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It’s hard to beat the energy density and convenience of liquid hydrocarbons. The product of energy used and journey time is another way to compare transportation systems. It is more practical to power electric cars from batteries than photovoltaics. Solar can be used to supply some of the energy needed to recharge the batteries. The primary energy used to make food, the fuel for the human cyclist, can be many times the calorific energy derived from the food.
Transportation is a major source of carbon dioxide emissions. Hermans makes some excellent points in his article “The challenge of energy-efficient transportation.” However primary energy to produce fuel should also be considered. The embodied energy of liquid hydrocarbon fuels is much less than their energy content. For a cyclist the fuel is food, and, depending on diet, the primary energy can be many times the food’s calorific energy. The article is over optimistic on the prospect of cars directly powered by solar photovoltaics. It’s more realistic to use batteries in electric cars and generate the electricity from a number of sources. For anything other than trains that run on fixed tracks it’s hard to beat the energy density and convenience of liquid hydrocarbons.
Historical pipe organs offer rich insights into the relationships between materials and music in the past, and they represent a laboratory for contemporary materials science. Recent cross-disciplinary research has explored problems of conservation and corrosion in old organ pipes. The ability of some notable European Baroque organs to produce sound is threatened by atmospheric corrosion of their lead-tin alloy pipes. Organic acids emitted from the wood of organ cases are corrosive agents for lead-rich pipes. Laboratory exposure experiments were used to study the roles of humidity and alloy composition in the susceptibility to organic acid attack. The rates of growth, as well as the compositions and morphologies of the corrosion products were studied using gravimetry, x-ray diffraction, and scanning electron microscopy of surfaces and cross sections. This interdisciplinary project provides one model for the interplay of scientific and humanities research in addressing materials problems in cultural heritage.
As materials science is becoming components development and systems technology, hydrogen economy is approaching your porch. Welcome!
Hydrogen mobility can now be purchased from the shelf. Fuel cell electric vehicles from various well-known car manufacturers are now available. The number of hydrogen filling stations in Europe is increasing at a rate that long-distance tours become less and less adventurous. The efforts of fuel cell researchers have paid off. Suppliers of components and systems for hydrogen infrastructure are anticipating business. Meanwhile, basic science in electrochemistry and materials research is continuing, with surprises such as the discovery of a proton polaron which are adding to the progress in fundamental understanding of energy materials in operation. Has the long awaited hydrogen economy finally arrived?
The development of Chicago and northeastern Illinois has been intimately tied to water, particularly Lake Michigan and the Chicago Area Waterways. The wastewater treatment plants of the past will become the power centers of the future by harnessing resources—including nutrients, energy, solids, and water itself—to bolster the economy and ensure regional sustainability.
The story of Chicago’s development is inextricably linked to its relationship with the natural environment, beginning 16,000 years ago when the land was covered and compressed by an enormous glacier. Ever since, urban planners and policymakers have grappled with how to manage a city built on flat, swampy land, and what to do with the animal and human waste that accumulates in urban environments. During the 19th and 20th centuries, the solution was to move waste as far away from the area as possible. The Chicago River, which originally flowed into Lake Michigan, was converted into an open sewer and reversed, sending the flow—and all the wastes dumped into it—downstream. Over the 20th century, sewage treatment plants were constructed to minimize the potential for harm to humans and the environment. Now, however, our thinking is changing. Rather than discarding waste products, wastewater treatment plants are beginning to recover the resources that flow through them—including nutrients, energy, solids, and water—and transform them into assets that generate revenue and protect the environment. This potential for resource recovery means that the sewage treatment plants of the past will become the power centers of the future.
The sustainability movement has more influence over company and government climate change actions than any treaty, law or regulation could possibly have, and results in quicker, measurable actions.
The sustainability movement is alive and well, and will continue to grow despite the outcry over some countries backpedaling from the Paris Accord. When one stops to consider just how much action companies from around the world have taken toward sustainability one cannot help but be amazed that so much was done without treaties, laws and regulations to force compliance. The primary driver of action is peer pressure—that which is derived from the actions of industry, and not the actions of government. This movement, found under a company’s corporate social responsibility (CSR) banner, will continue to grow by virtue of the continuous adoption of sustainability reporting, and in particular, supply chain reporting, benchmarking and risk management practices of industry, and the adoption of energy efficient (EE) projects. These actions have already resulted in significant positive changes to private company and government behavior, company value, lower emissions, greater operational efficiency, and competitive advantage. One could argue that peer pressure is much more effective than any treaty, laws, or regulations could possibly be. But, it should be noted that the term “climate change” remains a contentious issue and companies would be wise to refer to all related actions as sustainability.
