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Titanomagnetite is an Fe–Ti oxide with variable composition (Fe3–xTixO4, 0 ≤ x ≤ 1) and solid solution between magnetite (Fe3O4, x = 0) and ulvöspinel (Fe2TiO4, x = 1) end members. It dominates the magnetism of oceanic basalts, which cover 65% of Earth’s surface. Titanomagnetite is an inverse spinel with variable magnetic properties across its compositional range. Saturation magnetization, anisotropy constant, and Curie temperature values are known for the titanomagnetites, although Curie temperature malleability can make this parameter an inaccurate proxy for composition in natural titanomagnetites. The exchange constant is best known for x = 0 and 0.6. Magnetostriction increases with increasing Ti content due to stresses associated with lattice distortions. The Verwey transition is not observed for low Ti contents, although isotropic points are present over the x < 0.5 compositional range. Magnetic susceptibility is a complex parameter for titanomagnetites because it varies with composition, particle size, and applied field magnitude. While the fundamental magnetic parameters and magnetic properties of titanomagnetite are well understood, knowledge gaps remain that need filling.
This chapter discusses the major features of intraseasonal (weekly to three-monthly) and interannual (year-to-year) variability in the Southern Hemisphere’s atmospheric circulation and their relationship with large-scale modes of variability such as the Madden–Julian Oscillation, El Niño Southern Oscillation, the Indian Ocean Dipole, and the Southern Annular Mode. The interactions between these modes of variability are also explored. Teleconnections to regional large-scale temperature and precipitation variability in the Southern Hemisphere are summarised. While the focus of this chapter is large-scale drivers and circulation patterns, we also briefly discuss regional processes occurring on interannual timescales (such as subtropical dipole modes) and associated impacts. Finally, a brief summary of observed trends and projected future changes to these modes is presented, as well as current challenges and research gaps.
Experimental techniques that are used to estimate the fundamental magnetic parameters and magnetic properties of minerals are outlined in this chapter. Emphasis is placed on techniques that provide fundamental information rather than well-known bulk magnetometry methods. A single presentation of these approaches is lacking in a mineral magnetic context. Techniques described include those used to determine the crystal and magnetic structures of magnetic minerals and include X-ray, neutron, and electron diffraction, Mössbauer spectroscopy, X-ray absorption spectroscopy, X-ray magnetic circular dichroism, X-ray microscopy, electron microscopy, Lorentz microscopy, and off-axis electron holography. Group theory and density functional theory are also described briefly. Techniques used to estimate fundamental magnetic constants, the saturation magnetization, exchange constant, and anisotropy constants are outlined. Finally, methods that enable assessment of magnetic domain state variations, low-temperature magnetic transitions, and Curie/Néel temperature estimation are outlined. This chapter is a ‘how-to’ guide that will assist researchers in progressing the field of mineral magnetism.
Mineral Magnetism provides essential details of the magnetic structure and magnetic properties of terrestrial rock-forming magnetic minerals. Such knowledge underpins mineral magnetic interpretations in diverse applications in the Earth, planetary, environmental, archaeological, biological, materials, and biomedical sciences. This systematic treatment points to knowledge gaps to advocate for concerted effort to fill these gaps. Here, I summarize the state of knowledge outlined in Chapters 5–14 of Mineral Magnetism. Magnetic knowledge for the ‘big five’ magnetic iron oxide minerals is reasonable, with magnetite leading the way, although gaps exist for most minerals. Five other major magnetic minerals (Al-hematite, goethite, 4C and 3C pyrrhotite, and greigite) are much less well characterized than the ‘big five’ iron oxides; much important work remains to be done for each mineral. Little systematic magnetic property information exists for further ‘minor’ magnetic minerals and other oxide spinels. This summary is provided to motivate researchers to conduct new work to fill these gaps and continue to underpin the diverse applications to which mineral magnetism contributes.
