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We consider the dynamics of a liquid film with a pinned contact line (for example, a drop), as described by the one-dimensional, surface-tension-driven thin-film equation $h_t + (h^n h_{xxx})_x = 0$, where $h(x,t)$ is the thickness of the film. The case $n=3$ corresponds to a film on a solid substrate. We derive an evolution equation for the contact angle $\theta (t)$, which couples to the shape of the film. Starting from a regular initial condition $h_0(x)$, we investigate the dynamics of the drop both analytically and numerically, focusing on the contact angle. For short times $t\ll 1$, and if $n\ne 3$, the contact angle changes according to a power law $\displaystyle t^{\frac {n-2}{4-n}}$. In the critical case $n=3$, the dynamics become non-local, and $\dot {\theta }$ is now of order $\displaystyle {\rm{e}}^{-3/(2t^{1/3})}$. This implies that, for $n=3$, the standard contact line problem with prescribed contact angle is ill posed. In the long time limit, the solution relaxes exponentially towards equilibrium.
The interaction between acoustic and surface gravity waves is generally neglected in classical water-wave theory due to their distinct propagation speeds. However, nonlinear dynamics can facilitate energy exchange through resonant triad interactions. This study focuses on the resonant triad interaction involving two acoustic modes and a single gravity wave in water of finite and deep depths. Using the method of multiple scales, amplitude equations are derived to describe the spatio-temporal behaviour of the system. Energy transfer efficiency is shown to depend on water depth, with reduced transfer in deeper water and enhanced interaction in shallower regimes. Numerical simulations identify parameter ranges, including resonant gravity wavenumber, initial acoustic amplitude and wave packet width, where the gravity-wave amplitude is either amplified or reduced. These results provide insights into applications such as tsunami mitigation and energy harnessing.
One of the earliest discoveries of Permo-Carboniferous terrestrial vertebrates in North America occurred in 1875 along Horseshoe Bend, a cutbank on the Salt Fork of the Vermilion River west of Danville, Vermilion County, east-central Illinois. The discovery was soon eclipsed by the description of similar but much more complete remains from the Lower Permian of Texas in 1878. The deposit itself was obliterated by slumping and erosion in the earliest 1900s and has not been collected since despite repeated efforts. Previously unreported outcrop records and subsurface data indicate that the deposit originated as a paleochannel fill in the Inglefield Sandstone Member of the Patoka Formation, which underlies the Macoupin Limestone Member (early Missourian Stage of the Midcontinent, early Kasimovian Stage of global Carboniferous time scale). In addition to aquatic to terrestrial tetrapods, teeth of lungfishes (Sagenodus Owen, 1867, Conchopoma Cope, 1877a, Gnathorhiza Cope, 1883a) and teeth, occipital spines, and coprolites of a xenacanth shark (Orthacanthus Agassiz, 1838) are known from Horseshoe Bend. The teeth of the marine petalodont shark Janassa Münster, 1839, also are present in the collection but presumed to have been derived from one of the beds on the cutbank that produced brackish to marine invertebrate fossils. Alhough not diverse, the tetrapod assemblage is significant in that it contains the oldest diplocaulid amphibian (Diplocaulus salamandroides Cope, 1877a), fragmentary remains of the oldest diadectid and limnoscelid stem reptiles, and possibly the oldest captorhinid eureptile, all of which have not been adequately described. The ophiacodontid synapsid Clepsydrops Cope, 1875, is the most common fossil at Danville, which could be an artifact of primitive collecting methods that did not promote the recovery of articulated material. An accurate stratigraphic placement of the Horseshoe Bend deposit and a review of other late Carboniferous tetrapod localities reveals that this important Illinois locality combines an overlooked vanguard of terrestrial taxa regarded as Permo-Carboniferous (Kasimovian-Asselian) and amphibious to aquatic forms known from older, Moscovian deposits.