Topological constraint theory is a convenient theoretical framework to predict structure–property relationships in glasses and identify optimal compositions featuring targeted macroscopic properties. Although introduced for chalcogenide glasses, molecular rigidity concepts have since been applied with great success to new families of materials, such as silicate glasses, phase-change materials, and proteins. Here, we review recent developments in the extension of rigidity theory to concrete, which is by far the most heavily manufactured material in the world. By capturing the important atomic topology while filtering out less relevant structural details of calcium–silicate–hydrate, the binding phase of concrete, topological constraint theory was used to nanoengineer concrete from the atomic scale by predicting the compositional dependence of hardness, toughness, and creep. As such, rigidity concepts represent a promising tool to accelerate the discovery of new materials with tailored properties.
Synroc has evolved over the last 40 years from the titanate full-ceramics developed in the late 1970s to a technology platform that can be applied to produce glass, glass–ceramic, and ceramic waste forms and where there are distinct advantages in terms of waste loading and suppressing volatile losses.
A first of a kind Synroc plant for immobilizing intermediate level waste arising from Mo-99 production is currently in detailed engineering at ANSTO.
Since the year 2000, Synroc has evolved from the titanate full-ceramics developed in the late 1970s to a technology platform that can be applied to produce glass, glass–ceramic, and ceramic waste forms and where there are distinct advantages in terms of waste loading and suppressing volatile losses. Furthermore recent efforts have focused strongly on waste form development for plutonium-bearing wastes in the UK, for different options for the immobilization of Idaho calcines and most recently developing an engineered waste form for the intermediate level wastes arising from 99Mo production, for the Australian Nuclear Science and Technology Organisation (ANSTO). A variety of other studies are currently in progress, including engineered waste forms for spent fuel and investigating the proliferation risks for titanate-based waste forms containing highly enriched uranium or plutonium. This paper also attempts to give some perspective on Synroc waste forms and process technology development in the nuclear waste management industry.
This manuscript provides a bird’s eye view on energy in buildings. We discuss how energy policy leads to building standards that affect innovation in the building sector. We review current and future materials and solutions for the building envelope (insulation and glazing), renewable energy generation and energy storage, and demonstrate how the integration of buildings into district networks mitigates problems arising from a building’s, and its users’, dynamic behavior.
Buildings account for ∼40% of global energy demands, and the increased adoption of innovative solutions for buildings represents an enormous potential to reduce energy demands and greenhouse gas emissions. Here, we critically review the current and future materials and solutions for the construction sector. We describe how policy affects innovative businesses and the adoption of new products and solutions. We investigate how the building envelope and user behavior determine building energy demands. Compared to conventional solutions, superinsulation materials (vacuum insulation panels, silica aerogel) can achieve the same thermal performance with drastically thinner insulation. With low-emissivity coatings and appropriate filler gasses, double and triple glazing reduces thermal losses by an order of magnitude. Vacuum and aerogel glazing reduce these even further. Switchable glazing solutions maximize solar gains during wintertime and minimize illumination demands whilst avoiding overheating in summer. Upon integration of renewable energy systems, buildings become both producers and consumers of energy. Combined with the dynamic user behavior, temporal variations in energy production require thermal and electrical storage and the integration of buildings into smart grids and energy district networks. The combination of these measures can reduce the energy consumption of the building’s stock by a factor of three.
We explore some aspects of the optimization of amorphous semiconductors as well as low- and high-dielectric-constant (low-/high-k) materials viewed purely from the perspective of percolation and topological constraint theories. We specifically illustrate how percolation, constraint theory, and mean network coordination, 〈r〉, play underlying roles in determining the electrical and mechanical properties of amorphous semiconducting and dielectric materials as well as interfaces that are important for modern micro-/nanoelectronic devices.