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An effective and just Financial Mechanism will be crucial to the success of the Global Plastic Treaty. The content in the latest Chair’s Text from INC-5.1 on finance (primarily in Article 11) could be strengthened to avoid replicating shortcomings in existing financing models, which have often been insufficient and have not always provided the necessary resources for global sustainable development. Experiences with climate finance mechanisms reveal a pattern of misdesign that needs to be addressed. The current Article 11 reflects the deep divisions evident in the two main proposals tabled at INC-5.1 in November 2024. In the light of past precedents and tensions, we argue that several core design principles related to scope, scale and social and health considerations could ensure that the Global Plastics Treaty’s Financial Mechanism supports just, ambitious and transformative global action on plastic pollution. Furthermore, we argue that several elements in the current treaty text may undermine the design and implementation of an effective and just Financial Mechanism for the future Global Plastics Treaty. These risks include overemphasizing waste management; missing connections between finance and other measures in the treaty; risks of not addressing the most effective responses; not adequately addressing plastic leakage, releases and emissions; sustaining financial investments in techno-economic lock-ins lacking sufficient safety and sustainability criteria, standards and monitoring requirements and the prospect of plastic credits, which risks repeating past false solutions. There is an opportunity for the treaty to overcome these challenges with a financial mechanism that addresses overproduction and incentivizes safer, more sustainable, accessible and cost-effective upstream solutions.
Direct numerical simulations are carried out to investigate the underlying mechanism of the low-frequency unsteadiness of a transitional shock reflection with separation at $M=1.5$. To clarify the nonlinear mechanisms, the incoming laminar boundary layer is forced with two different arrangements of oblique unstable modes. Each wave arrangement is given by a combination of two unstable waves such that their difference in frequency falls in a low-frequency range corresponding to a Strouhal number (based on the length of interaction) of 0.04. This deterministic forcing allows the introduction of nonlinearities, and high-order statistical tools are used to identify the properties of quadratic couplings. It is found that the low-frequency unsteadiness and the transition to turbulence are decoupled problems. On the one hand, the unstable modes of the boundary layer interact nonlinearly such that energy cascades to higher frequencies, initiating the turbulent cascade process, and to lower frequencies. On the other hand, the low-frequency quadratic coupling of the oblique modes is found to be responsible for low-frequency unsteadiness affecting the separation point. The direction of the quadratic interactions is extracted and it is shown that, in the presence of low-frequency unsteadiness, these interactions enter the separated zone just before reattachment and travel both downstream and upstream, extending beyond the separation point, hence feeding the low-frequency bubble response. In addition to the two main arrangements of oblique modes, two other combinations are analysed, including multiple oblique waves and streaks. Interestingly, their inclusion did not alter the low-frequency unsteadiness phenomenon. Furthermore, the effect of the forcing difference frequency is examined and it is shown that the breathing phenomenon is sensitive to the range of frequencies present in the system due to a low-pass filter effect.
Ionizing radiation is known to have a destructive effect on biology by causing damage to DNA, cells and the production of reactive oxygen species, among other things. While direct exposure to high-radiation dose is indeed not favorable for biological activity, ionizing radiation can and, in some cases, is known to produce a number of biologically useful products. One such mechanism is the production of biologically useful products via charged particle-induced radiolysis. Energetic charged particles interact with the surfaces of planetary objects such as Mars, Europa and Enceladus without much shielding from their rarefied atmospheres. Depending on the energy of said particles, they can penetrate several meters deep below the surface and initiate a number of chemical reactions along the way. Some of the byproducts are impossible to produce with lower-energy radiation (such as sunlight), opening up new avenues for life to utilize them. The main objective of the manuscript is to explore the concept of a Radiolytic Habitable Zone (RHZ), where the chemistry of galactic cosmic ray-induced radiolysis can be potentially utilized for metabolic activity. We first calculate the energy deposition and the electron production rate using the GEANT4 numerical model, then estimate the current production and possible chemical pathways which could be useful for supporting biological activity on Mars, Europa and Enceladus. The concept of RHZ provides a novel framework for understanding the potential for life in high-radiation environments. By combining energy deposition calculations with the energy requirements of microbial cells, we have defined the RHZ for Mars, Europa and Enceladus. These zones represent the regions where radiolysis-driven energy production is sufficient to sustain microbial metabolism. We find that bacterial cell density is highest in Enceladus, followed by Mars and Europa. We discuss the implications of these mechanisms for the habitability of such objects in the solar system and beyond.