A complete analytical solution procedure is proposed here to work out the mixed boundary value problems associated with the oblique wave scattering problem involving either a complete elastic porous plate or a permeable membrane in both the cases of finite and infinite depth water in a two-layer fluid. Problems for two different velocity potentials with a phase difference are described in the upper half-planes. They are redefined as the solution potentials for the problems in the quarter-plane. A couple of novel integro-differential relations are constructed to connect the solution potentials of the redefined problems with auxiliary wave potentials. The subsequent potentials are solutions to relatively simpler boundary value problems for the modified Helmholtz equation, with structural boundary conditions of the Neumann type. The generalised orthogonal relation is then used to address the auxiliary wave potential problems analytically. The solution wave potentials are then derived in terms of these auxiliary wave potentials with the aid of the integro-differential relations. Further, explicit analytical expressions are derived for the significant hydrodynamic quantities such as energy reflection and transmission coefficients corresponding to the surface mode (SM) and interface mode (IM), respectively. Moreover, the deflection of the flexible porous structures is derived analytically. The scattering quantities in both SM and IM are presented graphically against the wavenumber and angle of incidence for various values of non-dimensional parameters involved in the structures.
The dissolution kinetics occurring on clay minerals are influenced by various factors, including pH, temperature and mineral lattice structure. However, the influence of the surfactant is rarely studied. In the present work, cationic surfactants were investigated in terms of the dissolution of clay minerals in acidic environments. Kaolinite was selected as the representative clay mineral. The cationic surfactant inhibited the dissolution of clay minerals because it limited the attack of H+ on the kaolinite surface and then inhibited the dissolution of kaolinite by modifying the hydrophilicity of the kaolinite surface towards hydrophobicity. The inhibition ability of the surfactant might be related to its molecular structure and the type of acid used in dissolution experiments.
The accumulation area ratio (AAR) of a glacier reflects its current state of equilibrium, or disequilibrium, with climate and its vulnerability to future climate change. Here, we present an inventory of glacier-specific annual accumulation areas and equilibrium line altitudes (ELAs) for over 3000 glaciers in Alaska and northwest Canada (88% of the regional glacier area) from 2018 to 2022 derived from Sentinel-2 imagery. We find that the 5 year average AAR of the entire study area is 0.41, with an inter-annual range of 0.25–0.49. More than 1000 glaciers, representing 8% of the investigated glacier area, were found to have effectively no accumulation area. Summer temperature and winter precipitation from ERA5-Land explained nearly 50% of the inter-annual ELA variability across the entire study region (${R}^2=0.47$). An analysis of future climate scenarios (SSP2-4.5) projects that ELAs will rise by ∼170 m on average by the end of the 21st century. Such changes would result in a loss of 25% of the modern accumulation area, leaving a total of 1900 glaciers (22% of the investigated area) with no accumulation area. These results highlight the current state of glacier disequilibrium with modern climate, as well as glacier vulnerability to projected future warming.
Two-dimensional Euler flows, in the plane or on simple surfaces, possess a material invariant, namely the scalar vorticity normal to the surface. Consequently, flows with piecewise-uniform vorticity remain that way, and moreover evolve in a way which is entirely determined by the instantaneous shapes of the contours (interfaces) separating different regions of vorticity – this is known as ‘contour dynamics’. Unsteady vorticity contours or interfaces often grow in complexity (lengthen and fold), either as a result of vortex interactions (like mergers) or ‘filamentation’. In the latter, wave disturbances riding on a background, equilibrium contour shape appear to inevitably steepen and break, forming filaments, repeatedly– and perhaps endlessly. Here, we revisit the onset of filamentation. Building upon previous work and using a weakly nonlinear expansion to third order in wave amplitude, we derive a universal, parameter-free amplitude equation which applies (with a minor change) both to a straight interface and a circular patch in the plane, as well as circular vortex patches on the surface of a sphere. We show that this equation possesses a local, self-similar form describing the finite-time blow up of the wave slope (in a re-scaled long time proportional to the inverse square of the initial wave amplitude). We present numerical evidence for this self-similar blow-up solution, and for the conjecture that almost all initial conditions lead to finite-time blow up. In the full contour dynamics equations, this corresponds to the onset of filamentation.
