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Diamonds are found occasionally in the United States of America. Diamonds from the Prairie Creek lamproite in Arkansas, USA occur within a north to south corridor of Neoproterozoic-to-mid-Cretaceous magmatism that extends across North America. These diamond-bearing lamproites are unusual because they intrude adjacent to sutured and strongly thinned lithosphere rather than stable within-plate settings and the diamonds themselves provide physical evidence of processes related to diamond formation at the cratonic margin. Indeed, A review of previously published geophysical data, isotopic compositions, inclusion suites and inclusion geochemistry suggest most diamonds were formed in subducted and eclogitic rocks within a highly localised diamondiferous lithosphere beneath the cratonic margin.
The morphology and spectroscopic character of 155 diamonds from the Prairie Creek lamproite suggest typical diamond formation conditions in an otherwise thinned continental lithosphere. Most diamonds examined during this investigation have spectroscopic features indicating strong nitrogen aggregation, a history of thermal perturbation and plastic deformation. Nitrogen contents range up to 1882 ppm and the diamonds preserve ∼70% aggregated nitrogen in the B aggregation state. Furthermore, inclusion elastic barometry and time-averaged mantle residence temperatures suggest most Arkansas diamonds formed at 5.2±0.2 GPa and 1205±63°C (1σ). However, a subpopulation of ∼4% of relatively large and inclusion free, colourless, flattened-to-irregular habit Arkansas diamonds are Type IIa with <5 at.ppm nitrogen. Those stones size, morphology, colour and N content might warrant their inclusion in the class of Cullinan-like, Large, Inclusion-Poor, Pure, Irregular and Resorbed or ‘CLIPPIR’ diamonds. Other diamonds examined commonly exhibit physical evidence of plastic deformation, including brown body colour and deformation lamellae.
We define oriented Temperley–Lieb algebras for Hermitian symmetric spaces. This allows us to explain the existence of closed combinatorial formulae for the Kazhdan–Lusztig polynomials for these spaces.
This study employs direct numerical simulations to examine the effects of varying backpressure conditions on the turbulent atomisation of impinging liquid jets. Using the incompressible Navier–Stokes equations, and a volume-of-fluid approach enhanced by adaptive mesh refinement and an isoface-based interface reconstruction algorithm, we analyse spray characteristics in the environments with ambient gas densities ranging from 1 to 40 times the atmospheric pressure under five different backpressure scenarios. We investigate the behaviour of turbulent jets, incorporate realistic orifice geometries and identify significant variations in the atomisation patterns depending on backpressure. Two distinct atomisation types emerge, namely jet-sheet-ligament-droplet at lower backpressures and jet-sheet-fragment-droplet at higher ones, alongside a transition from dilute to dense spray patterns. This variation affects the droplet size distribution and spray dynamics, with increased backpressure reducing the spray's spreading angle and breakup length, while increasing the droplet size variation. Furthermore, these conditions promote distributions that induce rapid, nonlinear wavy motion in liquid sheets. Topological analysis of the atomisation field using velocity-gradient tensor invariants reveals significant variations in topology volume fractions across different regions. Downstream, the droplet Sauter mean diameter increases and then stabilises, reflecting the continuous breakup and coalescence processes, notably under higher backpressures. This research underscores the substantial impact of backpressure on impinging-jet atomisation and provides essential insights for nozzle design to optimise droplet distributions.
