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Goethite (α-FeOOH) occurs widely in soils and surface sediments as a result of surface weathering in the presence of water and oxygen. It becomes unstable compared to hematite with dehydration occurring at elevated temperatures and/or decreased humidity in practically all geological environments. Goethite has a defect antiferromagnetism with weak net magnetic moment; it also has the highest coercivity among known rock-forming minerals (although mixtures of superparamagnetic and stable single domain nanoparticles can have low coercivities). It has a low Néel temperature of 120°C, which can be lowered further in natural samples by cation substitution. Goethite lacks a low-temperature magnetic transition, although it undergoes a distinctive approximately linear remanence enhancement during cooling from room temperature to low temperatures. A combination of the distinctive low temperature magnetic properties and low unblocking temperatures of goethite can be used to identify it in complexly mixed natural samples.
Sustainable management of watersheds to secure freshwater resources and maintain ecological stability relies on adopting land-use strategies supporting diverse ecosystem services through natural processes. This necessitates systematic evaluation of prospective land-use practices and their associated costs and benefits. We conducted a comprehensive economic evaluation of pro-watershed land-use options, focusing on a well-recognized agroforestry system with alternative organic cultivation in the Navnera watershed in Rajasthan, India. We adopted the ‘total economic valuation’ framework, using the revealed preference approach for monetary evaluation and modelling indirect benefits primarily through Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST). Our findings indicate that the total economic value of ecosystem services in this watershed has the potential to increase by 4.6% with the adoption of agroforestry and only by 1.3% under organic farming compared to current land-use practices. While agroforestry might reduce farmland revenue and water yield, it compensates for these with other important environmental benefits such as water purification, sediment reduction, nutrient retention and carbon sequestration. This local-scale appraisal of ecosystem services helps policymakers understand the cost–benefit dynamics of watershed land-use changes, which is vital for developing effective management strategies through the involvement of local communities.
As a step towards realising a skin-friction drag reduction technique that scales favourably with Reynolds number, the impact of a synthetic jet on a turbulent boundary layer was explored through a study combining wind-tunnel measurements and large eddy simulations. The jet was ejected in the wall-normal direction through a rectangular slot whose spanwise dimension matched that of dominant large-scale structures in the logarithmic region to target structures of that size and smaller simultaneously. Local skin-friction reduction was observed at both $x/\delta =2$ and $x/\delta =5$ downstream of the orifice centreline, where $\delta$ is the boundary-layer thickness. At $x/\delta =2$, the skin-friction reduction was observed to be due to the synthetic-jet velocity deficit intersecting the wall. At $x/\delta =5$, evidence from the simulations and wind-tunnel measurements suggests that a weakening of wall-coherent velocity scales is primarily responsible for the skin-friction reduction. Local skin-friction reduction which scales favourably with Reynolds number may be achievable with the synthetic jet employed in this study. However, there are many technical hurdles to overcome to achieve net skin-friction drag reduction over the entire region of influence. For instance, regions of skin-friction increase were observed close to the orifice ($x/\delta \lt 2$) and downstream of the orifice edge due to the induced motion of synthetic-jet vortical structures. Additionally, a recirculation region was seen to form during expulsion, which has implications for pressure drag on non-planar surfaces.
Northern Calabria forms part of the Calabrian Arc, a geologically complex region in southern Italy shaped by the convergence between the Eurasian and African plates. This convergence drove the closure of the Tethys Ocean and produced the subsequent phases of collisional and extensional tectonics. Thrusting during the Alpine orogeny produced extensive nappe stacking, followed by structural reorganization and exhumation during the Oligocene-Miocene. Tectonostratigraphically, the Apennine carbonate platform forms the lowest structural unit, overlain successively by the Liguride Oceanic Complex and the Calabride Complex, which includes the Sila nappe stack. Along Calabria’s eastern Ionian margin, forearc basins developed in response to the retreating subduction zone. To better constrain sediment routing pathways and regional uplift in northern Calabria from early to late Miocene, a multi-proxy provenance study was applied to four forearc basins: Rossano, Cirò, Crotone and Catanzaro. Quantitative heavy-mineral analysis, single-grain garnet and apatite chemistry, and apatite U–Pb chronology reveal spatial and temporal variations in sediment sources. Siliciclastic samples, spanning Aquitanian to Messinian in age, record changing contributions from a combination of low- to high-grade metamorphic and plutonic sources, including mafic Liguride units. Up-section shifts in sediment sourcing patterns indicate that Calabrian Arc exhumation and uplift, characterized by a rapid increase in the middle Miocene followed by a slow reduction in relief, played a pivotal role in controlling the timing and direction of sediment transport. This study demonstrates the benefits of multi-method provenance approaches to achieve valuable insights into relief build-up and demise, associated divide migration and sedimentary responses within a young and complex, zircon-poor orogenic arc system.
