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Defects in solid-state systems are responsible for much of what we take for granted in modern society, with applications ranging from electronics and lasers, to metallic alloys with tailored properties, and the unique characteristics of gemstones. As we enter the age of quantum technology, solid-state defects are also having their say, with substantial research focused on using their properties for fundamental tests of quantum mechanics, storage of quantum information, and investigations of quantum decoherence. Two of the most exciting prospects of quantum technology are the creation of computers that take advantage of quantum rather than classical laws to outperform current devices, and the realization of highly sensitive magnetometers limited only by quantum uncertainty. In pursuit of these two goals, many proposals and proof-of-principle experiments have been performed in the solid-state, which required location of defects very close to the host crystal’s surface. This article reviews recent work on creation of nitrogen-vacancy centers near the diamond surface and experiments toward the realization of these goals.
Advances in nanotechnology have enabled the opportunity to fabricate nanoscale optical devices and chip-scale systems in diamond that can generate, manipulate, and store optical signals at the single-photon level. In particular, nanophotonics has emerged as a powerful interface between optical elements such as optical fibers and lenses, and solid-state quantum objects such as luminescent color centers in diamond that can be used effectively to manipulate quantum information. While quantum science and technology has been the main driving force behind recent interest in diamond nanophotonics, such a platform would have many applications that go well beyond the quantum realm. For example, diamond’s transparency over a wide wavelength range, large third-order nonlinearity, and excellent thermal properties are of great interest for the implementation of frequency combs and integrated Raman lasers. Diamond is also an inert material that makes it well suited for biological applications and for devices that must operate in harsh environments.
The nitrogen-vacancy (NV) center in diamond offers the opportunity to develop quantum technologies that leverage the defect’s atom-like properties using established engineering techniques from the semiconductor industry. While many NV center applications are motivated by the remarkable properties of isolated NV centers in bulk diamond, realizing these technologies requires addressing a number of device and materials engineering challenges unique to creating and controlling individual semiconductor spins. We review recent advances in interfacing NV centers with on-chip electronics that enable control over the defect’s spin and orbital degrees of freedom and review fabrication techniques for creating single NV centers with nanometer-scale placement accuracies. We also discuss efforts, motivated by the success of diamond NV center applications, to identify defect spins with similar properties to the NV center in more technologically mature semiconductors such as SiC.
Within the last decade, inkjet printing technology has developed from only a text and graphic industry to a major topic of scientific research and development. Inkjet printing can be used as a highly reproducible noncontact patterning technique to print at high speeds either small or large areas with high quality features; it requires only small amounts of functional materials, which immediately lower production costs. Furthermore, inkjet printing reduces the amount of processing steps due to its additive technique of materials deposition, which further decreases productions costs. This contribution provides a literature survey covering the latest results in low temperature sintering inkjet-printed metal precursor materials in a fast and efficient manner, aiming for roll-to-roll processing. The prepared features can be used as interconnects and contacts for microelectronic applications, including organic light-emitting diodes, organic photovoltaics, and radio frequency identification tags.
Nitrogen-vacancy (NV) color centers in diamond are currently considered excellent solid-state magnetic field sensors. Their long coherence times at room temperature and their atomic size allow for achieving both high magnetic field sensitivity and nanoscale spatial resolution in ambient conditions. This article reviews recent progress in magnetic field imaging with NV centers. We focus on two topics: scanning probe techniques with single NV centers and their application in the imaging of nanoscale magnetic structures, as well as recent development of magnetometers with ensembles of NV centers, which image magnetic fields at micron-length scales with extremely high sensitivities.
Many studies have been carried out to thoroughly understand the colorization mechanisms of bird feathers. However, most of the methods used so far are time-consuming (in days) and involve rather complicated steps (5 to 12). Here, we report a rapid way of producing ‘PbS bird feathers’; this method is inspired by a hair-dyeing method used in ancient Egypt 4000 years ago. The complete synthesis route comprises only two steps and can be completed within 2 h, with the original morphologies of bird feathers well preserved. This method has potential to be extended to the fast fabrication of other functional sulfides which are too complicated to fabricate otherwise.
This article describes the multifunctional applications of TiO2. It substantiates the universality of the anodization process to grow well-ordered TiOxnanotube (T–NT) of hollow cylindrical shape on a variety of planar and nonplanar substrates. It highlights an approach to effectively bring down the cost of anodization via utilization of a small volume of electrolyte. The multifunctionality of these nanostructures is highlighted through representative examples that illustrate wide ranging optical, electronic, and catalytic properties. Combining the T–NT with other materials such as metals and photoactive additives to form composite nanostructures has been shown to benefit photocatalysis, photovoltaics, biological processes, and environment-related applications. This article also demonstrates the applicability of T–NT as an agent to produce dissolved oxygen in simulated blood—an application that can assist in the development of artificial lungs. Key results from the research group, collaborations, and recent articles are highlighted.
A whisker and hillock growth model based on local film microstructure, grain misorientation, and elastic strain energy density (ESED) as the driving force for growth was developed to predict preferred sites for growth. Local grain orientations and strains measured by synchrotron microdiffraction in nine regions containing whiskers or hillocks were compared with elastic finite element analysis simulations including Sn elastic anisotropy. Whisker and hillock grains were observed to have higher crystallographic misorientations with neighboring grains than generally observed in the microstructure. While elastic simulations predicted higher local out-of-plane elastic strains and ESEDs at those locations with high misorientations before growth, synchrotron measurements of out-of-plane strains of whisker and hillock grains after growth showed relaxation, with correspondingly low ESEDs calculated from measured strains. Hence, highly localized out-of-plane elastic strains and ESEDs of grains with high relative misorientations with their neighbors determined, at least in part, which grains became whiskers or hillocks.