Medium to small petrels that mostly nest in burrows or crevices represent a large fraction of the world’s seabirds, yet their population trends are largely unknown. This lack of knowledge, which has implications for conservation planning, results mostly from methodological difficulties and from the approaches that have been used for their monitoring. Here, we present the surveying scheme created to monitor Cory’s Shearwater Calonectris borealis breeding numbers at their largest known colony, Selvagem Grande (Portugal). We defined 60 circular plots at fixed locations on this 2.45 km2 island and counted nests with eggs annually at the end of laying. Results show that the population increased at 1.45% (95% confidence interval [CI]: 0.72–2.01%) per year between 2009 and 2023. We estimate that the current population size is 38,830 pairs (95% quantile CIs = 34,373–43,713). To the best of our knowledge, this study provides the first systematic information (using fully repeatable methods and providing CIs for the estimates) on population trends of Cory’s Shearwaters, one of the most abundant seabirds in the warm temperate and subtropical North Atlantic and one of the most studied petrels globally. Monitoring using the approach detailed here requires two days of work (by 2–3 persons) per year. Our results and simulations indicate that this is a powerful methodology, with narrow confidence limits for estimated trends and an ability to detect small population changes over short time spans. We suggest that more monitoring protocols similar to this one (with necessary site-specific adaptations, particularly for potential colony expansion where suitable habitat exists) should be developed and implemented in a range of colonies with crevice and burrowing nesting petrels to improve our knowledge on the population status of a broad fraction of the world’s seabirds.

Sport climbing requires a combination of physical and cognitive skills, with working memory (WM) playing a crucial role in performance. This study aimed to investigate the association between WM capacity and climbing ability, while considering potential confounding factors including sex, age, education level, and climbing experience. Additionally, the study compared prefrontal cortex (PFC) hemodynamic responses among different climbing ability groups and sex during WM performance. Twenty-eight climbers participated, with WM assessed using the eCorsi task and PFC hemodynamic responses measured with near infrared spectroscopy (NIRS). Initial linear regression analyses revealed no association between WM and climbing ability. However, significant associations were found after adjustment for covariates. Specifically, sex (p = .014), sex in conjunction with age (p = .026), sex combined with climbing experience (p = .022), and sex along with education level (p = .038) were identified as significant predictors of differences in WM between Expert and Elite climbers. Additionally, notable differences in PFC hemodynamic responses were observed between Expert and Elite climbers, as well as between sexes during the WM task, providing support for differences in WM capacity. This study contributes to understanding the complex relationship between WM capacity and climbing performance, emphasizing the need to account for influencing factors in assessments.

The problem of spontaneity and the capability of adaptation in the development of civilizations, which is the subject of the current issue, is in my view inseparable from the problem posed by the relations between reality and the images of reality. Two cultures existing side by side confront each other in many ways and in countless sectors. And in every case this confrontation gives rise in each of them to a particular image of the other. Unstable, changing images succeed each other, and from the moment they appear condition the terms of the confrontation to the extent to which they constitute the key that every culture possesses for judging the singular characteristics of the other. It is this image that gives meaning to each of the isolated elements and consequently to the whole. Judging—or prejudging—on the basis of this established meaning, the social groups through which two cultures make contact with each other accept or reject the peculiar characteristics of their opposite number, and react in this confrontation with conditioned attitudes. Thus, the image of a cultural reality has become an established fact of the reality and operates as such. What appears spontaneous in one culture, which has become merged with another, or what results from adaptation, may derive from certain genuine forms of the other culture but also from the idea that one culture may have gained of another. And as this belief —which operates as a given factor of the reality—has been elaborated through very obscure psycho-social processes, it is indispensable to start from the basis of the accepted forms that have created it and to follow from there the process of its formation.

High-risk pregnancies elevate maternal stress, impacting offspring neurodevelopment and behavior. This study, involving 112 participants, aimed to compare perceived stress, neurodevelopment, and behavior in high-risk and low-risk pregnancies. Two groups, high-risk and low-risk, were assessed during pregnancy for stress using hair cortisol and psychological analysis. At 24 months post-birth, their children’s neurodevelopment and behavior were evaluated. Results revealed higher perceived stress and pregnancy-related concerns in high-risk pregnancies, contrasting with low-risk pregnancies. Offspring from high-risk pregnancies displayed elevated internalizing behavior scores, while low-risk pregnancies showed higher externalizing behavior scores. Additionally, women in low-risk pregnancies exhibited increased cortisol concentrations 24 months post-delivery. These findings underscore the necessity for early stress detection and prevention programs during pregnancy, particularly in high-risk cases, to enhance maternal and infant health.

