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Ocean submesoscales, flows with characteristic size $10\,\text{m}{-}10\,\text{km}$, are transitional between the larger, rotationally constrained mesoscale and three-dimensional turbulence. In this paper, we present simulations of a submesoscale ocean filament. In our case, the filament is strongly sheared in both vertical and cross-filament directions, and is unstable. Instability indeed dominates the early behaviour with a fast extraction of kinetic energy from the vertically sheared thermal wind. However, the instability that emerges does not exhibit characteristics that match the perhaps expected symmetric or Kelvin–Helmholtz instabilities, and appears to be non-normal in nature. The prominence of the transient response depends on the initial noise, and for large initial noise amplitudes, saturates before symmetric instability normal modes are able to develop. The action of the instability is sufficiently rapid – with energy extraction from the mean flow emerging and peaking within the first inertial period ($\sim\! 18\ \text{h}$) – that the filament does not respond in a geostrophically balanced sense. Instead, at all initial noise levels, it later exhibits vertically sheared near-inertial oscillations with higher amplitude as the initial minimum Richardson number decreases. Horizontal gradients strengthen only briefly as the fronts restratify. These unstable filaments can be generated by strong mixing events at pre-existing stable structures; we also caution against inadvertently triggering this response in idealised studies that start in a very unstable state.
Bubbles entrained by breaking waves rise to the ocean surface, where they cluster before bursting and release droplets into the atmosphere. The ejected drops and dry aerosol particles, left behind after the liquid drop evaporates, affect the radiative balance of the atmosphere and can act as cloud condensation nuclei. The remaining uncertainties surrounding the sea spray emissions function motivate controlled laboratory experiments that directly measure and link collective bursting bubbles and the associated drops and sea salt aerosols. We perform experiments in artificial seawater for a wide range of bubble size distributions, measuring both bulk and surface bubble distributions (measured radii from $30\,\unicode{x03BC} \mathrm{m}$ to $5\,\mathrm{mm}$), together with the associated drop size distribution (salt aerosols and drops of measured radii from $50\,\mathrm{nm}$ to $500\,\unicode{x03BC} \mathrm{m}$) to quantify the link between emitted drops and bursting surface bubbles. We evaluate how well the individual bubble bursting scaling laws describe our data across all scales and demonstrate that the measured drop production by collective bubble bursting can be represented by a single framework integrating individual bursting scaling laws over the various bubble sizes present in our experiments. We show that film drop production by bubbles between $100\,\unicode{x03BC} \mathrm{m}$ and $1\,\mathrm{mm}$ describes the submicron drop production, while jet drop production by bubbles from $30\,\unicode{x03BC} \mathrm{m}$ to $2\,\mathrm{mm}$ describes the production of drops larger than $1\,\unicode{x03BC} \mathrm{m}$. Our work confirms that sea spray emission functions based on individual bursting processes are reasonably accurate as long as the surface bursting bubble size distribution is known.
We present the results of a theoretical investigation of orbital stability in pilot-wave hydrodynamics, wherein a droplet bounces and self-propels across the surface of a vertically vibrating liquid bath. A critical notion in pilot-wave hydrodynamics is that the bath plays the role of the system memory, recording the history of the droplet in its wave field. Quantised orbital motion may arise when the droplet is confined by either an axisymmetric potential or the Coriolis force induced by system rotation. We here elucidate the dependence of the stability of circular orbits on both the form of the confining force and the system memory. We first provide physical insight by distinguishing between potential- and wave-driven instabilities. We demonstrate that the former are a generic feature of classical orbital dynamics at constant speed, while the latter are peculiar to pilot-wave systems. The wave-driven instabilities are marked by radial perturbations that either grow monotonically or oscillate at an integer multiple of the orbital frequency, in which case they are said to be resonant. Conversely, for potential-driven wobbling, the instability frequency may be resonant or non-resonant according to the form of the applied potential. Asymptotic analysis rationalises the different stability characteristics for linear-spring and Coriolis forces, the two cases that have been explored experimentally. Our results are generalised to consider other potentials of interest in pilot-wave hydrodynamics, and elucidate the distinct roles of wave- and potential-driven instabilities. Our study highlights the limitations of prior heuristic arguments for predicting the onset of orbital instability.