Mass transport induced by group-forced subharmonic waves (infragravity waves) is investigated in the present study. A theoretical solution for subharmonic waves’ kinematic contributions to fourth-order mass transport and drift velocity has been proposed for any depth and bandwidth for the first time. This model is validated using particle-tracking simulations driven by the flow field generated by the SWASH. The subharmonic-induced mass transport solution is a weighted sum of the subharmonic velocity variance spectrum and velocity skewness bispectrum due to the triad-difference interaction among two primary and one subharmonic components. For narrow-banded waves with long wave group relative to depth, the weightings become independent of spectral components, and the solution is recovered in the time domain. Two mechanisms contributing to mass transport were identified: a forward drift resulting from self-interaction similar to Stokes drift, and a depth-decaying backward drift induced by negative subharmonic velocity skewness due to the anti-phase coupling between subharmonics and wave groups. For narrow-banded waves the forward transport surpasses the backward transport for kh< 0.72, where k is the short wave wavenumber and h is the water depth. For other waves, the critical kh for this phenomenon decreases with increasing wave period and bed slope and decreasing bandwidth. At greater depths or steeper bed slopes, near-surface backward transport predominates over forward transport; at shallower depths or gentler slopes, forward transport is dominant throughout the water column. Although smaller than Stokes transport by short waves, the subharmonic wave-induced mass transport can affect the long-term trajectory of a floating and suspended particle. This study provides the first evidence and insight for the influences of group-forced subharmonics on vertically varying mass transport from the ocean surface to seabed in coastal environments.
The incorporation of trace metals into land snail shells may record the ambient environmental conditions, yet this potential remains largely unexplored. In this study, we analyzed modern snail shells (Cathaica sp.) collected from 16 sites across the Chinese Loess Plateau to investigate their trace metal compositions. Our results show that both the Sr/Ca and Ba/Ca ratios exhibit minimal intra-shell variability and small inter-shell variability at individual sites. A significant positive correlation is observed between the shell Sr/Ca and Ba/Ca ratios across the plateau, with higher values being recorded in the northwestern sites where less monsoonal rainfall is received. We propose that shell Sr/Ca and Ba/Ca ratios, which record the composition of soil solution, may be controlled by the Rayleigh distillation in response to prior calcite precipitation. Higher rainfall amounts may lead to a lower degree of Rayleigh distillation and thus lower shell Sr/Ca and Ba/Ca ratios. This is supported by the distinct negative correlation between summer precipitation and shell Sr/Ca and Ba/Ca ratios, enabling us to reconstruct summer precipitation amounts using the Sr/Ca and Ba/Ca ratios of Cathaica sp. shells. The potential application of these novel proxies may also be promising for other terrestrial mollusks living in the loess deposits globally.
Convection in planetary environments is often modelled using stress-free boundary conditions, with diffusion-free geostrophic turbulence scalings frequently assumed. However, key questions remain about whether rotating convection with stress-free boundary conditions truly achieves the diffusion-free geostrophic turbulence regime. Here, we investigated the scaling behaviours of the Nusselt number ($Nu$), Reynolds number (${Re}$) and dimensionless convective length scale ($\ell /H$, where $H$ is the height of the domain) in rotating Rayleigh–Bénard convection under stress-free boundary conditions within a Boussinesq framework. Using direct numerical simulation data for Ekman number $Ek$ down to $5\times 10^{-8}$, Rayleigh number $Ra$ up to $5\times 10^{12}$, and Prandtl number $Pr = 1$, we show that the diffusion-free scaling of the heat transfer $Nu - 1 \sim Ra^{3/2}\, Pr^{-1/2}\, Ek^2$ alone does not necessarily imply that the flow is in a geostrophic turbulence regime. Under the stress-free conditions, ${Re}$ and $\ell /H$ deviate from the diffusion-free scalings, indicating a dependence on molecular diffusivity. We propose new non-diffusion-free scaling relations for this diffusion-free heat transfer regime with stress-free boundary conditions: $\ell /H \sim Ra^{1/8}\, Pr^{-1/8}\, Ek^{1/2}$ and ${Re} \sim Ra^{11/8}\, Pr^{-11/8}\, Ek^{3/2}$. Our findings highlight the need to assess both thermal and dynamic characteristics to confirm geostrophic turbulence.