Spectral analysis of the transport process of turbulence kinetic energy (TKE) in a channel roughened with spanwise-aligned circular-arc ribs is conducted based on direct numerical simulations (DNS). Test cases of varying pitch-to-height ratios ($P/H=3.0$, 5.0 and 7.5) and bulk Reynolds numbers (${\textit{Re}}_b=5600$ and 14 600) are compared. It is observed that the characteristic spanwise wavelength of the energy-containing eddies in the internal shear layer (ISL) increases as the value of $P/H$ increases, but decreases as the Reynolds number increases. In the ISL, the energy transport processes are dominated by turbulent production as the lead source term, but by turbulent diffusion and dissipation as the lead sink terms. It is found that regions with high production and dissipation rates of TKE in the ISL are associated with moderate and small wavelengths, respectively. The TKE production for sustaining moderate- and large-scale motions enhances gradually with an increasing value of $P/H$, while that for sustaining small-scale motions augments as the Reynolds number increases. It is interesting to observe that the interscale-transport term plays a critical role in draining TKE at moderate wavelengths as a sink and carries the drained TKE to small-scale eddies as a source. It is discovered that a higher pitch-to-height ratio leads to shortening of the characteristic spanwise wavelength of the dissipation process but prolongation of those of the production, interscale-transport and turbulent-diffusion processes in the ISL. By contrast, a higher Reynolds number results in reductions in the characteristic spanwise wavelengths of all spectral transport terms.
The emergence of large-scale spatial modulations of turbulent channel flow, as the Reynolds number is decreased, is addressed numerically using the framework of linear stability analysis. Such modulations are known as the precursors of laminar–turbulent patterns found near the onset of relaminarisation. A synthetic two-dimensional base flow is constructed by adding finite-amplitude streaks to the turbulent mean flow. The streak mode is chosen as the leading resolvent mode from linear response theory. In addition, turbulent fluctuations can be taken into account or not by using a simple Cess eddy viscosity model. The linear stability of the base flow is considered by searching for unstable eigenmodes with wavelengths larger than the base flow streaks. As the streak amplitude is increased in the presence of the turbulent closure, the base flow loses its stability to a large-scale modulation below a critical Reynolds-number value. The structure of the corresponding eigenmode, its critical Reynolds number, its critical angle and its wavelengths are all fully consistent with the onset of turbulent modulations from the literature. The existence of a threshold value of the Reynolds number is directly related to the presence of an eddy viscosity, and is justified using an energy budget. The values of the critical streak amplitudes are discussed in relation with those relevant to turbulent flows.
Procolophonidae, a clade of stem reptiles, are hypothesized to be some of the first highly specialized herbivores to evolve following the end-Permian mass extinction event. That hypothesis is largely based on qualitative observations of tooth shape, which are highly subjective and not generalizable. Quantitative studies of reptilian tooth shape have employed relatively sophisticated methods to capture tooth complexity, but these approaches often require expensive equipment and software and are time intensive. In this study, we built a predictive model based on extant lizards to quantitatively predict the diets of procolophonids using simple measures of tooth morphology. We use linear discriminant analysis (LDA) to predict dietary ecology from tooth dimensions and phylogenetic MANOVA to test for significant differences in tooth dimensions for different diet categories. We report two key findings: (1) procolophonids are largely predicted as herbivorous but occupy a different area of the LDA space from extant lizards, and (2) simple metrics return similar results as complex methods, but with less confidence. We hypothesize that Triassic flora posed different mechanical and processing challenges from modern plants, which contributed to the unique tooth morphologies of procolophonids and likely other Triassic taxa.
The Quaternary period, which began 2.58 million years ago and continues to the present day, is distinctive for its significant climate variability. Understanding the mechanisms of climate change during this period and the relationship between carbon dioxide levels and temperature are hugely important in improving our ability to develop models to predict future climate change. This book discusses the main methods of empirical climatology and the models used to address different aspects of Quaternary climate dynamics, offering a multidisciplinary view of past and future climate changes. It examines the proposed mechanisms of Quaternary climate variability, including glacial cycles and abrupt climate changes, and their relationship to the intrinsic instability of ocean circulation and ice sheets. Including a final chapter on the Anthropocene, it provides a comprehensive overview of Quaternary and modern climate dynamics for graduate students and researchers working in paleoclimatology and climate change science.
