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Drag reduction induced by a polydisperse solution of polyethylene oxide is investigated by direct numerical simulations of the Navier–Stokes equations coupled with the Lagrangian evolution of the polymers, modelled as dumbbells. Simulation parameters are chosen to match the experimental conditions of Berman (1977), who measured the polymer molecular weight distribution. Drag reduction is induced only by the few high molecular weight polymers fully stretched by the turbulent flow, whilst the hundreds of parts per million of low molecular weight chains are ineffective.
Morphodynamic descriptions of fluid deformable surfaces are relevant for a range of biological and soft matter phenomena, spanning materials that can be passive or active, as well as ordered or topological. However, a principled, geometric formulation of the correct hydrodynamic equations has remained opaque, with objective rates proving a central, contentious issue. We argue that this is due to a conflation of several important notions that must be disambiguated when describing fluid deformable surfaces. These are the Eulerian and Lagrangian perspectives on fluid motion, and three different types of gauge freedom: in the ambient space; in the parameterisation of the surface; and in the choice of frame field on the surface. We clarify these ideas, and show that objective rates in fluid deformable surfaces are time derivatives that are invariant under the first of these gauge freedoms, and which also preserve the structure of the ambient metric. The latter condition reduces a potentially infinite number of possible objective rates to only two: the material derivative and the Jaumann rate. The material derivative is invariant under the Galilean group, and therefore applies to velocities, whose rate captures the conservation of momentum. The Jaumann derivative is invariant under all time-dependent isometries, and therefore applies to local order parameters, or symmetry-broken variables, such as the nematic $Q$-tensor. We provide examples of material and Jaumann rates in two different frame fields that are pertinent to the current applications of the fluid mechanics of deformable surfaces.
Sepiolite is considered a suitable substrate for Maya blue pigment. However, the interaction between sepiolite and indigo dye has not been fully understood. Previous studies have demonstrated that pre-treatment of sepiolite by heating or acid was useful in identifying the sepiolite–indigo interaction. The purpose of the present study was to prepare a series of hybrid sepiolite–indigo pigments after modifying the sepiolite using various alkali treatments (NaOH), then to evaluate their properties with respect to color, chemical resistance, and photostability. Samples were characterized using reflectance spectroscopy, X-ray diffraction, Fourier-transform infrared spectroscopy, Raman spectroscopy, transmission electron microscopy, and N2 adsorption-desorption. Under alkaline conditions, Si4+ and Mg2+ ions in sepiolite partially dissolved, disrupting the coordinated water associated with them. Mg2+ ions precipitated and blocked the structural channels of the sepiolite. The impact of the alkali treatment on the microporous structure and coordinated water of sepiolite significantly influenced the color properties and stability of the hybrid pigments. Proper alkaline treatment enhanced the greenish hue and chemical stability of the pigment, while severe treatments apparently compromised the structural integrity of the sepiolite, thus diminishing the quality of the hybrid pigment. Results from this study provide new insights into the color-causing and stabilizing mechanisms of sepiolite-based Maya blue pigment and also provide guidance for developing hybrid pigments based on clay minerals and organic dyes.
This chapter provides a political economy interpretation of the Inflation Reduction Act: Its spending aims to recode the circuits of capital accumulation along the decarbonization imperative and institute a regime of green accumulation. It presents the clean energy tax credits, the home tax credits, the manufacturing tax credits, and the Greenhouse Gas Reduction Fund as elements of this attempted reconfiguration.
In this work, we investigate the mixing of active scalars in two dimensions by the stirring action of stochastically generated weak shock waves. We use Fourier pseudospectral direct numerical simulations of the interaction of shock waves with two non-reacting species to analyse the mixing dynamics for different Atwood numbers (At). Unlike passive scalars, the presence of density gradients in active scalars alters the molecular diffusion term and makes the species diffusion nonlinear, introducing a concentration gradient-driven term and a density gradient-driven nonlinear dissipation term in the concentration evolution equation. We show that the direction of concentration gradient causes the interface across which molecular diffusion occurs to expand outwards or inwards, even without any stirring action. Shock waves enhance the mixing process by increasing the perimeter of the interface and by sustaining concentration gradients. Negative Atwood number mixtures sustain concentration gradients for a longer time than positive Atwood number mixtures due to the so-called nonlinear dissipation terms. We estimate the time until that when the action of stirring is dominant over molecular mixing. We also highlight the role of baroclinicity in increasing the interface perimeter in the stirring dominant regime. We compare the stirring effect of shock waves on mixing of passive scalars with active scalars and show that the vorticity generated by baroclinicity is responsible for the folding and stretching of the interface in the case of active scalars. We conclude by showing that lighter mixtures with denser inhomogeneities ($At\lt 0$) take a longer time to homogenise than the denser mixtures with lighter inhomogeneities ($At\gt 0$).
