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The crystal structure of decoquinate has been solved and refined using synchrotron X-ray powder diffraction data and optimized using density functional theory techniques. Decoquinate crystallizes in space group P21/n (#14) with a = 46.8261(5), b = 12.94937(12), c = 7.65745(10) Å, β = 91.972(1), V = 4640.48(7) Å3, and Z = 8 at 295 K. The crystal structure consists of alternating layers of hydrocarbon chains and ring systems along the a-axis. Hydrogen bonds link the ring systems along the b-axis. The rings stack along the c-axis. The two independent decoquinate molecules have very different conformations, one of which is typical and the other has an unusual orientation of the decyl chain with respect to the hydroxyquinoline ring system, facilitating chain packing. The powder pattern has been submitted to the ICDD for inclusion in the Powder Diffraction File™ (PDF®).
Phase characterization with selected area electron diffraction (SAED) represents a significant challenge when the pattern contains a substantial number of diffraction spots arranged in concentric but incomplete rings. This is a common situation when the crystallites are neither large enough to form a single crystal pattern nor sufficiently small and numerous to form continuous Debye-Scherrer rings. In such circumstances, it is often extremely difficult to distinguish between reflections belonging to a specific phase or to identify reflections that originate from secondary phases. To facilitate the process of phase identification for these kinds of multiphase samples, a macro script with the recursive acronym FINDS (FINDS Identifies Non-matrix Diffraction Spots) was developed on the ImageJ/FIJI platform. The program allows the user to mark diffraction spots of known phases by superimposed rings, making it easy to identify and address additional reflections between them. In addition to the full functionality of calculating and plotting the diffraction ring patterns of the known phases in different styles and colors, FINDS also provides tools for locating spot positions and determining the corresponding d-values of the reflections of interest. The effectiveness of this approach and of the developed program in assisting the process of phase identification with SAED patterns of multiphase samples is demonstrated by two representative examples. The macro code of FINDS is published under GNU General Public License v3.0 or later at https://doi.org/10.5281/zenodo.13748483.
The variability in ground manoeuvre occurrences for aircraft landing gear is intrinsically linked to the airport geometries served by aircraft in-service and consequently, the cyclic loads that landing gear carry are driven by the route network and characteristics of aircraft operators. Currently, assumptions must be made when deriving fatigue load spectra for aircraft landing gear, which may fail to capture the operator characteristics, potentially leading to design conservatism. This paper presents the enhanced characterisation of ground turning manoeuvres within the Automatic Dependent Surveillance-Broadcast (ADS-B) trajectories for six narrow-body aircraft across a full-service carrier (FSC) and a low-cost carrier (LCC) fleet. The methodology presented within this paper employs ADS-B latitude and longitude information to overcome limitations of previous approaches, increasing the rate of correct manoeuvre identification within ADS-B trajectories to 77% of flights from the 50% rate achieved previously. When characterising the ground manoeuvres across 3,000 flights, significant differences in manoeuvre occurrences were observed between individual aircraft within the LCC fleet and between the FSC and LCC fleets. The occurrence of tight and pivot turns were shown to vary across the six aircraft with six and eight fatigue-critical turns being performed by the FSC and LCC fleet for every 10 flights performed. In addition, it was observed that the direction of fatigue critical turns is biased in specific directions, suggesting that individual main landing gear assemblies will accumulate fatigue damage at an increased rate, leading to greater justification for operator-specific spectra and structural health monitoring of aircraft landing gear.