In turbulent pipe flows, drag-reducing polymers are commonly used to reduce skin-friction drag; however, predicting this reduction in industry applications, such as crude oil pipelines, remains challenging. The skin-friction coefficient ($C_f$) of polymer drag-reduced turbulent pipe flows can be related to three dimensionless parameters: the solvent Reynolds number ($Re_s$), the Weissenberg number ($Wi$) and the ratio of solvent viscosity ($\eta _s$) to zero-shear-rate viscosity ($\eta _0$), denoted as $\beta$. The function that relates these four dimensionless numbers was determined using experiments of various pipe diameters ($D$), flow velocities ($U$) and drag-reducing polyacrylamide solutions. The experiments included measurements of streamwise pressure drop ($\Delta P$) for determining $C_f$, and measurements of shear viscosity ($\eta$) and elastic relaxation time ($\lambda$). This experimental campaign involved 156 flow conditions, each characterised by distinct values for $C_f$, $Re_s$, $Wi$ and $\beta$. Experimental results demonstrated good agreement with the relationship: $C_f^{-1/2} = \widehat {A}\log _{10}(Re_sC_f^{1/2})+\widehat {B}$, where $\widehat {A} = 27.6(Wi \beta )^{0.346}$ and $\widehat {B} = 122/15-58.9(Wi \beta )^{0.346}$. Based on this relationship, onset and maximum drag reduction are predicted to occur when $Wi \beta$ equals $3.76 \times 10^{-3}$ and $3.40 \times 10^{-1}$, respectively. This function can predict $C_f$ of dilute polyacrylamide solutions based on predefined parameters (bulk velocity, pipe diameter, density, solvent viscosity) and two measurable rheological properties of the solution (shear viscosity and elastic relaxation time) with an accuracy of $\pm 9.36$ %.
We describe two new species of green algae in Dasycladales from Lower Cretaceous strata of the Eastern Carpathians (Romania), Suppiluliumaella schlagintweitii n. sp. and Triploporella loducai n. sp. The two new species display mineralization that coats most of the thallus, possibly casting light on their growth patterns. Suppiluliumaella schlagintweitii n. sp. displays a differentiated, club-shaped thallus with a very elongated vegetative part below the fertile zone (“head”) and a corticated external layer, suggesting a Neomeris type of growth. We further describe a possible mineralized juvenile growth stage. Triploporella loducai n. sp. is characterized by a rather short cylindrical thallus with a reduced vegetative region (sharp tapering rounded lower end), seemingly following a growth type resembling that of spherical Bornetella.
Aquatic ecosystem monitoring is important for supporting biodiversity and environmental stability, yet it faces increasing threats from pollution, climate change and human activities. This study presents the development and deployment of a low-cost multi-sensor data logging system for real-time monitoring of Lagos Lagoon. The system integrates temperature sensors, hydrophones, and imaging devices to collect environmental data. Results showed that temperature variations ranged from ~28.5 to 31.5 °C, with fluctuations influenced by partial and full submersion. Acoustic analysis revealed dominant frequencies below 500 Hz, indicative of biological and anthropogenic activity in the lagoon. Machine learning models trained on 31 species closely agreed with the environmental dataset despite some noticeable deviations, suggesting potential improvements through data augmentation and model refinement. Despite challenges such as signal attenuation in submerged conditions and image degradation due to water turbidity, the system successfully recorded and logged environmental parameters. This study demonstrates the feasibility of using artificial intelligence-powered, cost-effective sensor technology for continuous aquatic monitoring, with implications for biodiversity conservation and water resource management. Future research should focus on enhancing wireless communication, refining species detection algorithms and improving sensor resilience in harsh aquatic conditions.
