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Mineralogical crystallography has evolved from the geometric and observational studies of the eighteenth century to a dynamic, predictive science capable of probing matter at atomic and nano-scales. Contemporary advances, including ultrafast X-ray free-electron lasers, high-pressure diamond anvil cells, cryo- and environmental electron microscopy, and multimodal in situ techniques, now permit real-time observation of mineral transformations under extreme conditions. Coupled with computational modelling and predictive simulations, these methods are transforming crystallography into an integrative, interdisciplinary discipline with applications ranging from Earth and planetary sciences to materials engineering. This essay explores technological innovations and emerging frontiers of mineralogical crystallography, highlighting its enduring role in revealing the hidden architectures of matter and guiding the exploration of both natural and synthetic materials.
In this paper, we showcase how flow obstruction by a deformable object can lead to symmetry breaking in curved domains subject to angular acceleration. Our analysis is motivated by the deflection of the cupula, a soft tissue located in the inner ear that is used to perceive rotational motion as part of the vestibular system. The cupula is understood to block the rotation-induced flow in a toroidal region with the flow-induced deformation of the cupula used by the brain to infer motion. By asymptotically solving the governing equations for this flow, we characterise regimes for which the sensory system is sensitive to either angular velocity or angular acceleration. Moreover, we show the fluid flow is not symmetric in the latter case. Finally, we extend our analysis of symmetry breaking to understand the formation of vortical flow in cavernous regions within channels. We discuss the implications of our results for the sensing of rotation by mammals.
Vertical thermal convection exhibits weak turbulence and spatio-temporally chaotic behaviour. For this configuration, we report seven new equilibria and 26 new periodic orbits. These orbits, together with four previously studied in Zheng et al. (J. Fluid Mech., 2024b, vol. 1000, p. A29) bring the number of periodic-orbit branches computed so far to 30, all solutions to the fully nonlinear three-dimensional Navier–Stokes equations. These new and unstable invariant solutions capture intricate spatio-temporal flow patterns including straight, oblique, wavy, skewed and distorted convection rolls, as well as bursts and defects. These interesting and important fluid mechanical processes in a small flow unit are shown to also appear locally and instantaneously in a chaotic simulation in a large domain. Most of the solution branches show rich spatial and/or spatio-temporal symmetries. The bifurcation-theoretic organisation of these solutions is discussed; the bifurcation scenarios include Hopf, pitchfork, saddle-node, period-doubling, period-halving, global homoclinic and heteroclinic bifurcations, as well as isolas. Furthermore, these orbits are shown to be able to reconstruct statistically the core part of the attractor, so that these results may contribute to a quantitative description of transitional fluid turbulence using periodic orbit theory.
During the Middle Bronze Age (ca. 2000–1500 BC), the Carpathian Basin witnessed new cultural groups characterized by distinctively different pottery styles and burial rites but unified by the occupation of sites surrounded by ditches or combinations of ditches and ramparts (Bóna 1975; Kovács 1984; Sørensen and Rebay-Salisbury 2008). Due to their long occupation, many such sites are classified as multi-layered settlements (Gogâltan et al. 2014; Jaeger 2016). Despite extensive research, there remains a lack of detailed information on the absolute chronology, spatial development, and chronological relationships between settlement occupation and fortification construction (Jaeger 2016; Staniuk 2021). Most site chronologies are based on funerary ceramic typologies associated with broad temporal ranges and high uncertainties (Jaeger 2016; Staniuk 2021). Kakucs-Turján is only one of nearly 190 multilayered Middle Bronze Age (MBA) settlements in the Carpathian Basin with a tripartite division of space (Harding 2018; Jaeger 2016) (Figure 1). This, combined with its high-resolution archaeological record makes it ideal for investigating the diachronic relationship between MBA habitations and fortifications (Filatova 2020; Staniuk 2020).