In this article, a low phase noise signal source to be used as local oscillator in pulse Doppler radio frequency (PDRF) sensor is proposed. Innovative design techniques for realization of the low phase noise frequency source using phase-locked loop (PLL) and dielectric resonator (DR) are presented. Qualitative investigations have been carried out on the effect of phase noise in PDRF sensor performance. An X-band vibration resistant PLL-based frequency source with phase noise better than −95 dBc at 1 kHz frequency offset has been designed here. It also presents the design of a 7.6 GHz low phase noise, vibration resistant DR oscillator. Systematic analysis of the key design aspects, their thermal-vibrational stability, and ease of integration with hybrid microwave integrated circuits have been disclosed. A prototype board is fabricated, assembled in a compact mechanical enclosure of dimension 55 × 55 × 15 mm3. Finally, developed module is experimentally validated under 7.6 g rms magnitude random vibration test in three axes and compared results with other state of-the-art similar works. The comparison clearly shows the merit of present research work over other similar existing works.
Migrating reefs, unprecedented species assemblages, neophytes, toxicities, pollutants, aquatic ruins – The future of coral reefs in the Anthropocene is likely to look different from anything we have experienced so far. While the classic conservation debate on coral reef restoration still treats these ecosystems as “sick patients,” a radically different view of convivial conservation is beginning to challenge exclusive human control over these endangered habitats. Putting aside notions of natural “purity” and adopting a much more humble and highly interconnected perspective on marine habitats, we can begin to see reefs as transformative, sympoïetic and blasted seascapes for a convivial future. The discipline of biodesign has been primarily focussed on researching ecological relationships with regard to new materials and products. The emerging interest in shaping the multi-layered ecological relationships of habitats for other-than-human lives, however, is steering design practice towards terraforming or, in the case of marine environments, “aquaforming.” This paper argues for taking convivial conservation practices in marine environments as a starting point for the development of a new design methodology that focuses on the design of living systems in open environments: a proposed methodology called Sympoïetic Design.
A viscous, lubrication-like response can be triggered in a thin film of fluid squeezed between a rigid flat surface and the tip of an incoming projectile. We develop a scaling for this viscous approach stage of fluid-mediated normal impact, applicable to soft impactors. Under the assumption of mediating fluid being incompressible, the impacting solid displays two limit regimes: one dominated by elasticity, and the other by inertia. The transition between the two is predicted by a dimensionless parameter, which can be interpreted as the ratio between two time scales that are the time that it takes for the surface waves to warn the leading edge of the impactor of the forthcoming impact, and the characteristic duration of the final viscous phase of the approach. Additionally, we elucidate why nearly incompressible solids feature (a) substantial ‘gliding’ prior to contact at the transition between regimes, (b) the largest size of entrapped bubble between the deformed tip of the impactor and the flat surface, and (c) a sudden drop in entrapped bubble radius past the transition between regimes. Finally, we argue that the above time scale ratio (a dimensionless number) can govern the different dynamics reported experimentally for a fluid droplet as a function of its viscosity and surface tension.
Numerous flying and swimming creatures use the ground effect to boost their propulsive performance, with the ‘ground’ referring to either a solid boundary or a free surface. While our knowledge of how a solid boundary affects biolocomotion is relatively comprehensive, the ground effect of a free surface is not fully understood. To address this limitation, we conduct a numerical investigation on the propulsion performance of a flapping plate under a free surface, subject to a range of control parameters. When the Froude number ($Fr$) is very low (i.e. little surface deformation), the effects of a free surface are similar to those of a solid boundary, with enhanced thrust and input power but little change in efficiency. However, as $Fr$ increases (i.e. more surface deformation), our results reveal an optimal $Fr$ of approximately 0.6, where the free surface induces a more streamlined flow around the flapping plate, effectively reducing the added mass. This results in a significant decrease in input power and greatly enhanced efficiency.
This paper describes an early-stage research and experiments exploring methods of co-cultivation of the fungal strain Ganoderma lucidum and the bacterial strain Sporosarcina pasteurii within the field of architecture. Co-cultivating these species within a bio-based compound, forming a living material, shows that the binding abilities of both microbial partners can be harnessed through multistep production techniques. As the mycelial network of the fungus spreads through the inoculated wood substrate, bacterial cells disperse and multiply on this same network and release the enzyme urease throughout the now-forming compound bound by the fungus. The enzyme is one of the key actors in the biocementation process, which is activated with the addition of a calcium source to the material. Calcium carbonate minerals form and attach on the hyphae, as well as in between the network, inside the wood sawdust pieces and around void spaces within the composite. While additional data collection is required, the current state of this research suggests that properties of both living materials can be expanded, for example, fire resistance and compressive strength compared to traditional mycelium-based composites, as well as the increased ability of the bacteria to homogeneously distribute and exist in unfavorable environments compared to mono-cultured bacterial communities.