The new mineral yellowcatite (IMA2024-030), KNaFe3+2(Se4+O3)2(V5+2O7)·7H2O, was found underground in the School Section #32 mine, Grand County, Utah, USA, where it is a secondary, post-mining phase occurring on montroseite-corvusite-asphaltite-mica-bearing sandstone in association with barnesite, gypsum and mandarinoite. Crystals are thin hexagonal plates, up to ∼0.2 mm in diameter. Crystals are yellow and transparent, with vitreous to pearly lustre and pale-yellow streak. The mineral is brittle with curved fracture and two cleavages: perfect on {001} and good on {100}. The Mohs hardness is ∼2. The measured density is 2.79(2) g·cm–3. Optically, yellowcatite is uniaxial (–) with ω = 1.910(5) and ε = 1.740(5) (white light). The mineral is pleochroic with O yellow and E colourless; O > E. The empirical formula is (K0.65□0.35)Σ1.00(Na0.66Mg0.30)Σ0.96Fe3+2.02Se4+1.99V5+2.01O20H14.02. Yellowcatite is hexagonal, space group P$\bar 6$m2, with cell parameters: a = 5.4966(7), c = 17.2109(16) Å, V = 450.31(13) Å3 and Z = 1. In the crystal structure of yellowcatite (R1 = 5.12% for 281 I > 2σI reflections), Fe3+O6 octahedra, Se4+O3 pyramids and V5+O4 tetrahedra link by corner-sharing to form sheets similar to those in the well-known merwinite structure, but with the apices of the Se4+O3 pyramids in the ‘pinwheels’ pointing in the same direction as the V5+O4 tetrahedra. The unshared vertices of the V5+O4 tetrahedra in adjacent sheets link to one another to form divanadate groups, thereby joining two sheets into a double-sheet slab structural unit. Between adjacent slabs is a layer of unlinked Na(H2O)6 coordinations that are presumed to represent octahedra exhibiting rotational disorder.
W. V. Quine suggests that meaning derives from the stimulus, the effects of the outside world on the subject’s nerve endings. However, the idiosyncrasy of the stimulus poses challenges to the intersubjectivity of meaning. Gary Kemp proposes the stimulus field approach as a solution. The stimulus field approach focuses on the forces affecting the subject, rather than the effects on the subject. In this article, I critique Kemp’s solution. Furthermore, I argue that the Quinean approach can be refined in a way that two agents may converge on the same meaning even without sharing the same stimuli or forces affecting them.
Philosophers have struggled to explain the mismatch of emotions and their objects across time, as when we stop grieving or feeling angry despite the persistence of the underlying cause. I argue for a sceptical approach that says that these emotional changes often lack rational fit. The key observation is that our emotions must periodically reset for purely functional reasons that have nothing to do with fit. I compare this account to David Hume’s sceptical approach in matters of belief, and conclude that resistance to it rests on a confusion similar to one that he identifies.
We have investigated the dynamics of floating tracer in an idealised turbulent quasi-geostrophic ocean by advecting Lagrangian particles in a high-resolution velocity field enhanced by the potential flow associated with vortex stretching. At first order in the Rossby number expansion, this component of the ageostrophic circulation can be derived through a diagnostic equation in terms of the geostrophic velocities. Borrowing methods from the theory of Lagrangian coherent structures, we identify coherent material loops around strong vortex cores using the Lagrangian averaged vorticity deviation (LAVD). Building on studies of clustering in kinematic, stochastic velocity fields, we utilise methods from statistical topography to show that the coherent vortices dominate the distribution of extreme values of the concentration field. We find that the presence of clusters and voids in a coherent vortex depends on more than just the sense of rotation, but also on the full evolution of the vorticity over its lifecycle. We identify the mechanism behind the cluster formation that respects the symmetries of the quasi-geostrophic equations but can be expected to hold robustly in more complicated regimes, due to the simple physical description. The association of cluster formation with vortex stretching implies that LAVD is a particularly relevant metric for floating tracer dynamics. The detection of intense clustering also has implications for reaction rates between ocean-borne flotsam, meaning that our results are relevant to understanding the general risk of floating microplastics and marine biological populations.
Accurate diagnosis of bipolar disorder (BPD) is difficult in clinical practice, with an average delay between symptom onset and diagnosis of about 7 years. A depressive episode often precedes the first manic episode, making it difficult to distinguish BPD from unipolar major depressive disorder (MDD).
Aims
We use genome-wide association analyses (GWAS) to identify differential genetic factors and to develop predictors based on polygenic risk scores (PRS) that may aid early differential diagnosis.
