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This work studies the hydrothermal synthesis of zeolitic materials from three types of industrial waste (granite cutting sludge; slate cutting sludge and aggregate washing sludge), which are regarded as low-cost materials. The synthesis was carried out through acid pretreatment with aqua regia to minimize iron content, followed by alkaline melting at 600°C followed by a hydrothermal crystallization stage at 180°C for 12 h. Characterization of the three synthesized zeolite materials by X-ray fluorescence, X-ray diffraction, Fourier-transform infrared spectroscopy and scanning electron microscopy with energy-dispersive X-ray spectroscopy confirmed that the methodology used induced the formation of LOS (Losod) zeolite (Na12Al12Si12O48·xH2O) as the predominant phase in all products, regardless of the waste used as the raw material. The end-products have a significant amorphous fraction (33–43 wt.%) and a zeolitic crystalline fraction (51–66 wt.%) and are enriched in Na and Al, and they have Si/Al and Na/Al ratios ranging from 1.27 to 1.39 and from 0.58 to 1.05, respectively, characteristic of low-silica zeolites. The synthetic zeolites showed reduced CO2 adsorption capacities at room temperature (0.50–0.55 mmol g–1) compared to commercial zeolites such as 13X (3.45 mmol g–1).
Coarse-grained continuous descriptions for lipid bilayers are typically based on minimising the Helfrich energy. Such models consider the fluid properties of these structures only implicitly and have been shown to nicely reproduce equilibrium properties. Model extensions that also address the dynamics of these structures are surface (Navier–)Stokes–Helfrich models. They explicitly account for membrane viscosity. However, these models also usually treat the lipid bilayer as a homogeneous continuum, neglecting the molecular degrees of freedom of the lipids. Here, we derive refined models that consider in addition a scalar order parameter representing the molecular alignment of the lipids along the surface normal. Starting from hydrodynamic surface liquid crystal models, we obtain a hydrodynamic surface Landau–Helfrich model for asymmetric lipid bilayers and a surface Beris–Edwards model for symmetric lipid bilayers. The fully ordered case for both models leads to the known surface (Navier–)Stokes–Helfrich models. Besides more detailed continuous models for lipid bilayers, we therefore also provide an alternative derivation of surface (Navier–)Stokes–Helfrich models. The impact on the dynamics is demonstrated by numerical simulations.
To address the challenges of long voyages and the significant effects of Earth’s curvature on ocean navigation, this paper proposes, for the first time, a guidance and control strategy for great-circle routes based on Mercator projection nautical charts. First, a guidance strategy for great-circle routes is designed by combining the traditional line-of-sight (LOS) algorithm with spherical triangles. Tracking control is subsequently achieved through the integration of a closed-loop gain-scheduling algorithm. Next, the vessel’s position is transformed from a planar map to a Mercator projection nautical chart to better meet the practical needs of maritime engineering. Finally, the effectiveness of the designed guidance and control algorithm is verified through simulations. The experimental results show that the proposed guidance and control strategy can significantly enhance the stability of the vessel along the great-circle route, reduce navigation time and lower fuel consumption, demonstrating high navigation efficiency and economy.
The inner–outer interaction model (IOIM), first proposed by Marusic et al. (Science, 2010, vol. 329, pp. 193–196), has proven to be an effective turbulence model for canonical and non-canonical wall-bounded flows, where a reference velocity signal from the logarithmic region acts as the input for predicting near-wall velocity fluctuations. Its most recent iteration by Baars et al. (Phys. Rev. Fluids, 2016, vol. 1, p. 054406) further proposes a user-independent scale separation point, refining model parameters. In this study, we compared the long-perceived universal IOIM’s parameters, including the linear transfer kernel, amplitude modulation coefficients and the universal signal for a range of Reynolds and Mach numbers, where mathematical relationships between the parameters are proposed. We observed that while the universal signals exhibit a high degree of similarity, particularly near the wall, the amplitude modulation coefficients and linear transfer kernels display Reynolds and Mach number effects, where varying the reference location also causes them to exhibit significant changes. We have found transformations to collapse amplitude modulation coefficients for incompressible flows and differing reference locations, improving modelling via the IOIM across flow parameters. Despite this, compressibility effects cannot be suitably accounted for currently and remain a future challenge for the IOIM framework.