The magnetic properties of minerals are tied intrinsically to their crystallographic and electronic structures. Most books that discuss mineral magnetism tend to treat magnetic minerals from a physics perspective. While this is valuable, magnetic properties are linked inextricably to their host minerals, and it is important to understand key aspects of mineralogy and crystallography as they relate to magnetic structures and the recording of magnetic information. While the treatment of mineralogy and crystallography in this chapter will be elementary for mineralogists, the aim is to provide an essential and foundational introduction for readers with minimal background in these subjects to aid understanding of critical concepts in magnetic mineralogy. We start by discussing the atomic structure of matter, followed by chemical bonding and the arrangement of atoms in crystals. Fundamentals of crystallography are discussed, including the ways that we describe crystal symmetry. Processes by which magnetic minerals form and are altered in igneous rocks are discussed, along with the most common types of crystal structures found in magnetic minerals.
This chapter offers an overview of Antarctica’s major meteorological and climate features using the latest methods, data products, and research findings. The first half of the chapter presents a thorough description of the Antarctic geography and its climatological temperature, precipitation, and near-surface environment. It provides a dedicated section covering Antarctic foehn and foehn-induced warming, which have been identified as major ‘hot spots’ for Antarctic surface melt and ice shelf destabilisation. Next the chapter details the major large-scale and regional atmospheric circulation patterns that characterise the high southern latitudes and strongly influence Antarctic meteorology, including the Southern Annular Mode, teleconnections associated with the El Niño Southern Oscillation, and the Amundsen Sea Low. We then present the latest research discoveries on Antarctic climate extremes, with a focus on Antarctic ‘atmospheric rivers’ and their role in driving extreme temperature, precipitation, and surface melt events. The chapter closes with a summary of recent Antarctic climate change, current research gaps and challenges, and recommendations for future work.
The oceans play a fundamental role in shaping the Southern Hemisphere climate, including aspects such as why the western tropical Pacific is warmer and rainier than the eastern Pacific or why some regions in Africa, Australia, and South America often experience intense drought, heatwaves, and extreme rainfall. Eighty percent of the Southern Hemisphere is covered by oceans, encompassing the Pacific, Indian, Atlantic, and Southern Oceans in which oceanic circulations, and their interplay with the atmosphere, give rise to some of the Earth’s most powerful climate phenomena that impact regions across the Southern Hemisphere. Climate processes across these ocean sectors interact with one another through the oceans and atmosphere, adding a layer of complexity in understanding climate phenomena and in robust future projections. The oceans play a vital role in regulating the climate as the planet warms under increasing greenhouse forcing.
The triadic interactions and nonlinear energy transfer are investigated in a subsonic turbulent jet at $Re = 450\,000$. The primary focus is on the role of these interactions in the formation and attenuation of streaky structures. To this end, we employ bispectral mode decomposition, a technique that extracts coherent structures associated with dominant triadic interactions. A strong triadic correlation is identified between Kelvin–Helmholtz (KH) wavepackets and streaks: interactions between counter-rotating KH waves generates streamwise vortices, which subsequently give rise to streaks through the lift-up mechanism. The most energetic streaks occur at azimuthal wavenumber $m = 2$, with the dominant contributing triad being $[m_1, m_2, m_3] = [1, 1, 2]$. The spectral energy budget reveals that the net effect of nonlinear triadic interactions is an energy loss from the streaks. As these streaks convect downstream, they engage in further nonlinear interactions with other frequencies, which drain their energy and ultimately lead to their attenuation. Further analysis identifies the dominant scales and direction of energy transfer across different spatial regions of the jet. While the turbulent jet exhibits a forward energy cascade in a global sense, the direction of energy transfer varies locally: in the shear layer near the nozzle exit, triadic interactions among smaller scales dominate, resulting in an inverse energy cascade, whereas farther downstream, beyond the end of the potential core, interactions among larger scales prevail, leading to a forward cascade.
Secondary flows induced by spanwise heterogeneous surface roughness play a crucial role in determining engineering-relevant metrics such as surface drag, convective heat transfer and the transport of airborne scalars. While much of the existing literature has focused on idealized configurations with regularly spaced roughness elements, real-world surfaces often feature irregularities, clustering and topographic complexity for which the secondary flow response remains poorly understood. Motivated by this gap, we investigate multicolumn roughness configurations that serve as a regularized analogue of roughness clustering. Using large-eddy simulations, we systematically examine secondary flows across a controlled set of configurations in which cluster density and local arrangement are varied in an idealized manner, and observe that these variations give rise to distinct secondary flow polarities. Through a focused parameter study, we identify the spanwise gap between the edge-most roughness elements of adjacent columns, normalized by the channel half-height ($s_a/H$), as a key geometric factor governing this polarity. In addition to analysing the time-averaged structure, we investigate how variations in polarity affect the instantaneous dynamics of secondary flows. Here, we find that the regions of high- and low-momentum fluid created by the secondary flows alternate in a chaotic, non-periodic manner over time. Further analysis of the vertical velocity signal shows that variability in vertical momentum transport is a persistent and intrinsic feature of secondary flow dynamics. Taken together, these findings provide a comprehensive picture of how the geometric arrangement of roughness elements governs both the mean structure and temporal behaviour of secondary flows.