Turbulence closures are essential for predictive fluid flow simulations in both natural and engineering systems. While machine learning offers promising avenues, existing data-driven turbulence models often fail to generalise beyond their training datasets. This study identifies the root cause of this limitation as the conflation of generalisable flow physics and dataset-specific behaviours. We address this challenge using symbolic regression, which yields interpretable, white-box expressions. By decomposing the learned corrections into inner-layer, outer-layer and pressure-gradient components, we isolate universal physics from flow-specific features. The model is trained progressively using high-fidelity datasets for plane channel flows, zero-pressure-gradient turbulent boundary layers (ZPGTBLs), and adverse pressure-gradient turbulent boundary layers (PGTBLs). For example, direct application of a model trained on channel flow data to ZPGTBLs results in incorrect skin friction predictions. However, when only the generalisable inner-layer component is retained and combined with an outer-layer correction specific to ZPGTBLs, predictions improve significantly. Similarly, a pressure-gradient correction derived from PGTBL data enables accurate modelling of aerofoil flows with both favourable and adverse pressure gradients. The resulting symbolic corrections are compact, interpretable, and generalise across configurations – including unseen geometries such as aerofoils and Reynolds numbers outside the training set. The models outperform baseline Reynolds-averaged Navier–Stokes closures (e.g. the Spalart–Allmaras and shear stress transport models) in both a priori and a posteriori tests. These results demonstrate that explicit identification and retention of generalisable components is key to overcoming the generalisation challenge in machine-learned turbulence closures.
A new species of flatfish (Pleuronectiformes) is described from early Oligocene deposits of the Keasey Formation near Mist, Oregon, USA. The rare preservation of an articulated fish in the Mist crinoid lagerstätte is likely because the specimen represents a relatively pelagic immature individual that had not yet settled into the typical benthic lifestyle of adult flatfishes. The new species is included in a phylogenetic analysis; although it is lacking many characters, it is recovered as an early diverging lineage, sister to the extant members of the superfamily Pleuronectoidea. This phylogenetic position fits well with the age of this fossil and conforms with the origin of flatfishes occurring in the early Cenozoic, followed by diversification and radiation throughout the Eocene, Oligocene and Miocene epochs.
Compressible jets impinging on a perpendicular surface can produce high-intensity, discrete-frequency tones. The character of these tones is a function of nozzle shape, jet Mach number, impingement-plate geometry, and the distance between nozzle and plate. Though it has long been recognised that these tones are associated with a resonance cycle, the exact mechanism by which they are generated has remained a topic of some debate. In this work, we present evidence for a number of distinct tone-generation mechanisms, reconciling some of the different findings of prior authors. We demonstrate that the upstream-propagating waves that close resonance can be confined within the jet, or external to it. These waves can be either weak and relatively linear, or strong and nonlinear from their inception. The waves can undergo coalescence or merging, and in some configurations, pairs of waves rather than singletons appear. We discuss both historical and new evidence for multiple distinct processes by which upstream-propagating waves are produced: direct vortex sound, shock leakage, wall-jet-boundary fluctuations, and wall-jet shocklets. We link these various mechanisms to the disparate collection of upstream-propagating waves observed in the data. We also demonstrate that multiple mechanisms can be provoked by a single vortex, providing an explanation as to why sometimes pairs of waves or merging waves are observed. Through this body of work, we demonstrate that rather than being in opposition, the various pieces of past research on this topic were simply identifying different mechanisms that can support resonance.
The paper by Pružina et al. (2025) J. Fluid Mech. 1009, sheds new light on the physical processes responsible for the formation of distinct layers in double-diffusive convection. Towards this end, it discusses direct numerical simulation results within the framework of sorted buoyancy coordinates. In particular, it demonstrates that the eddy diffusivity is negative everywhere, including in the interior of the well-mixed layers. This approach holds promise for analysing other, closely related, flow configurations that give rise to the emergence of pronounced layering features.
Dot array deposition through electrohydrodynamic (EHD) printing is widely used for high resolution and material utilization advantages. However, the conventional printing method is subject to a printing frequency limit known as the capillary frequency of the meniscus oscillation, where the jet directly contacts the substrate. This makes the printing frequency of EHD printing maintain at a low level and that is difficult to improve. In this work, a method for high-frequency EHD printing through continuous pinch-off is proposed. The characteristic frequency is broken through. A model is established to reveal the printing mechanism by combining the Poisson–Nernst–Planck equation and the phase field method. The unreal charge leakage is prevented by constructing a transition function for the fluid’s properties. The stability of the Taylor cone’s deformation and the droplets’ generation is studied. The measurement criterion for printing frequency is determined. The suitable printing height that can prevent the jet from directly contacting the substrate is obtained by investigating its influence on the printing states and frequency. The phase diagram considering the liquid’s conductivity and viscosity is presented to distinguish whether the printing is based on the end-pinching or Rayleigh–Plateau instability. The influence of the conductivity, viscosity, flow rate and printing voltage on the printing frequencies is studied quantitatively. Finally, scaling laws for printing frequency are proposed by theoretical analyses and summarizing the numerical data. This work could be beneficial for further enhancing the printing frequency of EHD printing.