Throughout the Pleistocene, valley glaciers repeatedly advanced into the forelands of the European Alps. However, the corresponding geological record is highly fragmentary and the regional glaciation history, especially prior to the last glacial maximum, is still poorly documented. We explored the archives of the Lower Aare Valley in the confluence area of the Aare river with Reuss and Limmat, focusing on the overdeepened Gebenstorf-Stilli Trough. In four scientific boreholes, ∼350 m of drill cores were recovered, and complemented with investigations of outcrops and reflection seismics in the nearby glaciofluvial Habsburg-Rinikerfeld Palaeochannel. The integrative interpretation of these data provides new insights into the local landscape evolution: We identified two generations of glacial basin infill in the Gebenstorf-Stilli Trough that are overlain by glaciofluvial gravels, and two distinct glaciofluvial gravel bodies in the neighboring paleochannel. In this specific local setting, gravel petrographic compositions and their statistical analysis prove to be powerful tools to identify inputs from the confluent catchments, to aid in lithostratigraphic classification, and to interpret the depositional and landscape histories. We suggest that it is mainly the penultimate glaciation, characterized by three separate ice advances, that shaped the present-day study area, and whose deposits are preserved in the Middle Pleistocene archives.
Terrestrial proxies of wind direction spanning the last deglaciation suggest easterly winds were present near the Laurentide Ice Sheet margin in the North American midcontinent. However, the existence and spatial extent of such easterly winds have not been investigated with transient paleoclimate model simulations, which could provide improved dynamical context for interpreting the causes of these winds. Here we assess near-surface winds near the retreating southern Laurentide Ice Sheet margin using iTRACE, a transient simulation of deglacial climate from 20–11 ka. Near the south-central margin, simulated near-surface winds are northeasterly to easterly through the deglaciation, due to katabatic flow off the ice sheet and anticyclonic circulation. As the ice sheet retreats and the Laurentide High moves northeastward and weakens, near-surface northeasterly winds weaken. Meltwater fluxes also influence temperature and sea level pressure over the North Atlantic, leading to easterly wind anomalies over eastern to midwestern North America. The agreement between proxy and model wind directions is promising, although simulated easterly to northeasterly winds extend too far south in iTRACE relative to the proxy data. Agreement is also strongest in winter, spring, and fall, suggesting these may have been seasons with greater aeolian activity.
A paleotemperature reconstruction inferred from subfossil chironomid (non-biting midge) assemblages in a 13-meter, 14,500-yr lake sediment record from a montane forest in the Pacific Northwest is compared to existing quantitative temperature reconstructions from the Pacific Northwest. With updated temperatures, a regional training set was used to develop a midge-based mean July air temperature (MJAT) inference model (r2jack = 0.71, root mean square error of prediction = 1.09°C). The average inferred MJAT varied between 9.4°C and 13.2°C. During the late-glacial period, MJAT ranged between 9.4°C and 10.8°C, and the lowest MJAT (9.4°C) is inferred at ca. 12.7 ka during the Younger Dryas. The transition into the Early Holocene was marked by an increase from 11°C at 11 ka to 12°C at 9.2 ka. Following deposition of the Mazama tephra, chironomid concentration decreased rapidly, and MJAT rose to 12.3°C at ca. 7.6 ka. This change in chironomid assemblage may be due to the direct effects of the tephra on the surface energy balance. The reconstructed temperature did not track decreasing Holocene summer insolation but instead revealed Late Holocene warming, which is similar to a chironomid reconstruction in the eastern Sierra Nevada and a sea-surface temperature reconstruction from northern California.
Elastoinertial turbulence (EIT) is a chaotic state that emerges in the flows of dilute polymer solutions. Direct numerical simulation (DNS) of EIT is highly computationally expensive due to the need to resolve the multiscale nature of the system. While DNS of two-dimensional (2-D) EIT typically requires $O(10^6)$ degrees of freedom, we demonstrate here that a data-driven modelling framework allows for the construction of an accurate model with 50 degrees of freedom. We achieve a low-dimensional representation of the full state by first applying a viscoelastic variant of proper orthogonal decomposition to DNS results, and then using an autoencoder. The dynamics of this low-dimensional representation is learned using the neural ordinary differential equation (NODE) method, which approximates the vector field for the reduced dynamics as a neural network. The resulting low-dimensional data-driven model effectively captures short-time dynamics over the span of one correlation time, as well as long-time dynamics, particularly the self-similar, nested travelling wave structure of 2-D EIT in the parameter range considered.
