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The general concept of multiferroic materials as those with strong interplay between two or more ferroic properties is first introduced. Then, particular cases of materials with coupling magnetic and polar (magnetoelectric coupling), polar and structural (electrostructural coupling), and magnetic and structural (magnetostructural coupling) degrees of freedom are discussed in more detail. The physical origin of the interplay is analysed and symmetry-based considerations are used to determine the dominant coupling terms adequate to construct extended Ginzburg–Landau models that permit the determination of cross-response to multiple fields. The last part of the chapter is devoted to study morphotropic systems and morphotropic phase boundaries that separate crystallographic phases with different polar (magnetic) properties as examples of materials with electro(magneto)-structural interplay and that are expected to show giant cross-response to electric (magnetic) and mechanical fields.
Ruzsa asked whether there exist Fourier-uniform subsets of $\mathbb Z/N\mathbb Z$ with density $\alpha$ and 4-term arithmetic progression (4-AP) density at most $\alpha^C$, for arbitrarily large C. Gowers constructed Fourier uniform sets with density $\alpha$ and 4-AP density at most $\alpha^{4+c}$ for some small constant $c \gt 0$. We show that an affirmative answer to Ruzsa’s question would follow from the existence of an $N^{o(1)}$-colouring of [N] without symmetrically coloured 4-APs. For a broad and natural class of constructions of Fourier-uniform subsets of $\mathbb Z/N\mathbb Z$, we show that Ruzsa’s question is equivalent to our arithmetic Ramsey question.
We prove analogous results for all even-length APs. For each odd $k\geq 5$, we show that there exist $U^{k-2}$-uniform subsets of $\mathbb Z/N\mathbb Z$ with density $\alpha$ and k-AP density at most $\alpha^{c_k \log(1/\alpha)}$. We also prove generalisations to arbitrary one-dimensional patterns.
Non-equilibrium phase transitions are non-thermal transitions that occur out-of-equilibrium. The chapter first discusses systems that are subjected and respond with hysteresis to an oscillating field due to a competition between driving and relaxation time scales. When the former is much shorter than the latter, a non-equilibrium transition occurs associated with the dynamical symmetry breaking due to hysteresis. A dynamical magnetic model is introduced and it is shown that the mean magnetization in a full cycle is the adequate order parameter for this transition. A mean-field solution predicting first-order, critical and tricritical behaviours is analysed in detail. The second example refers to externally driven disordered systems that respond intermittently through avalanches. The interesting aspect is that for a critical amount of disorder, avalanches occur with an absence of characteristic scales, which define avalanche criticality as reported in different ferroic materials. This behaviour can be accounted for by lattice models with disorder, driven by athermal dynamics.
Convective boundary layers are governed by an interplay of vertical turbulent convection and shear-driven turbulence. Here, we investigate vertical velocity and buoyancy fields in convective boundary layers for varying atmospheric conditions by combining probability density function methods and direct numerical simulations. The evolution equations for the probability density functions of vertical velocity and buoyancy contain unclosed terms in the form of conditional averages. We estimate these terms from our direct numerical simulations data, and discuss their physical interpretation. Furthermore, using the method of characteristics, we investigate how these unclosed terms jointly determine the average evolution of a fluid element in a convective boundary layer, and how it relates to the evolution of the probability density functions of vertical velocity and buoyancy as a function of height. Thereby, our work establishes a connection between the turbulent dynamics of convective boundary layers and the resulting statistics.
The instability characteristics and laminar–turbulent transition of a series of laminar separation bubbles (LSBs) formed due to a single sinusoidal surface waviness are investigated in the absence of external disturbances or forcing. A scaling based on the geometrical parameters of the waviness and flow Reynolds number is found that enables the prediction of flow separation on the wall leeward side. The analysis of three-dimensional instabilities of two-dimensional base flows reveals a relation between the number of changes in the curvature sign of the recirculating streamlines and the number of unstable centrifugal modes that coexist for the same flow. When multiple curvature changes occur, in addition to the usual steady mode reported for two-dimensional recirculation bubbles, a new self-excited mode with a higher growth rate emerges, localised near the highest streamline curvature, close to the reattachment point. A detailed analysis of the mode growth and saturation using DNS reveals that the localised mode only disturbs the LSB locally, while the usual one leads to a global distortion of the bubble in the spanwise direction; this has a distinctive impact on the self-excited secondary instabilities. Then, the complete transition scenario is studied for two selected LSB cases. The first one only presents an unstable eigenmode, namely the usual centrifugal mode in recirculating flows. The second case presents three unstable eigenmodes: two centrifugal eigenmodes (the usual and the localised ones) and a two-dimensional eigenmode associated with the self-sustained Kelvin–Helmholtz waves. These results show how completely different transition scenarios can emerge from subtle changes in the LSB characteristics.
