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Recent studies have shown that superimposing rhythmic perturbations to oscillating tailbeats could simultaneously enhance both the thrust and efficiency (Lehn et al., Phys. Rev. Fluids, vol. 2, 2017, p. 023101; Chao et al., PNAS Nexus, vol. 3, 2024, p. 073). However, these investigations were conducted with a tethered flapping foil, overlooking the self-propulsion intrinsic to real swimming fish. Here, we investigate how the high-frequency, low-amplitude superimposed rhythmic perturbations impact the self-propelled pitching and heaving swimming of a rigid foil. The swimming-speed-based Reynolds number ranges from 1400 to 2700 in our study, depending on superimposed perturbations and swimming modes. Numerical results reveal that perturbations significantly increase swimming speeds in both pitching and heaving motions, while enhancing efficiency exclusively in the heaving motion. Further derived scaling laws elucidate the relationships of perturbations with speeds, power costs and efficiency, respectively. These findings not only hypothesise the potential advantages of perturbations in biological systems, but also inspire designs and controls in biomimetic propulsion and manoeuvring within aquatic environments.
The methods for synthesising by precursor routes films of insoluble poly(phenylene vinylene) (PPV), the prototypical poly(arylene vinylene) (PAV) are described and compared and its properties discussed. Methods for preparing soluble substituted PPVs are described and their structure–property relationships discussed. By suitable choice of structure, PAVs with emission colours ranging from the blue to the near infra-red have been made and tested in light-emitting diodes. The choice of substituents has also been used to enhance the charge accepting and transporting properties of PAVs, thus improving their efficiency in devices. The efficiency of polymer-based LEDs is also affected by the presence of defects in the polymer structures and methods have been developed to minimise these, enabling commercially-viable LEDs to be made using PAVs. The potential use of PAVs in OTFTs and OPVs is also discussed.
The methods for synthesising polyacetylene are discussed and compared. As unsubstituted polymer is insoluble, precursor methods must be used to make films suitable for use in devices. While the fact that doped polyacetylene is conducting is of scientific interest, its instability and lack of luminescece has made it useless for practical applications. Substituted polyacetylenes can be made which are both soluble and luminescent, making them potentially useful in LEDs.The synthesis and properties of such polymers are discussed as well as their structure–property relationships and potential for use in devices.
We conducted a systematic numerical investigation of spherical, prolate and oblate particles in an inertial shear flow between two parallel walls, using smoothed particle hydrodynamics (SPH). It was previously shown that above a critical Reynolds number, spherical particles experience a supercritical pitchfork bifurcation of the equilibrium position in shear flow between two parallel walls, namely that the central equilibrium position becomes unstable, leading to the emergence of two new off-centre stable positions (Fox et al., J. Fluid Mech., vol. 915, 2021). This phenomenon was unexpected given the symmetry of the system. In addition to confirming this finding, we found, surprisingly, that ellipsoidal particles can also return to the centre position from the off-centre positions when the particle Reynolds number is further increased, while spherical particles become unstable under this increased Reynolds number. By utilizing both SPH and the finite element method for flow visualization, we explained the underlining mechanism of this reverse of bifurcation by altered streamwise vorticity and symmetry breaking of pressure. Furthermore, we expanded our investigation to include asymmetric particles, a novel aspect that had not been previously modelled, and we observed similar trends in particle dynamics for both symmetric and asymmetric ellipsoidal particles. While further validation through laboratory experiments is necessary, our research paves the road for development of new focusing and separation methods for shaped particles.
Taking the Myx Sail displayed at the Danish Design Museum as a case study, this article investigates the room acoustics of an architectural installation made of Mycelium Textiles. Mycelium Textiles represent a novel typology of mycelium-based composites (MBC). The Myx Sail absorbers are grown on a composition of different layers of plant fibres combining woven jute textile with hemp mat and loose wood wool substrate enhancing the mechanical and acoustic properties of the composite. Two complementary acoustic tests were conducted to measure the absorbing properties of the mycelium material and its effects on the acoustics of the exhibition hall. The results show that the sail acts effectively as an acoustic absorber especially in higher range of frequencies, reducing the reverberation time and improving speech intelligibility. The effect of the sail on the overall room acoustics is especially effective, if the sound source is placed directly underneath the sail. The results of a complementary survey amongst visitors on their subjective perception of comfort and well-being however indicate that the degree to which a grown surface (and by extension, a grown building) is perceived positively or negatively depends on the relationship the individual has with Nature.