Indigenous and tribal communities often make claims to territory citing their longstanding ties to the land. Since 1989, they increasingly reference ILO Convention No. 169, the only legally binding international agreement on Indigenous and tribal peoples rights. This Element proposes a three-pronged analytical framework to assess the promise and limits of indigenous rights to land as influenced by international law. The framework calls for the place-specific investigation of the interrelations between: (1) indigenous identity politics, (2) citizenship regimes, and (3) land tenure regimes. Drawing on the case of Mexico, it argues that the ILO Convention has generally been a weak tool for securing rights to ancestral land and for effectively challenging the expansion of extractivism. Still, it has had numerous other significant socio-political implications, such as shaping discourses of resistance and incentivizing the use of prior consultation mechanisms in the context of territorial disputes.
In this paper, we study experimentally the dispersion of colloids in a two-dimensional, time-independent, Rayleigh–Bénard flow in the presence of salt gradients. Due to the additional scalar, the colloids do not follow exactly the Eulerian flow field, but have a (small) extra velocity $\boldsymbol{v}_{{dp}} = D_{{dp}}\, \boldsymbol{\nabla }\log C_s$, where $D_{{dp}}$ is the phoretic constant, and $C_s$ is the salt concentration. Such a configuration is motivated by the theoretical work by Volk et al. (2022, J.FluidMech., vol. 948, A42), which predicted enhanced transport or blockage in a stationary cellular flow depending on the value of a blockage coefficient. By means of high dynamical range light-induced fluorescence, we study the evolution of the colloids concentration field at large Péclet number. We find good agreement with the theoretical work, although a number of hypotheses are not satisfied, as the experiment is non-homogeneous in space, and intrinsically transient. In particular, we observe enhanced transport when salt and colloids are injected at both ends of the Rayleigh–Bénard chamber, and blockage when colloids and salt are injected together and phoretic effects are strong enough.
We present experiments of settling and dissolving sugar grains continuously sieved above a water tank with varying grain size and mass flux. Through drag and dissolution, grains force a downward flow whose dynamics are analysed in a laser sheet through particle image velocimetry and the use of home-made fluorescent sugar to track the negatively buoyant sugary water. We reveal different regimes, mostly controlled by the grain size, from a particle-constrained laminar flow at large grain size, to a turbulent plume with an effectively fluid-like behaviour when grains are small. The transitions between regimes are predicted from dimensionless numbers quantifying fluid–particle coupling, collective effects between grains and the possible onset of a Rayleigh–Taylor instability at the source. When a quasi-steady regime is reached, all grains dissolve above a finite depth, below which the flow is exclusively driven by dissolved sugar. We derive simple idealised models based on the source properties that predict the depth of this dissolution layer as well as the characteristic flow velocity.
Travertine is widely distributed in northwestern (NW) Iran and Turkey and serves as a valuable sample for paleoenvironmental reconstructions in semi-arid areas. Previous studies have analyzed the chemical compositions, carbon and oxygen isotopes of the travertines in NW Iran for paleoenvironmental reconstructions, but little dating has been done because travertine 14C dating faces the problem of identifying the initial 14C concentration of each sample. The objective of this study is to determine the formation age of travertine in NW Iran using radiocarbon (14C) and δ13C from a travertine mound and its related spring water. Travertine samples were collected from the base to the top of a cone-shaped travertine mound, Zendan-e Soleyman, in the Takab region of NW Iran. The 14C concentrations of the travertine samples ranged from 0.67 to 3.72 pMC, with values fluctuating considerably and higher 14C being observed at higher elevations. The δ13C values were lower at higher elevations (+10.1 to +7.4‰) with fluctuations. The values suggest that the travertines were formed through the decarbonation of limestone and rapid degassing. The dissolved inorganic carbon (DIC) of nearby spring water samples had 14C concentrations of about 10.4 pMC, about 89.6% dead carbon fraction (DCF), and δ13C value of +1.3‰. These values indicate that one of the of CO2 sources in the travertine-deposited spring water was of hydrothermal origin. Considering the DCF of the spring water DIC, the formation of the travertine mound began about 20 kyr BP, and the growth of the mound ended about 7 kyr BP.