The Leidenfrost effect occurs when drops are deposited on a highly superheated solid surface, creating a thin vapour film through rapid evaporation that levitates the drops. For drop with a radius exceeding a critical value, a vapour bubble forms and bursts from its bottom centre, a phenomenon known as chimney instability. Despite extensive investigation, the impact of Leidenfrost drop’s rotation on its chimney instability has remained unexplored. This study addresses this gap by providing both numerical and approximate solutions to the theoretical models. We identify two distinct regimes where either gravitational force or centrifugal force is the primary driver of chimney instability. These regimes are characterised by a non-dimensional rotation number, Ro, which represents the ratio between centrifugal force and gravitational force. Our findings reveal clear scaling laws that relate the critical geometrical parameters (radius, volume and height of the drop) for chimney instability to Ro, demonstrating that rotation can induce chimney instability in smaller drops. The scaling laws are elucidated through pressure perturbation analyses under a virtual perturbation to the drop profile at the critical state for chimney instability. Additionally, by varying the evaporation number $Ev$, we demonstrate that while increased superheat reduces the critical radius in the absence of rotation, the scaling laws related to Ro for a rotating drop remain unaffected. Building on these insights, we present a master curve in a simplified form that accurately predicts the critical state for chimney instability under various angular velocities, gravitational accelerations and superheat conditions.
The existing studies on vortex rings have concentrated on non-zero circulation. However, the cases of zero circulation may also be significantly noteworthy on both theoretical and practical grounds. As the first attempt on this subject, in this paper a family of viscous laminar vortex rings with zero circulation and a moderate ratio of core radius to ring radius is studied using numerical simulations of the incompressible Navier–Stokes equations. This unusual zero circulation is achieved by assigning a special layered vorticity distribution with alternate signs to the vortex core. At the initial moment, the ring is axisymmetric, swirl-free and of a circular cross-section. It is found that the axial symmetry and the non-swirl nature of the vortex ring are preserved during the evolution, and the vortex ring endures a transition from the initial layered structure to a shell structure, then degenerates to an ordinary vortex ring with non-zero circulation at last. Significant vorticity cancellation is observed due to the interactions among the layered structures. A new Reynolds number, based on the absolute value of vorticity, is applied to the zero-circulation vortex rings in the present work. For such vortex rings, cases of both zero and non-zero vortical impulse can happen, unlike the ordinary ones with only non-zero vortical impulse. Additionally, it is found that the vortical impulse can be irrelevant to the ring diameter. The study may shed light on modelling certain real flows characterised by distinct vortex structures or configurations.
The new mineral argentopearceite (IMA2020-049) was found at the mine dump of the abandoned Lehnschafter mine, Mikulov–Hrob district (holotype), and later at museum samples (cotypes) from the Moldava fluorite deposit, both in the Krušné hory Mountains, Czech Republic. Argentopearceite is associated with proustite in quartz gangue (Mikulov) or acanthite and proustite in fluorite gangue (Moldava). The new mineral occurs as tabular (pseudo)hexagonal crystals up to 0.8 mm (Mikulov) and 3 mm (Moldava), and as groups and aggregates up to 1 cm. Argentopearceite from Mikulov is steel grey to black. Mohs hardness is ca. 3; the calculated density is 6.29 g.cm–3. In reflected light, argentopearceite is grey with a greenish shade. Bireflectance was not observed and pleochroism is very weak. Anisotropy under crossed polars is moderate with weak greenish and green–blue tints. Internal reflections were not observed. Reflectance values of argentopearceite in air (Rmin/Rmax, %) are: 27.3/30.0 at 470 nm, 26.6/29.3 at 546 nm, 26.2/28.8 at 589 nm, and 25.9/28.1 at 650 nm). The empirical formula for argentopearceite, based on electron-microprobe analyses (n = 15), is (Ag15.95Cd0.02)Σ15.97(As1.82Sb0.11)Σ1.93(S11.03Cl0.05Te0.01)Σ11.09. The ideal formula is Ag16As2S11, which requires (in wt.%) Ag 77.45, As 6.72 and S 15.83, total of 100.00. Argentopearceite is trigonal, P321, a = 14.8583(5), c = 12.3038(15) Å, with V = 2352.38(15) Å3 and Z = 4. Its crystal structure was refined by single-crystal X-ray diffraction data to a final R1 = 0.0773 on the basis of 6594 unique reflections with Fo > 3σ(F) and 242 refined parameters. The structure of argentopearceite mostly conforms to the general architecture of the As-dominant members of the pearceite–polybasite family of minerals.
