In this appendix we review some of the basic ideas and methods behind quantum mechanics. This brief treatment is meant only to introduce the reader to this important subject. A number of elementary texts are listed in the Suggested reading for those who would like to go further into this fascinating field.
HISTORY
Quantum mechanics arose from an attempt to understand discrepancies between predictions of classical mechanics and observed (experimental) behavior. Around 1900, there was increasing recognition that some phenomena could not be understood based on classical physics. One of these problems was blackbody radiation, i.e., the glow that is given off by a heated object which is an indicator of its temperature. Planck came up with an explanation for blackbody radiation in a cavity, but had to describe the energetics of the system as consisting of oscillators whose energy was quantized (i.e., integer multiples of some quantity). In 1905, Einstein took that idea one step farther and proposed that electromagnetic radiation (i.e., light) is itself quantized as an explanation of the photoelectric effect. We now call these quanta of light photons.
One of the other main failures of classical theory was its inability to explain the spectrum of hydrogen, which has distinct lines. One of the most important results from the quantum mechanical description of the H atom, and of all matter, is that quantum systems have states with discrete energy levels (not continuous as in classical mechanics). Transitions of electrons between these discrete levels lead to the observed spectra of the H atom and other atoms and molecules.
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