The present study describes a new Mediterranean terebellid, Spinosphaera latachaeta sp. nov., found along the Aegean coast of Türkiye and the Sea of Marmara, between 27 and 80 m depth in soft substrata. It can be morphologically distinguished from all other species of Spinosphaera having 18 pairs of notopodia, double rows of uncini present until the last notopodia, and 11 pairs of Spinosphaera-chaetae. A dichotomous taxonomic key and a table summarizing the morphological characters that distinguish all species of Spinosphaera are provided. This study also reports, for the first time, the transformations of Spinosphaera-chaetae and saw-like chaetae from the anterior to posterior segments of body.
The wave kinetic equation has become an important tool in different fields of physics. In particular, for surface gravity waves, it is the backbone of wave forecasting models. Its derivation is based on the Hamiltonian dynamics of surface gravity waves. Only at the end of the derivation are the non-conservative effects, such as forcing and dissipation, included as additional terms to the collision integral. In this paper, we present a first attempt to derive the wave kinetic equation when the dissipation/forcing is included in the deterministic dynamics. If, in the dynamical equations, the dissipation/forcing is one order of magnitude smaller than the nonlinear effect, then the classical wave action balance equation is obtained and the kinetic time scale corresponds to the dissipation/forcing time scale. However, if we assume that the nonlinearity and the dissipation/forcing act on the same dynamical time scale, we find that the dissipation/forcing dominates the dynamics and the resulting collision integral appears in a modified form, at a higher order.
Planar linear flows are a one-parameter family, with the parameter $\hat {\alpha }\in [-1,1]$ being a measure of the relative magnitudes of extension and vorticity; $\hat {\alpha } = -1$, $0$ and $1$ correspond to solid-body rotation, simple shear flow and planar extension, respectively. For a neutrally buoyant spherical drop in a hyperbolic planar linear flow with $\hat {\alpha }\in (0,1]$, the near-field streamlines are closed for $\lambda \gt \lambda _c = 2 \hat {\alpha } / (1 - \hat {\alpha })$, $\lambda$ being the drop-to-medium viscosity ratio; all streamlines are closed for an ambient elliptic linear flow with $\hat {\alpha }\in [-1,0)$. We use both analytical and numerical tools to show that drop deformation, as characterized by a non-zero capillary number ($Ca$), destroys the aforementioned closed-streamline topology. While inertia has previously been shown to transform closed Stokesian streamlines into open spiralling ones that run from upstream to downstream infinity, the streamline topology around a deformed drop, for small but finite $Ca$, is more complicated. Only a subset of the original closed streamlines transforms to open spiralling ones, while the remaining ones densely wind around a configuration of nested invariant tori. Our results contradict previous efforts pointing to the persistence of the closed streamline topology exterior to a deformed drop, and have important implications for transport and mixing.
Soricidae is the most species-rich eulipotyphlan family since the Pliocene. Numerous Late Miocene soricids and plesiosoricids are well known from southern Europe. Localities from central Europe, despite being rare, historically have yielded better preserved material that reveals a great diversity. We here add to this existing record with the description of eight species from MN9- to MN12-aged localities of Slovakia (Paenelimnoecus repenningi, Paenesorex bicuspis, Isterlestes aenigmaticus n. gen. n. sp., Crusafontina endemica, Crusafontina kormosi, Amblycoptus jessiae, Asoriculus gibberodon, Petenyia dubia), alongside one species of Plesiosoricidae (Plesiosorex evolutus). The early occurrence of A. gibberodon and A. jessiae, the occurrence of Paenesorex, and the identification of Isterlestes aenigmaticus n. gen. n. sp., reinforce the hypothesis that the Pannonian region (south-eastern central Europe) was a source area for several soricid taxa (Allosoricinae, Anourosoricini, Soricini) during the Late Miocene.
