- and far-field zones. Nanometre-sized tracer particles and molecules were utilised to measure the rarefied supersonic jet flow field using particle image velocimetry and acetone molecular tagging velocimetry, respectively. The experiments revealed that in rarefied conditions, the supersonic jet exhibits a one-barrel shockwave structure in the near field, and after passing the Mach disk, a long annular viscous layer develops downstream. Experimental data on the jet velocity profile and width demonstrated a transition to a laminar flow regime in the far-field zone. This transition aligns with the theoretically inferred flow regimes based on the complex Reynolds number. The velocity profile and potential core length of the laminar flow regime could be modelled using a bi-modal distribution, which represents the summation of symmetric Gaussian distributions.
Ventilated cavities in the wake of a two-dimensional bluff body are studied experimentally via time-resolved X-ray densitometry. With a systematic variation of flow velocity and gas injection rate, expressed as Froude number ($\textit{Fr}$) and ventilation coefficient ($C_{qs}$), four cavities with different closure types are identified. A regime map governed by $\textit{Fr}$ and $C_{qs}$ is constructed to estimate flow conditions associated with each cavity closure type. Each closure exhibits a different gas ejection mechanism, which in turn dictates the cavity geometry and the pressure in the cavity. Three-dimensional cavity closure is seen to exist for the supercavities at low $\textit{Fr}$. However, closure is nominally two-dimensional for supercavities at higher $\textit{Fr}$. At low $C_{qs}$, cavity closure is seen to be wake-dominated, while supercavities are seen to have interfacial perturbation near the closure at higher $C_{qs}$, irrespective of $\textit{Fr}$. With the measured gas fraction, a gas balance analysis is performed to quantify the gas ejection rate at the transitional cavity closure during its formation. For a range of $\textit{Fr}$, the transitional cavity closure is seen to be characterised by re-entrant flow, whose intensity depends on the flow inertia, dictating the gas ejection rates. Two different ventilation strategies were employed to systematically investigate the formation and maintenance gas fluxes. The interaction of wake and gas injection is suspected to dominate the cavity formation process and not the maintenance, resulting in ventilation hysteresis. Consequently, the ventilation gas flux required to maintain the supercavity is significantly less than the gas flux required to form the supercavity.
Ultra-thin liquid sheets generated by impinging two liquid jets are crucial high-repetition-rate targets for laser ion acceleration and ultra-fast physics, and serve widely as barrier-free samples for structural biochemistry. The impact of liquid viscosity on sheet thickness should be comprehended fully to exploit its potential. Here, we demonstrate experimentally that viscosity significantly influences thickness distribution, while surface tension primarily governs shape. We propose a thickness model based on momentum exchange and mass transport within the radial flow, which agrees well with the experiments. These results provide deeper insights into the behaviour of liquid sheets and enable accurate thickness control for various applications, including atomization nozzles and laser-driven particle sources.
Cavitation bubble pulsation and liquid jet loads are the main causes of hydraulic machinery erosion. Methods to weaken the load influences have always been hot topics of related research. In this work, a method of attaching a viscous layer to a rigid wall is investigated in order to reduce cavitation pulsations and liquid jet loads, using both numerical simulations and experiments. A multiphase flow model incorporating viscous effects has been developed using the Eulerian finite element method (EFEM), and experimental methods of a laser-induced bubble near the viscous layer attached on a rigid wall have been carefully designed. The effects of the initial bubble–wall distance, the thickness of the viscous layer, and the viscosity on bubble pulsation, migration and wall pressure load are investigated. The results show that the bubble migration distance, the normalised thickness of the oil layer and the wall load generally decrease with the initial bubble–wall distance or the oil-layer parameters. Quantitative analysis reveals that when the initial bubble–wall distance remains unchanged, there exists a demarcation line for the comparison of the bubble period and the reference period (the bubble period without viscous layer under the same initial bubble–wall distance), and a logarithmic relationship is observed that $\delta \propto \log_{10} \mu ^*$, where $\delta =h/R_{max}$ is the thickness of the viscous layer h normalised by the maximum bubble radius $R_{max}$, $\mu ^* = \mu /({R_{max }}\sqrt {{\rho }{{\mathop {P}\nolimits } _{{atm}}}})$ is the dynamic viscosity $\mu$ normalised by water density $ \rho $ and atmospheric pressure $P_{atm}$. The results of this paper can provide technical support for related studies of hydraulic cavitation erosion.
The escalating presence of microplastics (<5 mm) in drinking water presents urgent environmental and health challenges, yet the United Nations Environment Programme’s (UNEP) Global Plastics Treaty draft texts, including UNEP/PP/INC.5/4 and the Chair’s Text, lack robust provisions to address this issue. This Letter to the Editor analyzes deficiencies in the treaty’s approach, identifying critical gaps in standardized terminology, globally consistent monitoring methodologies, comprehensive source control and enforceable international regulations. Leveraging insights from California’s innovative microplastics monitoring framework, which employs spectroscopy-based detection and provisional health thresholds, we highlight scalable solutions for global policy. Key obstacles include technological disparities, economic reliance on plastic production, limited toxicological data and geopolitical barriers to unified action. We propose targeted strategies for the Intergovernmental Negotiating Committee (INC-5.2), including adopting precise microplastics definitions, establishing universal detection protocols, regulating both primary and secondary microplastic sources and supporting research and capacity-building in low-resource regions. These measures aim to enhance the treaty’s ability to mitigate microplastic pollution in drinking water, fostering science-driven global cooperation to protect ecosystems and public health.