Method
Based on individual genotypes from case–control cohorts of BPD and MDD shared through the Psychiatric Genomics Consortium, we compile case–case–control cohorts, applying a careful quality control procedure. In a resulting cohort of 51 149 individuals (15 532 BPD patients, 12 920 MDD patients and 22 697 controls), we perform a variety of GWAS and PRS analyses.
Results
Although our GWAS is not well powered to identify genome-wide significant loci, we find significant chip heritability and demonstrate the ability of the resulting PRS to distinguish BPD from MDD, including BPD cases with depressive onset (BPD-D). We replicate our PRS findings in an independent Danish cohort (iPSYCH 2015, N = 25 966). We observe strong genetic correlation between our case–case GWAS and that of case–control BPD.
Conclusions
We find that MDD and BPD, including BPD-D are genetically distinct. Our findings support that controls, MDD and BPD patients primarily lie on a continuum of genetic risk. Future studies with larger and richer samples will likely yield a better understanding of these findings and enable the development of better genetic predictors distinguishing BPD and, importantly, BPD-D from MDD.
Let ${\mathcal {E}}$ be a complex elliptic curve and S be a non-empty finite subset of ${\mathcal {E}}$. We show that the functions $\tilde {\Gamma }$ introduced in [BDDT] out of string theory motivations give rise to a basis (as a vector space) of the minimal algebra $A_{{\mathcal {E}}{\smallsetminus } S}$ of holomorphic multivalued functions on ${\mathcal {E}}{\smallsetminus } S$ which is stable under integration, introduced in [EZ]; this basis is alternative to the basis of $A_{{\mathcal {E}}{\smallsetminus } S}$ constructed in loc. cit. using elliptic analogs of the hyperlogarithm functions.
We develop a time-dependent conformal method to study the effect of viscosity on steep surface waves. When the effect of surface tension is included, numerical solutions are found that contain highly oscillatory parasitic capillary ripples. These small-amplitude ripples are associated with the high curvature at the crest of the underlying viscous-gravity wave, and display asymmetry about the wave crest. Previous inviscid studies of steep surface waves have calculated intricate bifurcation structures that appear for small surface tension. We show numerically that viscosity suppresses these. While the discrete solution branches still appear, they collapse to form a single smooth branch in the limit of small surface tension. These solutions are shown to be temporally stable, both to small superharmonic perturbations in a linear stability analysis, and to some larger amplitude perturbations in different initial-value problems. Our work provides a convenient method for the numerical computation and analysis of water waves with viscosity, without evaluating the free-boundary problem for the full Navier–Stokes equations, which becomes increasingly challenging at larger Reynolds numbers.
Few studies examine how often people of color voice their views or shape the discussion in civic or political decision-making groups. Existing studies do not link participants’ private preferences to what they say and lack data on racial inequalities in individuals’ public speech. We analyze a large sample of citizens randomized to groups tasked with deciding on punishment for corporate malfeasance, an issue of consequence for communities of color. We develop systematic measures of racial inequality in voice and uptake during discussion. We find that members of color speak less and are less likely to mention their own preferences. These effects are not explained by racial differences in preferences or by being the lone racial minority. Race also shapes the uptake of preferences during discussion. A seat at the table does not suffice for equal voice.
A new model for the interpretation of radiocarbon (14C) dates of Holocene marine shells is presented. For the Netherlands, the size of reservoir effect is difficult to assess, as these shells often lived in an environment of mixed marine- and river waters. Both stable isotopes 13C and 18O of the shell carbonate give insight in the environmental conditions the shells lived in. River water occurs in two main categories, distinguished by 18O: the Rhine which is dominant, and other rivers. This leads to two estuary mixing lines between the North Sea and rivers. The stable isotopes of the shell carbonate are also indicative for additional processes, such as uptake of secondary carbonate from the soil by shells, and exchange of C isotopes between atmosphere and water. Extensions of the main model deal with special cases such as pools of stagnant water and lakes. The model leads to an assessment of the recent 14C activities of the system the shells lived in, called 14aSYS. The measured 14C activities relative to these 14aSYS values determine the 14C age of the shells and include the reservoir effect. This way we circumvent normalizing to δ13C = –25‰, i.e. the terrestrial timescale and the subsequent correction for reservoir effects. The model is applied to a large legacy dataset of marine shells from the Netherlands, obtained during the last 7 decades. It contains 1116 14C dated shells; for the majority of these, the 3 isotopes 13C, 14C and 18O are measured.