Covering both theory and experiment, this text describes the behaviour of homogeneous and density-stratified fluids over and around topography. Its presentation is suitable for advanced undergraduate and graduate students in fluid mechanics, as well as for practising scientists, engineers, and researchers. Using laboratory experiments and illustrations to further understanding, the author explores topics ranging from the classical hydraulics of single-layer flow to more complex situations involving stratified flows over two- and three-dimensional topography, including complex terrain. A particular focus is placed on applications to the atmosphere and ocean, including discussions of downslope windstorms, and of oceanic flow over continental shelves and slopes. This new edition has been restructured to make it more digestible, and updated to cover significant developments in areas such as exchange flows, gravity currents, waves in stratified fluids, stability, and applications to the atmosphere and ocean.
By constraining organic carbon (OC) turnover times and ages, radiocarbon (14C) analysis has become a crucial tool to study the global carbon cycle. However, commonly used “bulk” measurements yield average turnover times, masking age variability within complex OC mixtures. One method to unravel intra-sample age distributions is ramped oxidation, in which OC is oxidized with the aid of oxygen at increasing temperatures. The resulting CO2 is collected over prescribed temperature ranges (thermal fractions) and analyzed for 14C content by accelerator mass spectrometry (AMS). However, all ramped oxidation instruments developed to date are operated in an “offline” configuration and require several manual preparation steps, hindering sample throughput and reproducibility. Here we describe a compact, online ramped oxidation (ORO) setup, where CO2 fractions are directly collected and transferred for 14C content measurement using an AMS equipped with a gas ion source. Our setup comprises two modules: (i) an ORO unit containing two sequential furnaces, the first of which holds the sample and is ramped from room temperature to ∼900°C, the second of which is maintained at 900°C and holds catalysts (copper oxide and silver) to ensure complete oxidation of evolved products to CO2; and (ii) a dual-trap interface (DTI) collection unit containing two parallel molecular sieve traps, which alternately collect CO2 from a given fraction and handle its direct injection into the AMS. Initial results for well-characterized samples indicate that 14C content uncertainties and blank background values are like those obtained during routine gas measurements at ETH, demonstrating the utility of the ORO-DTI setup.
Turbulent flames in practical devices are subject to a superposition of broadband turbulence and narrowband harmonic flow oscillations. In such cases, flames have a superposition of space–time correlated wrinkles, superposed with broadband turbulent disturbances that interact nonlinearly. This paper extends our prior experimental work to characterise and quantify these flame dynamics. We extract ensemble-averaged flame edge and velocity by ensemble-averaging the instantaneous data at the same phase with respect to the forcing cycle. This paper shows that the ensemble-averaged spatio-temporal dynamics of the flame changes significantly with turbulence intensity. From a spatial viewpoint, the ensemble-averaged flame at weak turbulence intensities exhibits clear cusps and a large ratio between curvature in concave and convex regions. In contrast, at high turbulence intensities, the concave and convex parts of the ensemble-averaged flame are nearly symmetric. From a temporal viewpoint, increasing turbulence intensity monotonically suppresses higher harmonics of the forcing frequency that are manifestations of flame nonlinearities. Taken together, these both point to the interesting observation that the ensemble-averaged flame exhibits increasingly linear dynamics with increasing turbulence intensities, in contrast to its very strong nonlinear behaviours at weak turbulence intensities and juxtaposed with the increasingly nonlinear nature of its instantaneous dynamics with increasing turbulence intensity. In addition, prior studies have shown clear coherent modulation of turbulent flame speed correlated with coherent curvature modulation and that this relationship could be quantified via a ‘turbulent Markstein number’, $M_{T}$. We develop correlations for $M_{T}$ showing how it scales with turbulent and narrowband disturbance quantities, such as turbulent flame brush thickness and convective length scale.