Many species of hermit crabs, such as Calcinus and Clibanarius spp., live on rocky shores in tropical and warm temperate regions. During low tide, some of these species climb out of tidal pools onto exposed rock surfaces with their shell-aperture directed upwards. However, the adaptive significance of the ‘air-exposure (AE) behaviour’ was only previously investigated in several Clibanarius species; this behaviour is hypothesised to prevent competition for shells in tide pools during low tide. Considering the lack of knowledge of Calcinus species, understanding their significance is necessary to elucidate the ecological or evolutionary and general adaptive significance of AE behaviour in hermit crabs. The AE behaviour of Ca. laevimanus, which is the dominant species in sub-tropical and tropical rocky shores, was investigated on the rocky shores of Naze, Amami, Kagoshima, Japan. The generalised linear model indicated a significant positive effect of the gastropod shell length on the occurrences of this AE behaviour. Therefore, the current result indicates that individuals with larger gastropod shells, which offer them the potential to grow to larger sizes, more frequently engage in AE behaviour during low tides. The present result supports the previous hypothesis but suggests that external factor (i.e. shell size)-dependent AE behaviour has evolved in Calcinus species, which differs from the internal factor (i.e. body size or sex)-dependent AE behaviour in Clibanarius species.
Lebanon has known permanent and successive human occupations since the Lower Palaeolithic, which contributed largely to its rich archaeological and cultural heritage. Numerous archaeological excavations have unearthed remains spanning most prehistorical and historical periods. The Chalcolithic (ca. mid-5th to mid-4th millennium BCE in the Levant), the focus period of this paper, represents a critical transitional phase in prehistoric societal evolution, though absolute chronological data from this period in Lebanon remains limited. A few sites from this period have been studied in Lebanon, with very few 14C dates produced. The RML79 site lies on the northern slope of the Ashrafieh hill, to the east of the capital Beirut, and was excavated intermittently between 2008 and 2012. The preliminary phasing of the site is based on the retrieved ceramics, which indicate that the site was occupied as early as the Chalcolithic period, giving for the first time new insights into a human occupation from this period in the eastern outskirts of the capital. Radiocarbon dates of four charcoal samples collected from the Chalcolithic phase of RML79 confirmed that the latter occupation occurred during the second half of the fifth millennium, with a possible peak in human activity between 4330 BCE and 4000 BCE.
Implicit in the construction of seed transfer zones (STZs) are the assumptions that plant populations are adapted to their home climates and that transferring native seed across climate gradients risks maladaptation and poor performance. However, plants are adapted to multiple aspects of their environments that are often excluded from STZ development. Here, we used models integrating geographic distance, climate distance and soil metrics to predict plant mortality in an experimental garden for three restoration-relevant species in the southwestern United States: Bouteloua curtipendula, Heterotheca villosa and Sporobolus cryptandrus. Overall, climate distance explained mortality better than geographic distance, but increasing climate distance was not consistently associated with higher mortality. In contrast, mortality always increased with geographic distance. Species responded idiosyncratically to environmental gradients such as soil texture and pH, indicating that incorporating site-specific variables beyond climate can improve predictions of survival. Finally, seed sources of H. villosa from hotter, drier climates exhibited improved survival during abnormally hot, dry conditions at the experimental site, whereas no consistent pattern emerged for the two grass species. Collectively, our results suggest that seeding strategies extending beyond climate matching alone may better support restoration outcomes when species-specific guidance is unavailable.
A recent study by Zhang et al. (2024, J. Fluid Mech., vol. 979, A43) introduced an effective control strategy, namely streamwise-uniform spanwise equally distributed injection/suction slots on the pressure (unstable) wall, to enhance passive scalar transport in spanwise rotating plane Poiseuille flows (RPPFs). In this work, we employ direct numerical simulations to further investigate the scalar transport increase rate ($\textit{STI}$) under different slot configurations. Two distinct configurations are investigated, namely uniform-width slots, where injection and suction slots share identical dimensions, and non-uniform-width slots, where their widths vary independently. The former is to examine the effect of slot width, whereas the latter is devoted to distinguishing the individual roles of injection versus suction. While the slot widths change, the root mean square wall-normal velocity is maintained at a fixed minimal value. For uniform configurations, $ \textit{STI}$ increases monotonically with slot width, nearly doubling as the width grows from $\pi /8$ to $\pi /2$. In contrast, non-uniform configurations exhibit a complex, non-monotonic dependence on slot dimensions. Spectral, quadrant and zonal-conditional quadrant analyses reveal that injection and suction slots play distinct roles in modulating near-wall dynamics. Injection enhances ejection events ($Q2$), promoting local plume detachment, and facilitating the formation of large-scale ascending plume currents. Suction, conversely, strengthens sweep events ($Q4$), suppressing plume detachment while intensifying descending currents. This dual mechanism organises turbulent structures into more stable large-scale structures, thereby improving scalar transport efficiency. A decomposition of $ \textit{STI}$ based on clustering analysis confirms that the enhancement stems primarily from increased occurrence possibilities and improved transport capacities of dominant clusters. These findings establish flow stabilisation through selective slot control as an effective mechanism for enhancing passive scalar transport in RPPFs.