There is a general consensus that providing care for a relative that has dementia is associated with negative outcomes for caregivers’ mental health. There seem to be also associations with negative physical health outcomes, although the literature on this topic is more scarce. Most of the available research consist in studies with a cross-sectional design. Longitudinal studies focused on psychosocial correlates of mental and physical health of the caregivers are lacking, mostly those analyzing the influence of factors such as behavioral and psychological symptoms of the dementia, caregivers` dysfunctional thoughts, and caregivers’ ambivalent and guilt feelings. The aim of this presentation will be to describe the findings from the Madrid Caregivers Longitudinal Study, that consist in a two year follow-up of family caregivers of people with dementia. Several models will be described testing the longitudinal effect of psychosocial variables on caregivers’ distress (depression and anxiety) and cardiovascular health (measured through biomarkers of inflammation). The practical implications of the findings will be discussed.

PEPAdb (Prehistoric Europe's Personal Adornment Database) is a long-term, open-ended project that aims to improve access to archaeological data online. Its website (https://pepadb.us.es) publishes and analyses datasets about prehistoric personal adornment, drawing on the results of various research projects and bibliographic references.

In this study, we address interpersonal violence during the transition between the Middle and the Late Formative periods in the Central Andes, a critical period of political disintegration, hypothesized population pressure, and reorganization of the belief systems that is poorly known from a bioarchaeological viewpoint. Our objective is to understand the nature of the violence and associated factors in this context based on a detailed description of skeletal trauma in 67 well-preserved individuals (20 adolescents and adults and 47 subadults) recovered from Quebrada Chupacigarro cemetery (500–400 BC); this site is located in the middle valley of Supe on the Peruvian north-central coast. To detect patterns and potential causes, we registered the prevalence of traumatic injury according to age, sex, anatomic location, mechanisms (blunt, sharp, mixed, etc.), timing (antemortem or perimortem), and manner (inflicted or accidental). The results show a high prevalence of fractures in the whole population, but especially in adolescents and adults. Eighty percent of the adolescents and adults perished due to the intentional trauma and show patterns that suggest repetitive episodes of interpersonal violence. Perimortem injuries in the skull, face, and thorax are compatible with lethal interpersonal violence. The findings support a probable scenario of intercommunity violence in the middle valley of Supe around 500–400 BC.

Titanium was introduced into the clay structure by cation exchange with polymeric Ti cations which were formed by partial hydrolysis of Ti alkoxide in HCl. X-ray diffraction, N2 adsorption-desorption, chemical analysis, thermogravimetric analysis, differential thermal analysis, temperature-programmed desorption of ammonia and temperature-programmed reduction were used to characterize the resulting Ti-pillared clays (Ti-PILCs). Titanium methoxide allows the synthesis of a solid with a large basal spacing (26 Å), a large surface area (360 m2/g), a significant amount of micropore surface area (90%), and notable acidity. Moreover, Ti-PILCs obtained from methoxide were found to be thermally stable up to 500°C. A correlation between the increase in acidity and the increases in both microporosity and Ti content was observed. The surface area, the micropore volume, the acidity and the d001 peak intensity all increased upon increasing the amount of Ti added to the preparation (up to ∼15 mmoles of Ti/g clay). The use of an aqueous suspension of 0.13 wt.% of clay yielded the best structural and textural properties in terms of subsequent use of the clay as a catalyst.

This review is concerned with the synthesis and physical-chemical characteristics of a specific type of modified clay material: Ti-PILCs. The two general synthetic procedures and the main problems associated with the scale-up synthesis of these pillared materials are discussed in detail. The general characteristics of Ti-PILCs in terms of basal spacing, pillar homogeneity, surface area, microporosity, mesoporosity, pore size and distribution, thermal resistance and acidity are discussed in depth. Likewise, the most important synthesis parameters that have a clear and marked influence on the final characteristics of the materials are summarized.

Iron-pillared clays (Fe-PILCs) were synthesized from hydrolyzed FeCl3 solutions added to NaOH solutions using different synthesis conditions. X-ray diffraction, N2 adsorption-desorption, chemical analysis, thermogravimetric analysis, differential thermal analysis, temperature-programmed desorption of ammonia and temperature-programmed reduction were used to characterize the resulting Fe-pillared clays (Fe-PILCs). A higher degree of pillaring was obtained when the Fe content was adjusted to 60 mmoles of Fe/g of clay. It was observed that higher values of this ratio led to worse acidity and textural characteristics, a consequence of the probable formation of Fe oxides that could not only deposit on the surface but also block the pores formed during the pillaring process. Likewise, it was found that the amount of Fe that can be introduced depended on the OH/Fe ratios. Total surface and micropore area decreased and Fe content increased with increasing pillaring solution concentrations. Finally, all pillared samples prepared here were thermally stable at temperatures up to 400°C.