The chapter starts with a unified view of glassy states in ferroic materials. Disorder and frustration are the main ingredients responsible for the glassy behaviour, which is identified as a strong frequency dependence of the ac-susceptibility in addition to the occurrence of memory effects detected in zero-field-cooling (ZFC) versus field-cooling (FC) measurements of the temperature dependence of the main ferroic property. Dilute magnetic alloys are taken as prototypical examples of materials displaying glassy behaviour. The physical origin is justified by considering the random distribution of the low concentration of magnetic atoms and their RKKY oscillating exchange interaction. This behaviour is used to inspire lattice models which are (extensions of the Ising model) adequate to study glassy behaviour at a microscopic scale. The particular case of spin glasses is considered in detail and mean-field solutions based on the replica symmetry approach are discussed. Finally, similar models for relaxor ferroelectric and strain glasses are also introduced and briefly described.
Quantum phase transitions occur at zero temperature driven by quantum fluctuations instead of thermal fluctuations. They take place due to competing ground state phases that are accessible for different values of certain non-thermal parameters such as coupling constants, pressure or magnetic field. The chapter starts with a discussion of the main phenomenological features of this class of non-thermal transitions. In particular, it is argued that traces of these transitions can be detected at finite (but low) temperature. Then, examples of materials that show this behaviour are provided. Finally, the quantum Ising model is discussed and it is shown that a quantum model in d dimensions can be mapped to a classical model in d+1 dimensions.
The chapter discusses caloric materials, which are those that show large and reversible thermal response to an applied external field, either mechanical, electric or magnetic. The corresponding effects are denoted as mechanocaloric, electrocaloric and magnetocaloric effects, respectively. The response is usually quantified by the changes of entropy and temperature induced by isothermal and adiabatic application/removal of a field, respectively. These quantities are large in the vicinity of phase transitions and, in particular, close to a first-order transition where the latent heat provides a large caloric response. Well-known examples are ferroic materials in the vicinity of their transition towards the ferroic phase. The chapter starts with the study of caloric effects near a critical point and subsequently caloric behaviour near a first-order transition is analysed. Then, the possibility of multicaloric effects that can be induced by multiple fields in multiferroic materials is considered and a general thermodynamic formalism of multicaloric effects is developed.
Liquid crystals are complex materials that share properties of both solids and liquids. This is a consequence of complex anisotropic molecules that permit establishing phases with orientational and positional orders. Thus, a large variety of phases and phase transitions can occur in these systems. After a detailed description of general features of these materials, the tensorial nature of the orientational order parameter is discussed. Then, the Landau–de Gennes theory is developed for the isotropic–nematic transition. Later, positional degrees of freedom are included to account for the nematic–smectic transition. Next, the theory is generalized to include fluctuations, distortions and the effect of an external field. In the last part, topological defects are discussed with a particular emphasis on defects such as skyrmions and merons which can form in chiral liquid crystals such as cholesteric and blue phases. Finally, the analogy of these classes of defects with those occurring in non-collinear magnetic materials is considered.
We perform direct numerical simulations of centrifugal convection with an oscillating rotational velocity of small amplitude to study the effects of oscillatory boundary motion. The oscillation period is the main control parameter, with its range corresponding to a Womersley number in the range $1\lt Wo\lt 300$. Oscillating boundaries generate a circumferential shear flow, which significantly inhibits heat transfer, with maximum suppression $87\,\%$ observed in the present parameter space. Through analysis of the background flow, we find that as the oscillation period increases, the increasing penetration depth of the oscillation and weakening local shear strength result in non-monotonic changes in heat transfer. Under high-frequency oscillation, the characteristic length scale of the viscous layer induced by the oscillation is smaller than the convective length scale, and shear manifests primarily as a continuous suppression of the boundary layer. In contrast, under low-frequency oscillation, the shear flow covers the entire region but with weak strength. The suppression effect of such shear flow exhibits periodicity, leading to alternating phases of convection inhibition and convection generation. The present findings explore the physical mechanisms behind the suppression of convective heat transfer by oscillation, and offer a new strategy for controlling convection systems, with potential implications for both fundamental research and industrial applications.