Meandering designates the main manifestation of unsteady vortex dynamics observed in experiments. This study has the twofold objective to (i) develop a theoretical model describing vortex meandering and (ii) conduct a quantitative and objective evaluation of the model against experimental data. Based on an analogy with Brownian motion, we derive the theoretical model in the framework of linear response theory. Taking the form of a Langevin equation, our model explains meandering as the competition between external excitation by free-stream perturbations, counteracted by stabilising intrinsic vortex dynamics. As such, it contains the previous approaches to explaining the phenomenon as limiting cases, and clearly highlights their shortcomings. The statistical identification of characteristic regularities in experimental data as well as the assessment of their consistency with theoretical models are important problems in physics. For samples obtained from finite-length records of correlated data, these statistical characteristics are not unique and may show spurious behaviour merely induced by the finiteness of the sample. Statistical inference provides a systematic and quantitative methodology to objectively assess the reproducibility of statistical characteristics and to evaluate their consistency with theoretical models. Their systematic application to the analysis of vortex meandering has not been done before and provides statistical evidence for our proposed Brownian-motion-like model. That is, experimental vortex meandering constitutes the manifestation of a stationary Gauss–Markov random process, which implies that the dynamics admits an ergodic probability measure.
We analyse the effect of drop-deformation-induced change in streamline topology on the scalar transport rate (the Nusselt number $Nu$) in an ambient planar linear flow. The drop-phase resistance is assumed dominant, and the drop deformation is characterised by the capillary number ($Ca$). For a spherical drop ($Ca = 0$) in an ambient planar extension, closed streamlines lead to $Nu$ increasing with the Péclet number ($Pe$), from $Nu_0$, corresponding to purely diffusive transport, to $4.1Nu_0$, corresponding to a large-$Pe$ diffusion-limited plateau. For non-zero $Ca$, we show that the flow field consists of spiralling streamlines densely wound around nested tori foliating the deformed drop interior. Now $Nu$ increases beyond the aforementioned primary plateau, saturating in a secondary one that approaches $22.3Nu_0$ for $Ca \rightarrow 0$, $Pe\,Ca \rightarrow \infty$. The enhancement appears independent of the drop-to-medium viscosity ratio. We further show that this singular dependence, of the transport rate on drop deformation, is generic across planar linear flows; chaotically wandering streamlines in some of these cases may even lead to a tertiary enhancement regime.
The elasto-inertial focusing and rotating characteristics of spheroids in a square channel flow of Oldroyd-B viscoelastic fluids are studied by the direct forcing/fictitious domain method. The rotational behaviours, changes in the equilibrium positions and travel distances are explored to analyse the mechanisms of spheroid migration in viscoelastic fluids. Within the present simulated parameters (1 ≤ Re ≤ 100, 0 ≤ Wi ≤ 2, 0.4 ≤ α ≤3), the results show that there are four kinds of equilibrium positions and six (five) kinds of rotational behaviours for the elasto-inertial migration of prolate (oblate) spheroids. We are the first to identify a new rotational mode for the migration of prolate spheroids. Only when the particles are initially located at a corner and wall bisector, some special initial orientations of the spheroids have an impact on the final equilibrium position and rotational mode. In other general initial positions, the initial orientation of the spheroid has a negligible effect. A higher Weissenberg number means the faster the particles migrate to the equilibrium position. The spheroid gradually changes from the corner (CO), channel centreline (CC), diagonal line (DL) and cross-section midline (CSM) equilibrium positions as the elastic number decreases, depending on the aspect ratio, initial orientation and rotational behaviour of the particles and the elastic number of the fluid. When the elastic number is less than the critical value, the types of rotational modes of the spheroids are reduced. By controlling the elastic number near the critical value, spheroids with different aspect ratios can be efficiently separated.