The preparation of porous materials from clay minerals by selective leaching is of interest because it yields residues with large specific surface areas that can be used as adsorbents of contaminants or as catalysts. Grinding produces surface modifications and therefore may significantly influence the leaching behavior. The aim of this paper is to study the effect of grinding and leaching on the structure of the vermiculite from Santa Olalla, Spain, using 57Fe Mössbauer spectroscopy, X-ray diffraction, infrared spectroscopy, and specific surface area (SBET) measurements. The study shows that grinding destroys the long range order of the vermiculite, but leaves the local structure in the environment of the Fe atoms intact, at least up to a grinding time of 10 min. The Mössbauer study shows that there is no Fe3+ in the tetrahedral sheets and that grinding does not lead to a significant oxidation of the structural Fe. Vermiculite ground for 4 min and leached with 1 M HCl solution at 80°C over a 24 h period was decomposed to X-ray amorphous silica with a very large specific surface area (SBET = 720 m2g−1) and with total pore volume of 0.586 cm3 g−1, whereas an unground sample leached with the same acid concentration yielded a specific surface area of only 504 m2 g−1. Most of the Mg2+ and Al3+ are removed from the ground sample after leaching with 1 M HCl, while large percentages of Fe2O3 remain with the X-ray amorphous silica. In unground vermiculite leached with 1 M HCl, a considerable amount of vermiculite remains in the residue. A sample ground for 4 min and treated with 0.25 M HCl also shows the typical vermiculite Mössbauer spectrum with an Fe2+/Fe3+ ratio similar to that of the unground vermiculite. The samples ground for 2 or 4 min and treated with 1 M HCl solution have an orange color and, according to the Mössbauer spectra, only Fe3+ remains. Mössbauer spectra of these samples taken at 4.2 K reveal the presence of akaganéite.

This article revises the spatial and temporal boundaries of the Casas Grandes tradition associated with northwest Chihuahua, Mexico, based on new data collected in neighboring northeastern Sonora. The Casas Grandes tradition attained its greatest extent during the Medio period (AD 1200–1450/1500) followed by a dramatic demographic and political collapse. Hunter-gatherer groups subsequently occupied most of northwest Chihuahua. Data from the Fronteras Valley, Sonora, presents an alternative scenario, with a clear pattern of cultural continuity from the eleventh century to the colonial period in which sedentary farmers occupied the same landscapes and occasionally the same villages. These observations contribute to our understanding of the spread and subsequent demise of the Casas Grandes tradition in hinterland regions. For the Fronteras Valley, we infer that immigrant groups originally introduced Casas Grandes traditions and that uneven participation in a suite of shared religious beliefs and practices was common to all the hinterlands.

This research note provides a preliminary discussion of changing agricultural and food procurement strategies in a smallholder farming community in Piribebuy District, Paraguay. Although considerable attention has been paid to the contemporary problems of soy agriculture in Paraguay, it is also important to engage with the experiences of smallholders who are not involved in or affected by soy cultivation, as this highlights farmers' diverse everyday experiences and their agricultural priorities. We consider three issues that have emerged as key to farmer agricultural decision making in this community: farmer perceptions of environmental changes, processes of dietary delocalization via the movement of food from urban centers to rural communities, and the intersection of labor issues and aging farmers.

Tricuspid valvulopathy has gained a lot of attention in recent years, especially due to the advances in percutaneous management. CHD can present with primary or secondary malfunction of the tricuspid valve, often not addressed due to high surgical risk after several interventions. We present two cases of adults with complex congenital heart malformations and borderline clinical situations who successfully underwent percutaneous tricuspid replacement.

Acanthamoeba spp. are widely distributed in the environment and cause serious infections in humans. Treatment of Acanthamoeba infections is very challenging and not always effective which requires the development of more efficient drugs against Acanthamoeba spp. The purpose of the present study was to test medicinal plants that may be useful in the treatment of Acanthamoeba spp. Here we evaluated the trophozoital and cysticidal activity of 13 flavonoid glycosides isolated from Delphinium gracile, D. staphisagria, Consolida oliveriana and from Aconitum napellus subsp. Lusitanicum against the amoeba Acanthamoeba castellanii. AlamarBlue Assay Reagent® was used to determine the activity against trophozoites of A. castellanii, and cytotoxic using Vero cells. Cysticidal activity was assessed on treated cysts by light microscopy using a Neubauer chamber to quantify cysts and trophozoites. Flavonoids 1, 2, 3 and 4 showed higher trophozoital activity and selectivity indexes than the reference drug chlorhexidine digluconate. In addition, flavonoid 2 showed 100% cysticidal activity at a concentration of 50 μm, lower than those of the reference drug and flavonoid 3 (100 μm). These results suggest that flavonoids 2 and 3 might be used for the development of novel therapeutic approaches against Acanthamoeba infections after satisfactory in vivo evaluations.