Volcanic fissure eruptions typically start with the opening of a linear fissure that erupts along its entire length, following which, activity localises to one or more isolated vents within a few hours or days. Localisation is important because it influences the spatiotemporal evolution of the hazard posed by the eruption. Previous work has proposed that localisation can arise through a thermoviscous fingering instability driven by the strongly temperature dependent viscosity of the rising magma. Here, we explore how thermoviscous localisation is influenced by the irregular geometry of natural volcanic fissures. We model the pressure-driven flow of a viscous fluid with temperature-dependent viscosity through a narrow fissure with either sinusoidal or randomised deviations from a uniform width. We identify steady states, determine their stability and quantify the degree of flow enhancement associated with localised flow. We find that, even for relatively modest variations of the fissure width (${\lt } 10$ %), the non-planar geometry supports strongly localised steady states, in which the wider parts of the fissure host faster, hotter flow, and the narrower parts of the fissure host slower, cooler flow. This geometrically driven localisation differs from the spontaneous thermoviscous fingering observed in planar geometries and can strongly impact the localisation process. We delineate the regions of parameter space under which geometrically driven localisation is significant, showing that it is a viable mechanism for the observed localisation under conditions typical of basaltic eruptions, and that it has the potential to dominate the effects of spontaneous thermoviscous fingering in these cases.
The present work experimentally investigates the interaction of a buoyant (rigid) spherical particle with a single translating (water) vortex ring, focusing on the effects of particle-to-vortex core size ratio ($D_p/D_{c,o}$) on both the particle dynamics and ring dynamics ($D_p$ = particle diameter, $D_{c,o}$ = vortex core diameter). These interactions are studied for $D_p/D_{c,o}$ = 0.6–1.7, over ring Reynolds numbers ($Re={\varGamma }/{\nu }$; $\varGamma$ = ring circulation) of 6000–67 300. As the buoyant particle comes close to the ring, it gets captured into the low-pressure vortex core, and the interaction begins. The particle within the core undergoes radial oscillation, spins and translates along the ring’s azimuthal axis. As $D_p/D_{c,o}$ increases, the particle undergoes higher-amplitude radial oscillation and a relatively shorter azimuthal translation. The differences in the particle size and its motion within the ring lead to large differences in the ring’s dynamics. A larger particle is seen to lead to a higher ring disruption, substantially reducing the ring’s convection speed and azimuthal enstrophy, which are seen to scale as $(D_p/D_{c,o})^{2.3}Re^{-0.37}$ and $(D_p/D_{c,o})^{1.3}Re^{-0.25}$, respectively. The ring disruption is significant above $D_p/D_{c,o}\approx$ 1.0, beyond which the ring fragments, with up to 60 % drop in convection speed and 90 % drop in enstrophy, at low $Re$, as compared with the base ring. These results for the rigid particle size effects on the vortex ring dynamics are more dramatic than for a deforming bubble. Our results could help to better understand and model buoyant particle (and bubble) interactions with coherent structures in turbulence.
A celadonitic clay deposit is located ∼40 km north-west of Yazlıca-Kütahya (Türkiye) and has promising reserves for ceramic production. To evaluate the potential use of this region, 10 representative clay samples were collected and characterized using X-ray diffraction (XRD), polarized-light microscopy (PM), X-ray fluorescence (XRF), differential scanning calorimetry (DSC), Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). According to the Chemical Index of Alteration and Chemical Index of Weathering, the celadonitic clay samples were formed by strong chemical alteration of the Kızıltepe volcanic rocks occurring in the study area. Based on XRD data, SEM-EDS data and chemical and thermal analysis results, the primary minerals present were celadonite-Al, montmorillonite and nontronite in the clay samples formed by the weathering of basaltic rocks. The clay samples were used in thermal and physical tests. Firing properties, including water absorption, dry shrinkage, firing shrinkage, total shrinkage and glaze adhesion, were determined. The white clay specimens are suitable for more decorative and less load-bearing applications, having high porosity and low strength. The green clay samples, however, are ideal for technical and industrial ceramics, having an extremely compact structure and high strength. The properties of these two clays are beneficial for application in different areas in terms of their mechanical and ceramic performance. Additionally, the representative green celadonitic clay samples were used in recipes for opaque, transparent and matte glazes, creating artistic glaze effects for pigments. Hence, the green clay samples could be used as a ceramic pigment.