When a droplet impacts onto a superheated liquid pool, vapour generation and drainage within the gas cushion play a crucial role in postponing or even preventing contact between the droplet and the pool surface. Through direct numerical simulations, we closely examine the transient dynamics of vapour flow confined within the thin film, with a particular focus on the minimum thickness of this film under a range of impact conditions. Our numerical findings manifest the significant influence of evaporation on the vertical motion of the liquid–vapour interface, revealing how the minimum film thickness evolves in response to variations in impact velocity and degree of superheat. In our numerical simulations, we have identified two distinct evolution laws for the minimum film thickness, corresponding to moderate and high superheat regimes, respectively. These regimes are differentiated by the dominance of evaporation effects within the vapour film during the early falling stage. Subsequently, we establish scaling relations to characterize these regimes by carefully balancing inertial, pressure and evaporation effects within the thin vapour film. Furthermore, we observe that the vapour pressure eventually reaches equilibrium with the rapid increase in capillary pressure at the spreading front, thereby controlling the minimum thickness of the vapour layer in both moderate and high superheat regimes. We derive self-similar solutions based on this equilibrium, and the predicted minimum film thickness aligns remarkably well with our numerical results. This provides compelling evidence that evaporation alone is insufficient to prevent droplet–pool coalescence.
A central concept of environmental justice is some populations’ disproportionate vulnerability to environmental pollution. This chapter contextualizes that vulnerability by articulating two racialized assignments of political power in the US Constitution and tracing those assignments to two contemporary racialized property relationships: redlining and allotment.
The Inflation Reduction Act introduces new social actors and new decarbonization opportunities to the decarbonization project. This chapter introduces ways of analyzing these new opportunities, leading to a presentation of what social theory is and how it can be useful for analyzing decarbonization policy.
This chapter presents Fligstein and McAdam’s theory of strategic action fields as a synthesis of the sociology of social change. The theory presents the social world as composed of embedded strategic action fields, each populated by three general types of social actors: incumbents, challengers, and an internal governance units. This chapter relies upon the electrical power company to illustrate the theory, preparing the way for a more granular discussion of the electrical power company.
Dust storms are a unique form of high-Reynolds-number particle-laden turbulence associated with intense electrical activity. Using a wavelet-based analysis method on field measurement data, Zhang et al. (2023 J. Fluid Mech.963, A15) found that wind velocity intermittency intensifies during dust storms, but it is weaker than both dust concentration and electric field. However, the linear and nonlinear multifield coupling characteristics, which significantly influence particle transport and turbulence modulation, remain poorly understood. To address this issue, we obtained high-fidelity datasets of wind velocity, dust concentration, and electric field at the Qingtu Lake Observation Array. By extending the wavelet-based data analysis method, we investigated localised linear and quadratic nonlinear coupling characteristics in strong turbulence–particle–electrostatics coupling regimes. Our findings reveal that linear coupling behaviour is largely dominated by the multifield intermittent components. At small scales, due to very high intermittency, no strong phase synchronisation can be formed, and the interphase linear coupling is weak and notably intermittent. At larger scales, however, perfect phase synchronisation emerges, and dust concentration and electric field exhibit strong, non-intermittent linear coupling, suggesting that large-scale coherent structures play a dominant role in driving the coupling. Importantly, the multifield spectra show well-developed $-1$ and $-5/3$ power-law regions, but the spectral breakpoints for dust concentration and electric field are two decades lower than that for streamwise wind velocity. This difference is due to the broader range and stronger intensity of quadratic nonlinear coupling in dust concentration and electric field, which leads to the broadening of Kolmogorov’s $-5/3$ power-law spectrum.
The dynamics of small-scale structures in free-surface turbulence is crucial to large-scale phenomena in natural and industrial environments. Here, we conduct experiments on the quasi-flat free surface of a zero-mean-flow turbulent water tank over the Reynolds number range $Re_{\lambda } = 207$–312. By seeding microscopic floating particles at high concentrations, the fine scales of the flow and the velocity-gradient tensor are resolved. A kinematic relation is derived expressing the contribution of surface divergence and vorticity to the dissipation rate. The probability density functions of divergence, vorticity and strain rate collapse once normalised by the Kolmogorov scales. Their magnitude displays strong intermittency and follows chi-square distributions with power-law tails at small values. The topology of high-intensity events and two-point statistics indicate that the surface divergence is characterised by dissipative spatial and temporal scales, while the high-vorticity and high-strain-rate regions are larger, long-lived, concurrent and elongated. The second-order velocity structure functions obey the classic Kolmogorov scaling in the inertial range when the dissipation rate on the surface is considered, with a different numerical constant than in three-dimensional turbulence. The cross-correlation among divergence, vorticity and strain rate indicates that the surface-attached vortices are strengthened during downwellings and diffuse when those dissipate. Sources (sinks) in the surface velocity fields are associated with strong (weak) surface-parallel stretching and compression along perpendicular directions. The floating particles cluster over spatial and temporal scales larger than those of the sinks. These results demonstrate that, compared with three-dimensional turbulence, in free-surface turbulence the energetic scales leave a stronger imprint on the small-scale quantities.
This chapter presents a thought experiment. We image a perfect carbon price coursing through the economy and coming into contact with other market failures conventionally identified by environmental economists. At these points of contact, we discover other social striations that need confrontation for successful decarbonization.