Ba2Bi0.572TeO6±δ and SrLa2NiFeNbO9 ceramics were prepared in polycrystalline form by conventional solid-state reaction techniques in air. The crystal structures of the title compounds were determined at room temperature from X-ray powder diffraction (XRPD) data using the Rietveld method. The Ba2Bi0.572TeO6±δ structure crystallizes in a triclinic space group I–1 with unit-cell parameters a = 6.0272(2) Å, b = 6.0367(1) Å, c = 8.5273(3) Å, α = 90.007(7)°, β = 90.061(2)°, and γ = 90.015(4)°. The tilt system of the BiO6 and TeO6 octahedra corresponds to the notation a–b–c–. The crystal structure of the SrLa2NiFeNbO9 compound adopts an orthorhombic Pbnm space group with lattice parameters a = 5.6038(5) Å, b = 5.5988(4) Å, and c = 7.9124(6) Å. The BO6 octahedra (B = Ni/Fe/Nb) sharing the corners in 3D. Along the c-axis, the octahedra are connected by O(1) atoms of (x,y,1/4) positions; while in the ab-plane, they are linked by O(2) atoms of (x,y,z) positions. The bond angle of B–O1–B is 168.7° and that of B–O2–B is 156.3°. The octahedral lattice corresponds to the tilt pattern a–a–c+; it indicates that the octahedra tilt out-of-phase along the a,b-axes and in phase along the c-axis.
Internal solitary waves are a widely observed phenomenon in natural waters. Mathematically, they are fundamentally a nonlinear phenomenon that differs from the paradigm of turbulence, in that energy does not move across scales. Internal solitary waves may be computed from the Dubreil–Jacotin Long equation, which is a scalar partial differential equation that is equivalent to the stratified Euler equations. When a background shear current is present the algebraic complexity of the problem increases substantially. We present an alternative point of view for characterizing the situation with a shear current using Lagrangian (particle-like) models analysed with graph theoretic methods. We find that this yields a novel, data-centric framework for analysis that could prove useful well beyond the study of internal solitary waves.
Predicting the transient flow fields that develop when a shock wave passes through an area expansion is a fundamental problem in compressible fluid mechanics and significant in many engineering applications. Experiments, large eddy simulations and geometrical shock dynamics are used to study the mechanism by which a normal shock wave that expands across an area expansion evolves into a uniform normal shock far downstream of it. This study analyses shock waves with moderate Mach numbers of 1.1–1.8 that expand at area ratios of up to 5. As the shock wave propagates into the expanded region, it experiences rapid deceleration, forming a non-uniform shock front. Impinging on the walls of the larger cross-section region, the shock wave reflects and generates a complex and highly transient shock pattern near the expansion region. We have found that as the shock front propagates further downstream, a laterally moving shock wave that intersects the shock front at a triple point reverberates laterally between the walls. This process effectively evens out the flow behind the incident shock front, thus reducing the variation of properties behind it. The extended duration of this process leads to significant pressure fluctuation behind the shock front. The results show that the evolution of the shock front can be scaled using the expanded region height and the velocity of the shock wave far downstream of the expansion. The results enabled the formulation of a simple empirical relation, allowing us to predict the shock velocity far downstream of gradual and abrupt area expansions.