Greigite (Fe3S4) is an iron sulphide mineral with, like magnetite, collinear ferrimagnetism and an inverse spinel crystal structure, but with markedly different magnetic properties to magnetite. It is now known to be a stable magnetic phase that forms authigenically in sediments and sedimentary rocks that have undergone sulphidic or methanic diagenesis; it can also be produced bacterially. Much progress has been made to understand its magnetic properties over the last 30 years. Its Curie temperature likely exceeds 400°C, but remains unknown because it alters when heated to ~220–350°C. Greigite has high saturation magnetization, moderate coercivity, and cubic magnetocrystalline anisotropy. It lacks a low-temperature magnetic transition. Its fundamental magnetic parameters are moderately well constrained and initial micromagnetic models suggest that ideal magnetic single domain behaviour occurs over a wider particle size range than for magnetite. This can explain why stable-single-domain-like behaviour is reported widely for natural greigite occurrences.
A fully resolved numerical study was performed to investigate interfacial heat and mass transfer enhanced by the fully developed Rayleigh–Bénard–Marangoni instability in a relatively deep domain. The instability was triggered by evaporative cooling modelled by a constant surface heat flux. The latter allowed for temperature-induced variations in surface tension giving rise to Marangoni forces reinforcing the Rayleigh instability. Simulations were performed at a fixed Rayleigh number (${\textit{Ra}}_h$) and a variety of Marangoni numbers (${\textit{Ma}}_h$). In each simulation, scalar transport equations for heat and mass concentration at various Schmidt numbers (${\textit{Sc}}=16{-}200$) were solved simultaneously. Due to the fixed (warm) temperature prescribed at the bottom of the computational domain, large buoyant plumes emerged quasi-periodically both at the top and bottom. With increasing Marangoni number a decrease in the average convection cell size at the surface was observed, with a simultaneous improvement in near-surface mixing. The presence of high aspect ratio rectangular convection cell footprints was found to be characteristic for Marangoni-dominated flows. Due to the promotion of interfacial mass transfer by Marangoni forces, the power in the scaling of the mass transfer velocity, $K_{\!L}\!\propto\! \textit{Sc}^{-n}$, was found to decrease from $n=0.50$ at ${\textit{Ma}}_h=0$ to $\approx 0.438$ at ${\textit{Ma}}_h=13.21\times 10^5$. Finally, the existence of a buoyancy-dominated and a Marangoni-dominated regime was investigated in the context of the interfacial heat and mass transfer scaling as a function of ${\textit{Ma}}_h+\varepsilon {\textit{Ra}}_h$, where $\varepsilon$ is a small number determined empirically.
Both experiments and direct numerical simulation (DNS) of hypersonic flow over a compression ramp show streamwise aligned streaks/vortices near the corner as the ramp angle is increased. The origin of this three-dimensional disturbance growth is not definitively known in the existing literature, but is typically connected to flow deceleration, centrifugal (Görtler) and/or baroclinic effects. In this work we consider the hypersonic problem with moderate wall cooling in the high Reynolds/Mach number, weak interaction limit. In the lower deck of the corresponding asymptotic triple-deck description we pose the linearised, three-dimensional, Görtler stability equations. This formulation allows computation of both receptivity and biglobal stability problems for linear spanwise-periodic disturbances with a spanwise wavelength of the same order as the lower-deck depth. In this framework the dominant response near the ramp surface is of constant density and temperature (at leading order) ruling out baroclinic mechanisms. Nevertheless, we show that there remains strong energy growth of upstream spanwise-varying perturbations and ultimately a bifurcation from two-dimensional to three-dimensional ramp flow. The unstable eigenmodes are localised to the separation region. The bifurcation points are obtained over a range of ramp angle, wall-cooling parameter and disturbance wavelength. Consistent with DNS results, the three-dimensional perturbations in this asymptotic formulation are streamwise aligned streaks/vortices, displaced above the separation region. In addition, the growth of upstream disturbances peaks near to the reattachment point, whilst the streaks persist beyond it, decaying relatively slowly downstream along the deflected ramp.