This study experimentally investigates bubble size evolution and void fraction redistribution in an unexplored, coalescence-dominated regime of a decaying turbulent bubbly flow. The flow is generated downstream of a regenerative pump in a duct, with bulk Reynolds number (Re)
$\sim \mathcal{O}(10^5)$, Taylor-scale Reynolds number (Re
$_\lambda$)
$\sim \mathcal{O}(10^3)$ and void fraction (
$\phi$)
$\sim \mathcal{O}(1\,\%)$, where the inlet turbulence is extremely intense (turbulence intensity
$\gt 30\,\%$) but decays rapidly along the duct. Shadowgraph imaging and particle shadow velocimetry are used for measurements. The experimentally obtained turbulent dissipation in the duct flow decays as
$\varepsilon \sim \mathcal{L}^{-2}$, where
$\mathcal{L}$ is the axial position, in close agreement with the homogeneous isotropic turbulence prediction of
$\varepsilon \sim \mathcal{L}^{-2.2}$. High-speed imaging and statistical analysis reveal that bubble coalescence dominates over breakup across most of the domain, leading to monotonic growth in the Sauter mean diameter (
$d_{32}$) and progressive broadening of the bubble size distribution. The normalised extreme-to-mean diameter ratio (
$\mathcal{D}$) increases axially and asymptotically from
${\sim} 1.9$ (breakup regime) and saturates at
${\sim} 2.2$ (coalescence regime), indicating the emergence of a quasi-self-similar bubble size distribution. The probability density function of the bubble diameter exhibits a dual power-law tail with exponents
$-10/3$ and
$-3/2$ near the duct inlet. However, after a few hydraulic diameters, a single
$-3/2$ power-law scaling emerges, indicating a regime of pure coalescence in which all bubbles are smaller than the Hinze scale. The cumulative distribution plotted against
$d/d_{32}$ shows that the slope decreases and the distribution width increases with both axial position and void fraction
$(\phi )$. Although classical Hinze scaling gives
$d_{\textit{H}} \propto \mathcal{L}^{0.9}$, our theory for
$d_{32}$ and
$d_{99.8}$ (99.8th percentile bubble diameter) in a pure-coalescence regime predicts the slower law
$\propto \mathcal{L}^{0.5}$, which our experimental results confirm – indicating negligible breakup and sub-Hinze growth. Concurrently, in contrast to current models, transient
$\phi$ profiles evolve from nearly uniform to sharply core-peaked Gaussian distributions in the developing regime, with increasing centreline values and decreasing near-wall values, due to lift-force reversal. These results provide the first spatially resolved characterisation of coalescence-dominated bubbly flows at high Re, advancing the design of industrial systems as in nuclear cooling and multiphase forming processes (e.g. paper manufacturing, chemical reactors).