Research on the settling dynamics of snow particles, considering their complex morphologies and real atmospheric conditions, remains scarce despite extensive simulations and laboratory studies. Our study bridges this gap through a comprehensive field investigation into the three-dimensional (3-D) snow settling dynamics under weak atmospheric turbulence, enabled by a 3-D particle tracking velocimetry (PTV) system to record over a million trajectories, coupled with a snow particle analyser for simultaneous aerodynamic property characterization of four distinct snow types (aggregates, graupels, dendrites, needles). Our findings indicate that while the terminal velocity predicted by the aerodynamic model aligns well with the PTV-measured settling velocity for graupels, significant discrepancies arise for non-spherical particles, particularly dendrites, which exhibit higher drag coefficients than predicted. Qualitative observations of the 3-D settling trajectories highlight pronounced meandering in aggregates and dendrites, in contrast to the subtler meandering observed in needles and graupels, attributable to their smaller frontal areas. This meandering in aggregates and dendrites occurs at lower frequencies compared with that of graupels. Further quantification of trajectory acceleration and curvature suggests that the meandering frequencies in aggregates and dendrites are smaller than that of morphology-induced vortex shedding of disks, likely due to their rotational inertia, and those of graupels align with the small-scale atmospheric turbulence. Moreover, our analysis of vertical acceleration along trajectories elucidates that the orientation changes in dendrites and aggregates enhance their settling velocity. Such insights into settling dynamics refine models of snow settling velocity under weak atmospheric turbulence, with broader implications for more accurately predicting ground snow accumulation.
The crystal structure of gepirone has been solved and refined using synchrotron X-ray powder diffraction data and optimized using density functional theory techniques. Gepirone crystallizes in space group P21/a (#14) with a = 16.81794(14), b = 11.71959(5), c = 10.10195(4) Å, β = 95.7012(5)°, V = 1981.239(14) Å3, and Z = 4 at 298 K. The crystal structure consists of discrete gepirone molecules. There are no classical hydrogen bonds in the crystal structure, but several intra- and intermolecular C–H⋯N and C–H⋯O hydrogen bonds contribute to the lattice energy. The powder pattern has been submitted to ICDD® for inclusion in the Powder Diffraction File™ (PDF®).
We investigate the dynamics of a columnar Taylor–Green vortex array under strong stratification, focusing on Froude numbers $0.125\leq Fr \leq 1.0$, with the aim of identifying and understanding the primary instabilities that lead to the vortices’ breakdown. Linear stability analysis reveals that the fastest-growing vertical wavenumber scales with $Fr^{-1}$, while the dimensionless growth rate remains approximately constant. The most unstable eigenmode, identified as the mixed hyperbolic mode by Hattori et al. (J. Fluid Mech., vol. 909, 2021, A4), bears significant similarities to the zigzag instability, first discovered by Billant & Chomaz (J. Fluid Mech., vol. 418, 2000, pp. 167–188). Direct numerical simulations further confirm that the zigzag instability is crucial in amplifying initial random perturbations to finite amplitude, with the flow structure and modal growth rate consistent with the linear stability analysis. In particular, the characteristic vertical length scale of turbulence matches that of the fastest-growing linear mode. These findings underscore the broader relevance of the zigzag instability mechanism beyond its initial discovery in vortex pairs, demonstrating its role in facilitating direct energy transfer from vertically uniform vortical motions to a characteristic vertical length scale proportional to $Fr$ in strongly stratified flows.
We propose a simple method to identify unstable parameter regions in general inviscid unidirectional shear flow stability problems. The theory is applicable to a wide range of basic flows, including those that are non-monotonic. We illustrate the method using a model of Jupiter's alternating jet streams based on the quasi-geostrophic equation. The main result is that the flow is unstable if there is an interval in the flow domain for which the reciprocal Rossby Mach number (a quantity defined in terms of the zonal flow and potential vorticity distribution), surpasses a certain threshold or ‘hurdle’. The hurdle height approaches unity when we can take the hurdle width to greatly exceed the atmosphere's intrinsic deformation length, as holds on gas giants. In this case, the Kelvin–Arnol’d sufficient condition of stability accurately detects instability. These results improve the theoretical framework for explaining the stable maintenance of Jupiter and Saturn's jets over decadal time scales.