Experimental investigation of the Rayleigh–Taylor instability (RTI) and its dependence on initial conditions has been challenging, primarily due to the difficulty of creating a well-defined gaseous interface. To address this, a novel soap film technique was developed to create a discontinuous two-dimensional SF$_6$air interface with precisely controlled initial conditions. High-order modes were superimposed on a long-wavelength perturbation to study the influence of initial conditions on RTI evolution. Experiments conducted at Atwood numbers ranging from 0.26 to 0.66 revealed that bubble growth shows a weak dependence on both initial conditions and Atwood numbers, whereas spike growth is more influenced by these factors. Spike growth accelerates as the wavenumber of the imposed high-order modes decreases and/or the Atwood number increases. To quantify these effects, a variation on the previously developed potential flow model was applied, capturing the suppression of high-order modes and Atwood number dependence on RTI growth. In turbulent flow, the self-similar factors of bubbles and spikes exhibit minimal sensitivity to initial conditions. However, in relation to the Atwood number, the self-similar factors of bubbles (or spikes) demonstrate negligible (or significant) dependence. Comparisons with literature revealed that two-dimensional flows yield lower self-similar factors than three-dimensional flows. Furthermore, the discontinuity of the initial interface in this study, achieved through the soap film technique, results in faster spike growth compared with previous studies involving a diffusive initial interface. These findings provide critical insights into the nonlinear dynamics of RTI and underscore the importance of well-characterised initial conditions in experimental studies.
Non-spherical bubble collapses near solid boundaries, generating water hammer pressures and shock waves, were recognized as key mechanisms for cavitation erosion. However, there is no agreement on local erosion patterns, and cavitation erosion damage lacks quantitative analysis. In our experiments, five distinct local erosion patterns were identified on aluminium sample surfaces, resulting from the collapse of laser-induced cavitation bubbles at moderate stand-off distances of $0.4\leqslant \gamma \leqslant 2.2$, namely bipolar, monopolar, annular, solar-halo and central. Among them, the bipolar and monopolar patterns exhibit the most severe cavitation erosion when the toroidal bubbles undergo asymmetrical collapse along the circumferential direction during the second cycle. Shadowgraphy visualization revealed that asymmetrical collapse caused shockwave focusing through head-on collision and oblique superposition of wavefronts. This led to the variations in toroidal bubble radii and the positions of maximum erosion depth not matching at certain stand-off distances. Both initial plasma asymmetry and bubble–wall stand-off distance were critical in determining circumferential asymmetrical collapse behaviours. At large initial aspect ratios, the elliptical jet tips form during the contraction process, resulting in the toroidal bubble collapsing from regions with smaller curvature radii, ultimately converging to the colliding point along the circumferential direction. Our three-dimensional simulations using OpenFOAM successfully reproduce the key features of circumferentially asymmetrical bubble collapse. This study provides new insights into the non-spherical near-wall bubble collapse dynamics and provides a foundation for developing predictive models for cavitation erosion.
Since 1994, the Andalusian Institute of Geophysics of the University of Granada group has been monitoring the seismic activity of Deception Island volcano (South Shetland Islands, Antarctica) during summer surveys. In this review, we analyse long-period and volcanic-tectonic events, including tremor episodes, recorded from 2011–2012 to 2021–2022 surveys with a local network and a seismic array. The seismo-volcanic activity on Deception Island occurs very locally, mainly as a result of tectonic destabilization induced by volcanic activity along with regional stresses, as a consequence of rifting and subduction processes spanning the South Shetland Islands, Bransfield Strait and Antarctica Peninsula. During this period, two changes to the volcanic alert level due to different volcanic parameters can be highlighted. The first of them was caused by the 2014–2015 seismic swarm as a consequence of a great regional perturbation located to the north-east of Deception Island, which spread around to the entire volcano. The second one, in the 2019–2020 survey, was established as a result of a significant increase in deformation parameters as a prelude of the August 2020 massive earthquake swarm that occurred in the Bransfield Strait, near the Orca submarine volcano. Furthermore, in the previous 2018–2019 survey, a peak of seismic activity was also recorded.