The chapter introduces in a unified manner all ferroic materials including the three main ferroic systems, namely ferromagnetic, ferroelectric and ferroelastic, in addition to the case of materials that can display ferrotoroidic order. General physical aspects of magnetism, electricity and elasticity are used in order to introduce the order parameters that conveniently describe all these classes of ferroic phase transitions. It is shown that while the order parameter has a vectorial nature for ferromagnetic (axial vector), ferroelectric (polar vector) and magnetic ferrotoroidal (axial vector) systems, it is a rank-2 polar tensor in ferroelastic materials. The resulting physical differences arising from the different nature of the order parameter are then analysed in detail. Next, it is shown how to construct a convenient Ginszburg–Landau free energy functional in terms of these order parameters and their coupling for the different ferroic systems besides how to obtain the corresponding phase diagrams and microstructural features.
A generalised multiparameter model for linear modal stability and sensitivity analysis is developed. The stability and sensitivity equations are derived from a generalised vector-form governing equation comprised of multiple dimensionless parameters that represent different physical forces affecting the system’s stability. By introducing adjoint variables and constructing the Lagrangian identity, a differential relationship between the eigenvalue of the perturbation mode and dimensionless parameters is determined and defined as the global sensitivity gradient. It provides the constraint that must be satisfied for changes in different dimensionless parameters along the isoeigenvalue curve, which aids in the fast computation of the neutral curve. Moreover, the global sensitivity gradient can directly and intuitively evaluate the competitive relationship among the influences of various parameters on system instability. Based on the global sensitivity gradient, an optimal stability control strategy for transitioning from an unstable state to a stable state is discussed. Additionally, the relative sensitivity function is also introduced to investigate the influence of relative parameter variations on instability. To demonstrate the effectiveness of this method, three applications are presented: two-dimensional flow around a circular cylinder with a single dimensionless parameter Re; three-dimensional axisymmetric magnetohydrodynamic (MHD) flow around a sphere with two parameters Re and $N$; and two-dimensional MHD mixed convection with three parameters Re, ${\textit{Gr}}$ and $\textit{Ha}$.
Power minimisation in branched fluidic networks has gained significant attention in biology and engineering. The optimal network is defined by channel radii that minimise the sum of viscous dissipation and the volumetric energetic cost of the fluid. For limit cases including laminar flows, high-Reynolds-number turbulence or smooth-channel approximations, optimal solutions are known. However, current methods do not allow optimisation for a large intermediate part of the parameter space which is typically encountered in realistic fluidic networks that exhibit turbulent flow. Here, we present a unifying optimisation approach based on the Darcy friction factor, which has been determined for a wide range of flow regimes and fluid models and is applicable to the entire parameter space: (i) laminar and turbulent flows, including networks that exhibit both flow types, (ii) non-Newtonian fluids (powerlaw, Bingham and Herschel–Bulkley) and (iii) networks with arbitrary wall roughness, including non-uniform relative roughness. The optimal channel radii are presented analytically and graphically. All existing limit cases are recovered, and a concise framework is presented for systematic optimisation of fluidic networks. Finally, the parameter $x$ in the optimisation relationship $Q\propto R^{x}$, with $Q$ the flow rate and $R$ the channel radius, was approximated as a function of the Reynolds number, revealing in which case the entire network can be optimised based on one optimal channel radius, and in which case all radii must be optimised individually. Our approach can be extended to a wide range of fluidic networks for which the friction factor is known, such as different channel curvatures, bubbly flows or specific wall slip conditions.
The spatiotemporal dynamics of a turbulent boundary layer subjected to an unsteady pressure gradient are studied. A dynamic sequence of favourable to adverse pressure gradients (FAPGs) is imposed by deforming a section of the wind tunnel ceiling, transitioning the pressure gradient from zero to a strong FAPG within 0.07 s. At the end of the transient, the acceleration parameter is $K$ = $6 \times 10^{-6}$ in the favourable pressure gradient (FPG) region and $K$ = $-4.8 \times 10^{-6}$ in the adverse pressure gradient (APG) region. The resulting unsteady response of the boundary layer is compared with equivalent steady pressure gradient cases in terms of turbulent statistics and coherent structures. While the steady FAPG effects, as shown by Parthasarathy & Saxton-Fox (2023), caused upstream stabilisation in the FPG, a milder APG response downstream, and the formation of an internal layer, the unsteady case presented in this paper shows a reduced stabilisation in the FPG region, a stronger APG response and a weaker internal layer. This altered response is hypothesised to stem from the different spatiotemporal pressure gradient histories experienced by turbulent structures when the pressure gradient changes at a time scale comparable to their convection.