A stratigraphic section made of Quaternary alluvial–lacustrine sediments belonging to the Baza Formation (South Spain) has been logged and studied for paleomagnetism, rock magnetic cyclostratigraphy, and electron spin resonance (ESR) quartz dating. Our results indicate that the section, which is found in the vicinity of a number of paleontological and archaeological localities, falls within the mid-Early Pleistocene (Calabrian), within the Matuyama Chron, and runs to the Jaramillo Subchron, encompassing the Cobb Mountain Subchron. The magnetostratigraphic results combined with rock magnetic cyclostratigraphy and ESR provide solid timelines, which allow gross accumulation rates to be estimated, and revealing an upsection decrease of sedimentation in accordance with the lithological and paleodepositional changes. Our study furnishes new chronologies to better understand the timing of the latest stages of endorheic sedimentation that precedes the capture of the Baza Basin by the Gualdalquivir River in the Middle Pleistocene.
In January 1852, as searches continued for Sir John Franklin’s missing Arctic expedition, large quantities of preserved (that is, canned) meats supplied to the Royal Navy were found putrid and caused concern that the expedition had received similar meats with fatal consequences. Whilst a Parliamentary enquiry concluded correctly that the expedition had received good-quality meats, it neglected the fact that some 5% of all canned meats were condemned on ships due to damage and corrosion. As the Franklin expedition would be no exception, the study applies recent evidence of the expedition’s victualling schedule to estimate the number of cans condemned by the time at Beechey Island when a decision would be made whether enough remained to sustain the mission. It also estimates the vitamin B1 (thiamine) content of the meat because high temperatures during canning would have degraded or destroyed that vitamin, and vitamin C, both being essential to health. Any reduction in general rations would add to the decline in the quality of the diet. The expedition’s unique circumstances of long entrapment without recourse to hunting to supplement such deficiencies, or to escape, would prove fatal regardless of the good quality of the canned provisions.
The difference between the ice and water pressures, or the effective pressure, influences water flow and sliding at the ice-bed interface. Effective pressure is typically quantified with subglacial hydrology models because direct measurements of the subglacial environment are sparse. Active subglacial lakes provide an opportunity to constrain effective pressures with altimetry because subglacial water-volume changes manifest at the ice-sheet surface as elevation-change anomalies. Here, we develop a method for estimating effective pressures from altimetry data above active subglacial lakes. We synthesise a previous theory of subglacial lake effective pressure with an altimetry-based inverse method that relates elevation-change data to water-volume changes. We apply the method to elevation-change data from NASA’s ICESat-2 satellite altimetry mission over several active lakes in Antarctica. We find that deviations from flotation (zero effective pressure) are typically a negligible fraction of the overburden (e.g., $\sim$10 kPa), although larger deviations can arise when the ice viscosity is large. For example, effective pressures over subglacial lake Byrds10 in East Antarctica locally reached magnitudes on the order of the tensile strength of glacier ice (e.g., over 100 kPa). These effective pressure estimates can constrain subglacial hydrology models in regions with active subglacial lakes and provide new insights into glacier-bed dynamics.