The new mineral pendevilleite-(Y) (IMA 2022-054), ideally Mg2Y3Al(UO2)2(CO3)7(OH)6(H2O)16, was found in the famous Kamoto-East open-cut, Lualaba province, Democratic Republic of Congo and named after Jean-Marie Pendeville (1936–2002), a specialist in collecting minerals of Congo. The new mineral occurs as extremely thin blades (up to ∼0.08–0.10 mm in length and only ∼1 μm thick), often forming lichen-like aggregates and crusts. It is associated with kamotoite-(Y), astrocyanite-(Ce) and shabaite-(Nd), uranophane and sklodowskite. Pendevilleite-(Y) crystals are whitish or greyish-white, locally pale-bluish white. The mineral is brittle; has an irregular fracture and a Mohs hardness of ∼2. Cleavage is perfect on {001}. Electron microprobe analyses provided (on the basis of 2 apfu U with CO32–, H2O derived from the structure and OH– to keep the electroneutrality) formula Mg1.78[(Y1.42Gd0.36Dy0.33Nd0.16Er0.14Sm0.13Eu0.12Tb0.05Ho0.04Yb0.04Ce0.03Tm0.03Pr0.01)Σ2.86 Ca0.11Pb0.01]Σ2.98Al0.88(UO2)2(CO3)7(OH)5.02(H2O)16. Pendevilleite-(Y) is triclinic, P$\overline 1 $, a = 11.9130(3) Å, b = 13.5252(11) Å, c = 16.1531(3) Å, α = 107.052(3)°, β = 92.7765(19)°, γ = 109.676(4)° and V = 2311.5(2) Å3 (Z = 2) at 97 K. The crystal structure (dynamical refinement against 3D ED data; R1 = 0.0948 for 1168 [I > 3σ(I)] reflections) possesses a large heteropolyhedral framework based on both a finite [(UO2)(CO3)3]4– cluster (UTC cluster) and a dimeric [(UO2)2(CO3)4(OH)2]6– unit formed due to olation of uranyl polyhedra. There are three M sites in the structure, occupied by Y3+ and Ln3+, with symmetry-related equivalents forming a polyoxometalate cluster of the general composition [(Y,Ln)6(OH)8(H2O)4(CO3)4]2+. Additionally, there is one Al site in the structure (symmetrically related equivalents forming a dimer of composition [Al2O2(OH)8]6–), and two Mg sites in octahedral coordination MgO2(H2O)4. In the sizeable channels of the framework (running parallel to c), there are at least eight independent partially occupied and disordered O sites of the H2O molecules.
We investigate enstrophy variations by collapse of point vortices in an inviscid flow and, in particular, focus on the enstrophy dissipation that is a significant property characterising two-dimensional (2-D) turbulent flows. To reveal the vortex dynamics causing the enstrophy dissipation, we consider the dynamics of point vortices, whose vorticity is concentrated on points and dynamics on the inviscid flow, governed by the point-vortex system. The point-vortex system has self-similar collapsing solutions, which are expected to be a key to understand the enstrophy dissipation, but the collapsing process cannot be described by solutions to the 2-D Euler equations. We thus consider the 2-D filtered-Euler equations, which are a regularised model of the 2-D Euler equations, and their point-vortex solutions. The preceding studies (Gotoda and Sakajo, J. Nonlinear Sci. 2016, vol. 26, pp. 1525–1570, Gotoda and Sakajo, SIAM J. Appl. Math. 2018, vol. 78, 2105–2128) have proven that there exist three point-vortex solutions to the filtered model such that they converge to self-similar collapsing orbits in the three point-vortex system and dissipate the enstrophy at the event of collapse in the zero limit of the filter parameter. In this study, we numerically show that the enstrophy dissipation by the collapse of point vortices could occur for the four and five vortex problems in a filtered model. Moreover, we show the detailed convergence process of the point vortices for gradually decreasing filter parameters, which provides a new insight for the three vortex problem. In addition, numerical computations suggest that the enstrophy dissipation is caused by collapse of separated point vortices with the negative interactive energy.