Aluminium-rich tourmaline can contain significant amounts of Li. Until now, syntheses have not been successful in producing Li-rich tourmalines. Because it is still not clear how Li enters the Y site in tourmaline, possible short-range orders, including Li, are discussed using bond valence calculations. Structural arrangement graphs of the Y-site neighbourhood in the structure of elbaitic tourmalines were investigated to determine more information about their stability. Possible short-range ordering including Al and Li at the Y sites, with Na, Ca or □ (vacancy) at the X site, with Si (and Al or B) at the T sites and either (OH) or F at the W site were investigated. Tourmaline with varying amounts of Na but no Ca can only contain ≤1 apfu (atoms per formula unit) YLi. This is consistent with the composition of synthetic tourmaline. Tourmaline with higher Li content (Li >1 apfu) can form when Ca is included. Such tourmaline requires fluorine because more Li results in O1 underbonding, whereas more Al at the Y site leads to O1 overbonding. Underbonding of O1 is preferable for F because OH at the O1 site usually has a bond valence sum (BVS) higher than 1.00 vu (valence units) due to hydrogen bonding of H to ring oxygen atoms. Therefore, liddicoatitic tourmaline is enriched in F and is usually F-dominant. If no fluorine is available in the starting material of a tourmaline synthesis, it is likely that significant proportions of cations such as B and Al will be incorporated into the tetrahedral site. Ultimately, however, only a smaller proportion of Li can be incorporated. Tourmalines with such tetrahedral cations, which also contain a significant Ca content, could theoretically also have significant Y-site vacancies. In order to synthesise Li-rich tourmalines, we would therefore recommend that the starting material also contains both Ca and F.
The long-term development of coral reef frameworks and the net vertical accretion of reefs fundamentally underpins the provisioning of most reef-related ecosystem services. One area of particular concern at present is how rates of reef accretion are changing under ecological decline and what the consequences of this may be for the capacity of reefs to keep pace with near-future sea-level rise (SLR). This may have major implications for the capacity of reefs to maintain their coastal protective functions and to support reef island stability. Both are issues relevant to understanding future tropical coastal risk. Long-term (millennial timescale) rates of reef accretion are relatively well constrained, including through past periods of sea-level fluctuations. However, widespread and persistent ecological degradation of coral communities has caused many reefs to diverge significantly from their past accretion trajectories. This renders historical analogues increasingly unreliable for projecting future accretion potential. Addressing this necessitates a reorientation towards considering reef accretion rates across shorter (ecological to geomorphic) timescales, i.e., over years to multi-decades. This is essential if we are to better constrain contemporary reef accretion rate and SLR interactions at timescales relevant to predicting emerging coastal risks and understanding future implications for reef-derived benefits. Here, we review existing approaches for quantifying vertical reef accretion rates of modern reefs. These methods span data recovered from fossil outcrops or core-derived records, the conversion of carbonate budget data, direct in situ measurements and emerging remote sensing and image-based techniques. The review explores the advantages and limitations of these different approaches and outlines options for developing an integrated framework to link past, present and future reef accretion potential.
Part II, comprising Chapters 5 to 7, presents the book’s core argument that IFIs are international lawmakers in the field of sustainable development who thus bear international legal accountability. The first prong of the thesis – IFIs’ contribution to international sustainable development lawmaking—is divided into two components. Chapter 5 details the first component and uses examples of ‘un-sustainable development projects’ in various developing countries to show how the safeguard systems work (and not) in ensuring the environmental, social, and economic sustainability of IFIs’ operations and the projects they support.
Chapter 2 runs parallel to the immediately preceding chapter by tracing the changing definitions of development, as understood and implemented by one of the pillar organizations of international financial law, ie the World Bank, whose mandate and functions have likewise been evolving. It employs the New Haven approach to international law and treaty interpretation to expound how development has come to be understood in the Bank’s operations as involving not only economic growth but also environmental, governance, and human rights concerns, despite the ‘political activity prohibition’ in its constituent instrument.
As the first chapter in Part One (which describes the book’s two main characters – sustainable development and the World Bank exemplifying the IFIs – and narrates how their paths meet), chapter 1 maps the international community’s varied and evolving understandings of sustainable development, drawing particular attention to how these understandings overlap with and echo themes from early attempts to reform international economic law, ie the legal rules governing the global economic order, and the contemporary efforts to codify the human right to development.