In the standard picture of fully developed turbulence, highly intermittent hydrodynamic fields are nonlinearly coupled across scales, where local energy cascades from large scales into dissipative vortices and large density gradients. Microscopically, however, constituent fluid molecules are in constant thermal (Brownian) motion, but the role of molecular fluctuations in large-scale turbulence is largely unknown, and with rare exceptions, it has historically been considered irrelevant at scales larger than the molecular mean free path. Recent theoretical and computational investigations have shown that molecular fluctuations can impact energy cascade at Kolmogorov length scales. Here, we show that molecular fluctuations not only modify energy spectrum at wavelengths larger than the Kolmogorov length in compressible turbulence, but also significantly inhibit spatio-temporal intermittency across the entire dissipation range. Using large-scale direct numerical simulations of computational fluctuating hydrodynamics, we demonstrate that the extreme intermittency characteristic of turbulence models is replaced by nearly Gaussian statistics in the dissipation range. These results demonstrate that the compressible Navier–Stokes equations should be augmented with molecular fluctuations to accurately predict turbulence statistics across the dissipation range. Our findings have significant consequences for turbulence modelling in applications such as astrophysics, reactive flows and hypersonic aerodynamics, where dissipation-range turbulence is approximated by closure models.
Deformable microchannels emulate a key characteristic of soft biological systems and flexible engineering devices: the flow-induced deformation of the conduit due to slow viscous flow within. Elucidating the two-way coupling between oscillatory flow and deformation of a three-dimensional (3-D) rectangular channel is crucial for designing lab-on-a-chip and organ-on-a-chip microsystems and eventually understanding flow–structure instabilities that can enhance mixing and transport. To this end, we determine the axial variations of the primary flow, pressure and deformation for Newtonian fluids in the canonical geometry of a slender (long) and shallow (wide) 3-D rectangular channel with a deformable top wall under the assumption of weak compliance and without restriction on the oscillation frequency (i.e. on the Womersley number). Unlike rigid conduits, the pressure distribution is not linear with the axial coordinate. To validate this prediction, we design a polydimethylsiloxane-based experimental platform with a speaker-based flow-generation apparatus and a pressure acquisition system with multiple ports along the axial length of the channel. The experimental measurements show good agreement with the predicted pressure profiles across a wide range of the key dimensionless quantities: the Womersley number, the compliance number and the elastoviscous number. Finally, we explore how the nonlinear flow–deformation coupling leads to self-induced streaming (rectification of the oscillatory flow). Following Zhang and Rallabandi (J. Fluid Mech., vol. 996, 2024, p. A16), we develop a theory for the cycle-averaged pressure based on the primary problem’s solution, and we validate the predictions for the axial distribution of the streaming pressure against the experimental measurements.
Sea urchins can have considerable ecological impacts on benthic habitats through grazing and bioerosion and many are exploited as fisheries resources. Of the abundant temperate sea urchins, Centrostephanus tenuispinus is among the least studied. We determined the reproductive seasonality of C. tenuispinus off western Australia at Hall Bank where a high density (2.94 ± 0.14 individuals m−2) of small to medium size (66.23 ± 0.24 mm mean test diameter) urchins has been found to suppress macroalgae recruitment and facilitate hard coral dominance of the benthos and at Minden Reef where, typical of most reefs in the region, a low density (0.14 ± 0.01 individuals m−2), larger sized (100.69 ± 0.45 mm) population occupies a habitat dominated by dense macroalgae. Centrostephanus tenuispinus exhibited a clear synchronized annual reproductive cycle. Gametogenesis began in autumn coincident with lowering sea water temperature and decreasing day length and spawning occurred in late winter and spring. The larger urchins from Minden Reef had significantly larger gonads and a higher % GSI (percentage gonadosomatic index) value than Hall Bank Reef. % GSI increased significantly at both sites between winter and summer, but the magnitude of the increase was much greater at Minden Reef (76%) compared to Hall Bank (10%). The results indicate that both populations have the same reproductive cycle but raise questions about the relative contribution the two populations make to the reproductive output of the species in southwestern Australia.