The Neptune Islands Group and Western Kangaroo Island Marine Parks were declared as part of South Australia’s representative system of Marine protected areas (MPAs) in 2009. Sanctuary zones, located within these MPAs, prohibited commercial fishing in the state’s Northern Zone Rock Lobster Fishery from 2014. In 2022, dedicated surveys were undertaken both inside and outside two of the sanctuary zones to estimate the relative abundance (catch per unit effort; CPUE) and size of southern rock lobster (Jasus edwardsii). Survey results were then compared to estimates of abundance obtained from long-term commercial fishery-dependent data within each area. The legal-size CPUE by weight of lobsters was 389% and 411% higher inside sanctuary zones of the Neptune Islands Group and Western Kangaroo Island, respectively, compared to outside, based on survey data. Survey catch rates inside the two sanctuary zones were also considerably higher than historical catch rates estimated from commercial fishing data. Lobsters inside both sanctuary zones were larger than those outside in terms of mean weight compared to historical estimates. However, surveys recorded similar mean size in lobsters both inside and outside the Neptune Islands Group sanctuary zone, indicating a possible spillover effect of MPA protection. The Northern Zone Rock Lobster Fishery is currently in a biomass rebuilding phase. The results highlight the productivity potential of temperate reef ecosystems within South Australia in terms of southern rock lobster abundances.
In this work, we numerically investigate heat transfer in low-Prandtl-number drop-laden wall-bounded turbulence. These flows are characteristic of nuclear and fusion technologies, where liquid metals – known for their high thermal conductivity – are laden with drops or bubbles of another liquid or pressurised gas. To this end, we consider forced convection turbulence between two differentially heated parallel plates. The carrier phase (i.e. liquid metal) is characterised by a low Prandtl number $Pr_c=0.013$, while for the dispersed phase, we explore a range of Prandtl numbers from $Pr_d=0.013$ (matched case) to $Pr_d=7$ (super-unitary Prandtl number in the dispersed phase). Simulations are conducted at constant friction Reynolds number $Re_\tau =300$, and for each dispersed phase Prandtl number, two volume fractions are examined: $\alpha =5.4\,\%$ and $\alpha =10.6\,\%$. The simulation framework relies on direct numerical simulation of the Navier–Stokes equations, coupled with a phase-field method and the energy equation. Results show that an increase of the dispersed phase Prandtl number reduces heat transfer, leading to a lower Nusselt number for both volume fractions. To explain this behaviour, we analyse how the drops modify the temperature field, and demonstrate that the heat transfer reduction stems from a decreased diffusive heat flux within the dispersed phase. Finally, we propose a phenomenological model to predict the Nusselt number as a function of both the dispersed phase volume fraction and Prandtl number.
A knowledge gap exists for flows and transport phenomena at the angstrom scale when the Poisson–Nernst–Planck equation based on the concept of the electrical double layer fails. We discovered that streaming conductance becomes pressure-dependent in angstrom channels using latent-track membranes. The streaming current emerges only when the applied pressure exceeds a threshold value, which is inconsistent with the existing knowledge as a constant. With increasing channel size, we found that the pressure-dependent streaming conductance phenomenon weakens and vanishes into a constant streaming conductance regime when the mean channel radius exceeds $\sim$2 nm. The effective surface potential derived from the streaming conductance that divides conduction anomalously increases as the channel narrows. We suspect that the pressure-dependent streaming current is due to the reinforced Coulomb interaction between counterions and deprotonated carboxyl groups at the surface, which is close to the ion channel but different from that of electrified two-dimensional materials. The streaming current emerged due to hydrodynamic friction when the counterions were released from the surface. We approximated the stochastic process of counterion dissociation by a one-dimensional Kramer escape theory framework and defined the Damk$\ddot {\mathrm{o}}$hler number to describe the transition from the nonlinear streaming conductance regime to the linear regime as functions of applied pressure and channel radius and well explained the enhanced effective surface potential in confinement.