This study investigated surface energy fluxes of the Huayna-Potosí Glacier in Bolivia to validate existing empirical melt estimates, including degree-day models and enhanced temperature-index models. A multilayer energy balance model of the snowpack was employed to estimate melt energy and analyze its correlation with meteorological variables. The energy balance analysis revealed that melt energy peaked in October and November, the period corresponding to the progressive development toward the core wet season. Most of the net radiation was consumed by the conductive heat flux into the snowpack or glacier ice, contributing to surface temperature increases. The remaining energy was used for melt. An analysis of diurnal variation indicated that atmospheric longwave radiation suppresses melt during the dry season while driving melt during the wet season. Variables such as specific humidity and relative humidity, which are related to atmospheric longwave radiation, emerged as primary controlling factors after solar radiation in estimating melt based on meteorological variables. This study highlights that a combination of solar radiation and specific humidity outperforms existing empirical melt models that depend exclusively on temperature or a combination of temperature and solar radiation.
The addition and refreezing of liquid water to Greenland’s accumulation area are increasingly important processes for assessing the ice sheet’s present and future mass balance, but uncertain initial conditions, complex infiltration physics and limited field data pose challenges. Satellite-based L-band radiometry offers a promising new tool for observing liquid water in the firn layer, although further validation is needed. This paper compares time series of liquid water amount (LWA) from three percolation zone sites generated by a localized point-model, a regional climate model, in situ measurement, and L-band radiometric retrievals. LWA integrates the interplay of liquid water generation and refreezing, which often occur simultaneously and repeatedly within firn layers on diurnal, episodic, and seasonal scales offering insights into methods for measuring and modeling meltwater processes. The four LWA records showed average discrepancies of up to 62% nRMSE, reflecting shortcomings inherent to each method. Better agreement between series occurred after excluding the regional climate model record, lowering nRMSE to 8–13%. The agreement between L-band radiometry and other LWA records inspires confidence in this observational tool for understanding firn meltwater processes and serving as a validation target for simulations of water processes in Greenland’s melting firn layer.
We study the dispersion of bubble swarms rising in initially quiescent water using three-dimensional Lagrangian tracking of deformable bubbles and tracer particles in an octagonal bubble column. Two different bubble sizes (3.5 mm and 4.4 mm) and moderate gas volume fractions ($0.52\,\%{-}1.20\,\%$) are considered. First, we compare the dispersion inside bubble swarms with that for single-bubble cases, and find that the horizontal mean squared displacement (MSD) in the swarm cases exhibits oscillations around the asymptotic scaling predicted for a diffusive regime. This occurs due to wake-induced bubble motion; however, the oscillatory behaviour is heavily damped compared to the single-bubble cases due to the presence of bubble-induced turbulence (BIT) and bubble–bubble interactions in the swarm. The vertical MSD in bubble swarms is nearly an order of magnitude faster than in the single-bubble cases, due to the much higher vertical fluctuating bubble velocities in the swarms. We also investigate tracer dispersion in BIT, and find that concerning the time to transition away from the ballistic regime, larger bubbles with a higher gas void fraction transition earlier than tracers, consistent with Mathai et al. (2018, Phys. Rev. Lett., vol. 121, 054501). However, for bubble swarms with smaller bubbles and a lower gas void fraction, they transition at the same time. This differing behaviour is due to the turbulence being more well-mixed for the larger bubble case, whereas for the smaller bubble case, the tracer dispersion is highly dependent on the wake fluctuations generated by the oscillating motion of nearby bubbles.
Dating the shear zone activity remains challenging and depends on geochronometer reactivity. We investigate the Forno-Rosarolo Shear Zone (Ivrea-Verbano Zone, Italy), developed in the intermediate-low continental crust under amphibolite-facies conditions. Sheared paragneisses and calc-silicates were dated using in situ U–(Th–)Pb monazite and titanite geochronology. Three monazite generations (MNZI-III) were identified based on microstructural position, internal features, chemical zoning (Th, Y) and isotopic data. Deformation was mainly recorded by MNZII, with high-Y domains yielding Triassic dates (average ages of: 238±8 and 222±8 Ma). Rare, highly fractured or porous MNZIII grains provided younger dates (202±8 to 184±6 Ma). MNZI, abundant in protomylonites, retains regional metamorphism, linking monazite U–Th–Pb data to fabric evolution. Titanite shows different zoning features and chemistry as a function of the surrounding mineral assemblage: (i) strongly zoned grains are mostly associated with silicate-rich layers; (ii) homogeneous grains are generally within the silicate-poor layers. Both types show a decoupling between chemistry, almost completely related to the peak metamorphism, and U–Pb isotopes. Deformation microstructures promoted a total reset of the U–Pb dataset at the beginning of deformation and a subsequent volume diffusion through the grains: the innermost domains of both titanite types provide a Triassic lower intercept age (240±5 Ma) while the rims/tips, locally coinciding with high strained portions, define an alignment of isotopic data with a Jurassic lower intercept age (186±6 Ma). This study highlights how combining monazite and titanite geochronology refines the timing and duration of deformation, particularly in large-scale shear zones involving different lithologies.
Completing the first prong of the main claim, Chapter 6 uses the coordination and cooperation among MDBs and among IAMs to demonstrate how they learn from one another’s approach to sustainability and engage in actions that reinforce the authoritativeness of their collective understanding of sustainable development. This chapter examines these interactions through three case studies on co-financed projects in Argentina/Paraguay, Uganda, and Albania.