Tri-octahedral clay minerals have the potential to be used as CO2 sorbents at intermediate temperatures (200–400°C) owing to their thermal stability in this temperature range. In this study, Laponite RD®, a commercially synthesized hectorite (with Na+ as the exchangeable cation) was used to investigate its capacity of CO2 adsorption at 200°C and ambient pressure. Various cations such as Co2+, Ni2+, Mg2+ and Ca2+ were employed to exchange Na+, with the aim being to study their effects on the capacity for adsorbing CO2. The commercial sample showed an adsorption capacity of 144 µmolCO2 g–1. Most of the other exchanged samples displayed a lower quantity of CO2 adsorbed. An exception was the Ca2+-saturated sample, which exhibited a better performance (163 µmolCO2 g–1) compared with Laponite RD®. Thus, with its greater affinity towards CO2, such a sample could be a good candidate for CO2 capture. For all of the samples, most of the CO2 was desorbed, and the formation of carbonate bonds was not observed using Fourier-transform infrared spectroscopy, suggesting that the CO2 was mainly physisorbed.
Financial redress for victims of occupational diseases can be offered through no-fault compensation schemes. No-fault compensation schemes have an explicit mission in promoting perceived fairness and justice. The objective is to offer a quick, fair and just procedure and outcome, while preventing civil court procedures and restoring trust. However, the question is whether applicants of these no-fault schemes indeed experience perceived fairness and justice. This paper discusses the result of an in-depth interview study with fifty-eight victims involved in no-fault schemes for occupational diseases in the Netherlands. We focus on the role of perceived procedural justice, outcome concerns and trust in the (former) employer.
The spotted hyena (Crocuta crocuta) was an important large carnivore of Pleistocene ecosystems in Africa and Eurasia. Like its modern relatives, this obligate carnivore was adapted to crush and digest bones of its prey and absorb organic matter from bones more efficiently than any other carnivore. This difference in the nutrient resource use between hyenas and most other carnivores led to differences in the isotope flux and variation in the carbon and nitrogen isotopic composition. In our paper, we assess the prey-to-hyena collagen-to-collagen Δ13C and Δ15N trophic discrimination factor (TDF), a key parameter needed in mixing models used for quantitative reconstruction of diet. We analyzed a Pleistocene hyena den bone accumulation in Perspektywiczna Cave (Poland), with a preserved assemblage of remains containing both hyenas and a wide spectrum of their prey represented by digested bones. With the use of proteomics-based taxonomic identification (ZooMS), we estimated the proportion of prey species in the hyena diet. The modeled collagen-to-collagen TDFs are around +1.6‰ to +1.7‰ for δ13C and around +3.4‰ to +3.5‰ for δ15N. This study provides new data on the dietary habits of this large carnivore and allows for a more accurate use of isotopic signals in modeling past hyena diets.
The global record of fossil hyenid tracks is sparse—the only formal reports that can be considered reliable are of trackways from Tanzania and a single track from Greece. However, trackway and track patterns of the four extant members of the Hyaenidae are distinctive among the tracks of carnivorans. A Pleistocene trackway comprising five manus–pes pairs has been identified on an aeolianite surface on the Cape south coast of South Africa, and is attributed to a hyena, most likely the brown hyena (Parahyaena brunnea). The diagnostic approach followed involves a combination of the knowledge of Indigenous Master Trackers and the methods of modern ichnology.