Megacities around the world are increasingly confronted with conservation and restoration bottlenecks due to the competing demands of urban expansion and environmental conservation. This study investigates conservation prioritization strategies for balancing biodiversity protection, ecosystem service (ES) supply and landscape connectivity in rapidly urbanizing Beijing. By employing spatially explicit modelling and prioritization scenario techniques, we identify spatially heterogeneous priority zones. We demonstrate that high-value areas for ES supply, particularly carbon storage and water regulation, concentrate primarily in Beijing’s north-western mountainous regions, covering c. 62% of the city’s area. Conversely, critical habitats for threatened species and key connectivity corridors are dispersed, with 22.89% of critical habitats located within urban built-up areas. Gap analysis reveals limited alignment between Beijing’s current ecological security patterns, with only 9.6% coverage of the identified top 10% conservation priority zones, especially within the metropolitan core. The study underscores significant trade-offs among different ecological objectives and multi-criteria conservation strategies. We propose an optimized conservation framework based on zonation analysis to guide targeted landscape planning decisions. This approach provides actionable insights for urban policymakers to achieve comprehensive sustainability, emphasizing the importance of protecting critical ecological areas in both urban and rural landscapes amid ongoing urban expansion.
The unchecked rise in global plastic production has resulted in widespread pollution and exposure to hazardous chemicals. Over 16,000 chemicals are used across the plastics life cycle, with thousands meeting criteria for persistence, bioaccumulation, mobility and toxicity. Many remain unregulated under existing multilateral environmental agreements. In response, the United Nations Environment Assembly has mandated the development of an international, legally binding instrument to end plastic pollution. Current treaty negotiations have begun addressing a short list of chemicals, yet significant gaps remain. These include insufficient regulatory mechanisms, lack of chemical transparency and reliance on ineffective recycling strategies that reintroduce toxic substances into consumer products. The presence of harmful chemicals in plastics contributes to major public health burdens and is an environmental threat, with high annual costs that reduce the potential for economic development through safer recycling. Vulnerable populations, including children, reproductive-aged individuals, and frontline communities, face heightened risks. To address this, we recommend the following three critical actions for the treaty: (1) globally regulating chemicals of concern based on hazard; (2) mandating transparency of plastic chemical composition and (3) designing plastics using safe-by-design principles and essential-use criteria. Group-based regulation, which would consider categories of related chemicals, should replace individual chemical approaches to prevent regrettable substitutions. Binding, global obligations, rather than fragmented or voluntary measures, are vital for sustainability, chemical safety, circularity and accountability across the plastics life cycle. A strong treaty is a critical opportunity to achieve a safer, more sustainable future for human and environmental health.
The connection between the drag and vorticity dynamics for viscous flow over a bluff body is explored using the Josephson–Anderson (J–A) relation for classical fluids. The instantaneous rate of work on the fluid, associated with the drag force, is related to the vorticity flux across the streamlines of a background potential flow. The vorticity transport itself is examined by aid of the Huggins vorticity-flux tensor. The analysis is performed for three flows: flow over a sphere at Reynolds numbers $Re=200,3700$, and flow over a prolate spheroid at $Re=3000$ and $20^{\circ }$ incidence. In these flows, the vorticity transport shifts the flow away from and towards the ideal potential flow, with a net balance towards the former effect thus making an appreciable contribution to the drag. The J–A relation is first demonstrated for the flow over a sphere at $Re=200$. The drag power injection is related to the viscous flux of azimuthal vorticity from the wall into the fluid, and the advection of vorticity by the detached shear layer. In the wake, the azimuthal vorticity is advected towards the wake centreline and is annihilated by viscous effects, which contributes a reduction in drag. The analysis of the flow over a sphere at $Re=3700$ is reported for the impulsively started and stationary stages, with emphasis on the effects of unsteady two-dimensional separation and turbulent transport in the transitional wake. The turbulent flux in the wake enhances the transport of mean azimuthal vorticity towards the wake centreline, and is the main driver of the recovery of enthalpy between the rear point of the sphere and far downstream. The rate of work on the fluid by the drag force for a prolate spheroid is mostly due to the transport of vorticity along the separated boundary layers. Primary and secondary separation contribute oppositely to the power injection by the drag force, while the large-scale vortices only re-distribute vorticity without a net contribution. A mechanism for secondary separation is proposed based on the theory of vortex-induced separation.