Electrochemical systems are rapidly evolving beyond traditional water electrolysis, including cathodic hydrogen evolution (HER) and anodic oxygen evolution (OER) reactions, to enhance energy efficiency and generate value-added products simultaneously. Cathodic reactions now facilitate multifunctional reductions – ranging from CO2 conversion into oxygenates and hydrocarbons to nitrogen (N2) fixation, and nitrate (NO3−) reduction – by tuning operational parameters. Hybrid co-reduction approaches, such as CO2/nitrile or CO2/nitrate, further enable the synthesis of valuable amines, amides and urea derivatives, among many others. Notably, even in the most advanced electrochemical configurations, the inclusion of the OER – or a functionally equivalent alternative – remains the most convenient oxidation reaction for maintaining charge balance within the cell. As highlighted in recent studies, alternative oxidation reactions (AORs) coupled with cathodic reduction reactions, such as CO2RR, HER, N2RR and NO3RR, are essential for overcoming the limitations of OER. These AORs include oxidation of biomass-derived alcohols and aldehydes, chlorine and water contaminants. In this perspective, we discuss the emerging promise of AORs – with a particular focus on aldehyde electrooxidation – as innovative alternatives to traditional OER. This strategy not only reduces the energy requirements for electrochemical hydrogen production by circumventing the sluggish and energy-intensive OER, but also enables concurrent hydrogen generation at both electrodes. Additionally, integrating AORs into electrolyzer design enables the direct coupling of CO2 reduction at the cathode with high-value chemical transformations at the anode, offering new opportunities for process intensification and enhanced economic viability in the synthesis of sustainable fuels and chemicals.
Environmental modeling is a powerful tool for facilitating discussions among stakeholders involved in decision-making for environmental planning. This article explores how models can be used to structure stakeholder discussions by visualizing the opportunity space – the range of interventions that are deemed to be technically and physically feasible – and how it overlaps (or does not) with the decision space – the set of interventions considered acceptable or desirable by stakeholders. Using the case study of the Aa of Weerijs catchment in the Netherlands and Belgium, we demonstrate how different model contributions (sensitivity analysis, impact assessment and scenario evaluations at catchment and local levels) can aid these discussions by providing structured insights into potential interventions, both within the opportunity and decision spaces. The findings highlight how models can bridge gaps between stakeholders and technical experts by facilitating more effective discussions and better-informed decision-making processes in environmental planning.
We present a critical survey on the consistency of uncertainty quantification used in deep learning and highlight partial uncertainty coverage and many inconsistencies. We then provide a comprehensive and statistically consistent framework for uncertainty quantification in deep learning that accounts for all major sources of uncertainty: input data, training and testing data, neural network weights, and machine-learning model imperfections, targeting regression problems. We systematically quantify each source by applying Bayes’ theorem and conditional probability densities and introduce a fast, practical implementation method. We demonstrate its effectiveness on a simple regression problem and a real-world application: predicting cloud autoconversion rates using a neural network trained on aircraft measurements from the Azores and guided by a two-moment bin model of the stochastic collection equation. In this application, uncertainty from the training and testing data dominates, followed by input data, neural network model, and weight variability. Finally, we highlight the practical advantages of this methodology, showing that explicitly modeling training data uncertainty improves robustness to new inputs that fall outside the training data, and enhances model reliability in real-world scenarios.
This study presents the first sponge biodiversity inventory of Los Picos reef in Veracruz, Mexico. Although the Veracruz Reef System is known for its high sponge diversity, several recently discovered submerged reefs – including Los Picos – had remained biologically uncharacterised until this investigation. Our comprehensive inventory documents 37 species, identified at the species level, all belonging to Demospongiae; 15 of which are new records for the Mexican coast, and 13 for the Gulf of Mexico (GoM). Six species are described as new: Psammocinia alcoladoi sp. nov., distinguished by a dermal surface armoured with sand and spongin filaments, lightly fasciculated primary fibres, and non fasciculated secondary with long conules and slender fiber diameters; Hyatella hyattus sp. nov., distinguished by its soft and lobular habitus, and slender fiber diameters; Zyzzya marinagreenae sp. nov., is an open fistula with acanthostrongyles irregularly spined and both, acanthostrongyles and isochelae, smaller in size; Desmapsamma paulumharenae sp. nov., has an encrusting shape with larger spicules than D. anchorata; Phorbas veracruzanus sp. nov., consists of conule-shaped processes on an embedded layer and morphometric differences on spicules; and Timea citlallitzina sp. nov., stands out by the lumpy tips of the oxyaster type. The whole, highlighted by two genera, Psammocinia and Zyzzya, both reported for the first time in the GoM. Samples were obtained by SCUBA surveys at 10–16 m depth, between August and October 2017.