Spaceflight missions must limit biological contamination on both the outbound and return legs to comply with planetary protection requirements. Depending on the mission profile, contamination concerns may include the potential presence of bioactive molecules as defined by NASA’s Planetary Protection policies. Thus, the present study has examined the temperature and time requirements for sufficient inactivation/degradation of an infectious, heat-stable prion protein (Sup35NM), which serves as a model bioactive molecule. Bovine serum albumin was used to establish the method parameters and feasibility. Differential scanning calorimetry, Fourier transform infrared spectroscopy, analytical reversed-phase high-performance liquid chromatography, and mass spectrometry were utilized to analyze heat-treated samples, with non-treated samples serving as controls. Heat treatment at 400°C for 5 seconds was found to result in substantial decomposition of Sup35NM. In addition to the disruption of the protein backbone amide bonds, the side chain residues were also compromised. Fragments of molecular weight <4600 were observed by mass spectrometry but the impact of treatment on both the backbone and side chains of Sup35NM suggested that these fragments would not self-associate to create potentially pathogenic entities. The present methodology provided insight into the protein degradation process and can be applied to a variety of treatment strategies (e.g., any form of sterilization or inactivation) to ensure a lack of protein-based contamination of isolated extraterrestrial specimens.
Biodiversity knowledge gaps and biases persist across low-income tropical regions. Genetic data are essential for addressing these issues, supporting biodiversity research and conservation planning. To assess progress in wildlife genetic sampling within the Philippines, I evaluated the scope, representativeness, and growth of publicly available genetic data and research on endemic vertebrates from the 1990s through 2024. Results showed that 82.3% of the Philippines’ 769 endemic vertebrates have genetic data, although major disparities remain. Reptiles had the least complete coverage but exhibited the highest growth, with birds, mammals, and amphibians following in that order. Species confined to smaller biogeographic subregions, with narrow geographic ranges, or classified as threatened or lacking threat assessments were disproportionately underrepresented. Research output on reptiles increased markedly, while amphibian research lagged behind. Although the number of non-unique authors in wildlife genetics studies involving Philippine specimens has grown steeply, Filipino involvement remains low. These results highlight the uneven and non-random distribution of wildlife genetic knowledge within this global biodiversity hotspot. Moreover, the limited participation of Global South researchers underscores broader inequities in wildlife genomics. Closing these gaps and addressing biases creates a more equitable and representative genetic knowledge base and supports its integration into national conservation efforts aligned with global biodiversity commitments.
Sulfur stable isotope ratios (δ34S) have become increasingly common in archaeology for studying paleodiet, especially in occasions where there is a need to identify aquatic resource consumption more accurately. This is particularly relevant in the Baltic Sea region, where brackish conditions tend to mask “typical” marine carbon isotopic signals. Here we report new δ34S values for 126 human bone collagen samples which will be analyzed together with previously published data to investigate the potential of sulfur isotopes as an alternative proxy for aquatic resource consumption in historic period Estonia (ca. AD 1100‒1800). Bayesian statistical programming was used to provide quantitative dietary estimates, suggesting that the diet of the general population was predominantly terrestrial. The inclusion of δ34S as an additional dietary proxy produced generally comparable model results to the scenario that excluded δ34S. A sub-selection of samples was also radiocarbon dated and calibrated to take into account potential reservoir effects. For burials of commoners, the average contribution of 10% fish to dietary carbon does not significantly alter calibrated date ranges, even in the occasion where data on local reservoir effects is insufficient. This study has demonstrated both the potential and the pitfalls of using δ34S in this temporo-spatial context, and the new stable isotope and 14C data have shed light onto individual site-histories but also to broader cultural processes and changes that occurred during these turbulent times in this region.