Devonian stromatoporoid collections have been added to the Natural History Museum, London (UK) for over 100 years. The characteristics and systematic position of these specimens, however, have received little attention. In this study, 297 Devonian stromatoporoid specimens comprising material documented by H. A. Nicholson from the UK, Germany, United States, and Canada, plus specimens described by E. A. Ripper from Australia, were re-examined. Overall, 50 species belonging to 29 genera were systematically redescribed based on recent progress, mainly including Actinostroma, Petridiostroma, Stictostroma, Pseudotrupetostroma, and Parallelopora. Three-dimensional reconstructions reveal stromatoporoid architectural patterns, crucial for enhancing understanding and revision of stromatoporoid identification. This study underscores the significance of three-dimensional reconstruction in taxonomic research on stromatoporoids. The NHMUK material is combined with data from publications and the Paleobiology Database (PBDB) to perform a network analysis of the global occurrence of Devonian stromatoporoids at the generic level; this reveals a close relationship of the global stromatoporoid fauna during the Early Devonian, indicating a widespread distribution, despite this interval being regarded as a time of global stromatoporoid contraction. The Middle Devonian assemblage shows a much higher cosmopolitan occurrence in the context of the subsequent Eifelian–Givetian global stromatoporoid proliferation, consistent with the known pattern from other studies of Middle Devonian stromatoporoids. Overall, the NHMUK collections are a valuable resource to help understand the global occurrence of Devonian stromatoporoids.
We performed three-dimensional simulations to study the motion and interaction of microswimmers (pulling- and pushing-type squirmers) and spheres for Reynolds numbers ranging from 0.01 to 1 under conditions in which all particles were axially aligned with each other. We show that pullers are attractive and pushers are repulsive, in terms of the pressure at the front and rear of the squirmers. Correspondingly, the pullers always come close to each other and form a string that swims slightly faster than does a single puller. A possible reason for this finding is discussed. In contrast, whether a leading puller touches a trailing pusher depends primarily on its strength. When the two have similar strengths, they come into contact and form a stable doublet with finite inertia. The speed of the doublet is substantially higher than that of a single pusher owing to the additional force stemming from the fore and aft pressure differences of the doublet. We also demonstrate how a leading pusher interacts with a trailing puller, which is quite different. In contrast, a sphere can be directly or hydrodynamically ‘pushed’ to run by a puller or a pusher. In particular, we reveal that the sphere exhibits the highest speed when ‘pulled’ by a leading puller and ‘pushed’ by a trailing pusher simultaneously. Grouping behaviours reflect the interacting nature of the microswimmers and spheres from different aspects. A bunch of pushers/pullers eventually appears in pairs or forms a string depending on the Reynolds number, similar to groups of pushers/spheres and pullers/spheres.
This study investigates droplet impact on elastic plates using a two-phase lattice Boltzmann method in both two-dimensional (2-D) and three-dimensional (3-D) configurations, with a focus on rebound dynamics and contact time. The 2-D simulations reveal three distinct rebound modes – conventional bounce, early bounce and rim rising – driven by fluid–structure interaction. Among them, the early bounce mode uniquely achieves a significant reduction in contact time, occurring only at moderate plate oscillation frequency. Momentum analysis shows a non-monotonic relationship between vertical momentum transfer and rebound efficiency: increased momentum does not necessarily promote rebound if it concentrates in a central jet, which contributes minimally to lift-off. This introduces a novel rebound mechanism governed by momentum distribution morphology rather than total magnitude. A theoretical model treating the droplet–plate system as coupled oscillators is developed to predict contact time in the early bounce regime, showing good agreement with numerical results. The mechanism and model are further validated through fully 3-D simulations, confirming the robustness of the findings.
Plane unsteady potential flows of an ideal incompressible fluid with a free boundary are considered in the absence of external forces and surface tension. At the initial time, the flow occupy a wedge with an angle at the apex. For different initial flow velocities and values of the angle at the vertex, a family of exact solutions is found. A method for finding solutions based on reducing the boundary-value problems to systems of ordinary differential equations.