Polythiophenes are the most widely studied class of heteroarene-based polymers. The properties of poly(3-alkylthiophene)s have been shown to depend upon the degree of regioregularity in the polymer backbone. Routes have been developed to make almost completely regioregular polymers with nearly 100% head-to-tail couplings. These regioregular polymers show much better chain packing in the solid state and significantly better charge carrier mobilities, making them suitable for use in OTFTs. They show less promise as LED materials due to low emission efficiencies, but are promising as solar cell materials. A combination of regioregular poly(3-hexylthipophene) and a fullerene acceptor is the most widely studied donor–acceptor pair in OPVs, with device efficiencies of over 5% combined with a relatively inexpensive synthesis, making it potentially commercially viable.
When a cylinder is free to move along a transverse rectilinear path within a current, the vibrations developing with and without structural restoring force (SRF) noticeably deviate: if the elastic support is removed, their onset is delayed from a Reynolds number ($Re$, based on the body diameter and inflow velocity) value of approximately 20 to 30, and their peak amplitudes and frequency bandwidths are substantially reduced. The present study examines the influence of a curved path on this deviation by considering that the cylinder, mounted on an elastic support or not, is free to translate along a circular path whose radius is varied. The investigation is carried out numerically at $Re=25$ and $100$, i.e. subcritical and postcritical values relative to the threshold of $47$ that marks the onset of flow unsteadiness for a fixed body. The principal result of this work is that the behaviours of the flow–structure systems with and without SRF tend to converge under the effect of path curvature. Beyond a certain curvature magnitude, both systems explore the same vibration ranges and the presence or absence of SRF becomes indiscernible. This convergence is accompanied by an enhancement of the responses appearing without SRF. It is analysed in light of the evolution of the effective added mass which determines the subset of responses reached with SRF that remain accessible without SRF. The apparent continuity of the physical mechanisms between the subcritical- and postcritical-$Re$ values suggests that the convergence phenomenon uncovered here could persist at higher $Re$.
Six Holland-class “pantserdekschepen” (protected cruisers) were built in two groups of three ships. They succeeded the ship-rigged unprotected cruisers of the Atjeh-class also classified as “steam frigates”. Being faster but without sails they had a large endurance capable to negotiate the considerable distances in the East Indies Archipelago.
ARMOURED CRUISERS
From the late 1850s navies began to substitute their wooden ships-of-the-line by ironclad warships. However, the frigates and sloops which carried out scouting, raiding, and merchant ship protection remained unarmoured. For several decades it proved difficult to design a ship with any substantial amount of protective armour and capable of the speed and range required of a ‘cruising warship’. The first attempt to design armoured cruisers like the British HMS Shannon, proved to be unsatisfactory. Generally these ships were too slow for their cruiser role. HMS Shannon was the last Royal Navy ironclad to be built with a propeller that could be hoisted to reduce drag when she was under sail and the first ship to have an armoured deck. During the 1870s the increasing firepower of armour-piercing guns made armouring the hull of a ship more difficult as heavier armour plates were required. Even if the weight of armour dominated the design of the ship it was likely that the next generation of guns would be able to pierce it. The alternative was to leave the sides of the ship vulnerable but to armour a deck just below the waterline. Since this deck would only be struck very obliquely by shells it could be less thick than belt armour.
DUTCH EAST INDIES TILL 1890
It can be maintained with some exaggeration that until the end of the First World War the Dutch East Indies existed by grace of the Royal Netherlands Navy. The East Indies meant trade competition but they were no longer a geopolitical threat to the British interests in Asia. Great Britain had an interest in maintaining the existing colonial political relations. This to avoid that another European power would settle itself in the East Indies Archipelago. The British however were during a long time the only ones who could pose a threat to the Dutch Indies.
While LEDs are the most common emissive device, other emissive devices using conjugated polymers are possible. The use of emissive polymers in devices such as light-emitting electrochemical cells, chemiluminescence cells and light-emitting transistors is described and the different design features needed to optimise their performance discussed. The use of polymers in microcavbities and lasers is discussed. While optically-pumped lasing has been demonstrated, electrically-pumped lasing form organic materials remains to be demonstrated but is not theoretically impossible. The prospects for integrated polymers devices such as optocouplers are also discussed.
White electroluminescence is required for lighting applications. This is obtainable by either blending two materials with complementary colours (usually blue and red or orange) or by obtaining simultaneous emission from independent chromophores with complementary colours. The designs of polymers that have been used to achieve this are described and compared and examples of the best performing materials given.
Conjugated polymers are semiconductors, which if doped can become conducting. Their electronic properties make them suitable for use in organic electronic devices such as transistors (OTFTs), light-emitting diodes (OLEDs) and solar cells (OPVs). The operating principles of these devices are discussed. Each of these devices have different requirements for their active materials. Among the important parameters which must be considered to optimise device performance are the energy difference between the Highest Occupied Molecular Orbital (HOMO) and the Lowest Unoccupied Molecular Orbital (LUMO) (known as the bandgap) which controls which colours of light can be absorbed or emitted, the energy levels of the HOMO and LUMO, which control the rate at which charges can be injected and extracted and the mobility of the charge carriers within the material. These parameters must be considered in designing or selecting suitable materials for use in these devices.
Methods for preparing soluble poly(arylene ethynylene)s (PAEs) and PAE-PAV copolymers are described and compared. The structure–property relationships in such polymers are described and their potential applications in devices such as LEDs and sensors discussed.
We explore the transition to chaos in a prototypical hydrodynamic oscillator, namely a globally unstable low-density jet subjected to external time-periodic forcing. As the forcing strengthens at an off-resonant frequency, we find that the jet exhibits a sequence of nonlinear states: period-1 limit cycle $\rightarrow $ quasiperiodicity $\rightarrow$ intermittency $\rightarrow$ low-dimensional chaos. We show that the intermittency obeys type-II Pomeau–Manneville dynamics by analysing the first return map and the scaling properties of the quasiperiodic lifetimes between successive chaotic epochs. By providing experimental evidence of the type-II intermittency route to chaos in a globally unstable jet, this study reinforces the idea that strange attractors emerge via universal mechanisms in open self-excited flows, facilitating the development of instability control strategies based on chaos theory.
Dilatational motions in the shape of travelling wave packets have been identified recently to be dynamically significant in hypersonic turbulent boundary layers. The present study investigates the mechanisms of their generation and their association with the solenoidal motions, especially the well-recognized near-wall self-sustaining process of the regeneration cycle between the velocity streaks and quasi-streamwise vortices. By exploiting the direct numerical simulation databases and orchestrating numerical experiments, we explore systematically the near-wall flow dynamics in the processes of the formation and transient growth of low-speed streaks. We conclude via theoretical ansatz that the nonlinearity related to the parallel density and pressure gradients close to the wall due to the restriction of the isothermal boundary condition is the primary cause of the generation of the dilatational structures at small scales. In fully developed turbulence, the formation and the existence of healthy dilatational travelling wave packets require the participation of the turbulence at scales larger than those of the near-wall regeneration cycles, especially the occurrence of the bursting events that generate vortex clusters. This is proven by the less intensified dilatational motions in the numerical experiments in which the Orr mechanism is alleviated and the vortical structures and turbulent bursts are weakened.
We compute steady planar incompressible flows and wall shapes that maximize the rate of heat transfer ($Nu$) between hot and cold walls, for a given rate of viscous dissipation by the flow ($Pe^2$), with no-slip boundary conditions at the walls. In the case of no flow, we show theoretically that the optimal walls are flat and horizontal, at the minimum separation distance. We use a decoupled approximation to show that flat walls remain optimal up to a critical non-zero flow magnitude. Beyond this value, our computed optimal flows and wall shapes converge to a set of forms that are invariant except for a $Pe^{-1/3}$ scaling of horizontal lengths. The corresponding rate of heat transfer $Nu \sim Pe^{2/3}$. We show that these scalings result from flows at the interface between the diffusion-dominated and convection-dominated regimes. We also show that the separation distance of the walls remains at its minimum value at large $Pe$.
Non-linear polymers, including hyperbranched and star polymers, and dendrimers, which contain emissive chromophores, have been made. Routes to make them are described and compared and their utility in LEDs is discussed.
HMCS Haida was a Tribal-class destroyer that served in the Royal Canadian Navy (RCN) from 1943-1963. Haida sank more enemy surface tonnage than any other Canadian warship. She is also the only surviving Tribal-class destroyer out of 27 vessels that were constructed between 1937-1945 for the Royal Navy, Royal Australian Navy, and the Royal Canadian Navy.