This work investigates experimentally and numerically the dynamics of rigid particles with two orthogonal symmetry planes settling under gravity in a highly viscous fluid at a Reynolds number much smaller than one. Joshi & Govindarajan (2025 Phys. Rev. Lett. 134(1), 014002), showed theoretically that for such shapes, the dynamics are qualitatively different for different signs of the product of two rotational–translational mobility coefficients, evaluated with respect to the particle centre of mass in a symmetric reference frame. However, upon examining a particle’s shape, it is not immediately evident if this product is negative, positive or zero. In this paper, we demonstrate how to estimate these coefficients and the sign of their product from experiments, using special initial orientations, and also numerically, based on the Stokes equations. Especially interesting are the ‘settlers’ – such particles that reorient and approach a stationary stable orientation, and we focus our study on this class of shapes. We show experimentally that cones, crescent moons, arrowheads and open flat rings are the settlers, and we evaluate from the experiments their rotational–translational mobility coefficients. Then, we reconstruct each experimental shape as a rigid conglomerate of many touching beads, and use the precise Hydromultipole code to calculate the mobility coefficients for the conglomerate. The numerical and experimental values are close enough to determine that the particles are the settlers, and to estimate the characteristic reorientation time scales. Our findings apply to non-Brownian micro-objects in water-based solutions – experimentally by the similarity principle and theoretically based on the Stokes equations. The reorientation of sedimenting rigid particles to a stationary stable configuration in a relatively short time might be used for environmental, biological, medical or industrial applications.
Contrary to accepted turbulence folklore, which holds that no mathematical relation exists between the Navier–Stokes equations (NSEs) and the multifractal model (MFM) of Parisi and Frisch, we develop a theory that reconciles the MFM with Leray’s weak solutions of Navier–Stokes analysis. From a combination of Euler invariant scaling and the NSEs set in a three-dimensional box of side $L$, we also derive the Paladin–Vulpiani scale $\eta_{h,pav}$ which is related to the Reynolds number Re by $L\eta _{h,\textit{pa}v}^{-1} = \textit{Re}^{1/(1+h)}$, and which acts as a mediator between the two theories. This is achieved by considering $L^{2m}$-norms of the velocity gradient to find a correspondence between $m$ and the local scaling exponent $h$ in the multifractal model. The parameter $m$ acts as if it were the sliding focus control on a telescope which allows us to zoom in and out on different structures. The range $1 \leqslant m \leqslant \infty$ is equivalent to $-{{ {2}/{3}}} \leqslant h_{\textit{min}} \leqslant {{{1}/{3}}}$, which lies precisely in the region where Bandak et al. (Phys. Rev. E, 2022, vol. 105, p. 065113; Phys. Rev. Lett., 2024, vol. 132, p. 104002) have suggested that thermal noise makes the NSEs inadequate and generates spontaneous stochasticity. The implications of this are discussed.
Flow around a submerged cylinder near a free surface reveals that adjusting the Froude number and gap ratio influences the underwater jet pattern, vortex shedding frequency and free-surface deformation. The jet typically separates near the trough, leading to vorticity concentration and breaking waves that dissipate wave energy. Antarctic orcas collaborate to generate deep depression waves, breaking ice and washing seals from floes. Orcas raise their heads and tap their tails downward when approaching ice, which may benefit strong wave generation. We investigate the wave-generating hydrodynamics using a towing tank and particle image velocimetry. A scaled model with an elliptical body and wedge-shaped tail was tested under Froude number similarity. Experiments covered towing speeds of $0.3- 0.7\,\textrm{ms}^{-1}$, combining different body ($10^\circ$/$0^\circ$/$-10^\circ$) and tail angles ($30^\circ$/$0^\circ$/$-30^\circ$), at chord-based Reynolds numbers of $17\,030- 40\,506$. Four wake regimes are identified: small-scale vortex emergence triggered by capillary waves; extensive wave breaking due to flow separation at the trough; smooth depression wave caused by jet reattachment and downward advection of wake vortices; and large-scale vortex impingement generated by wake vortex perturbations. Under the pitched posture, the jet attaches successively to the solid surface and the trough via the Coandâ effect, suppressing flow separation, creating the most pronounced wave. The strong jet maintained a low-potential-energy state of the wave and led to large ice floes flipping and fracturing through the bending effect, while smaller ice floes were overwashed. This study suggests a novel flow-control strategy for objects near the free surface through jet attachment.
Neural network observers (NNOs) are proposed for online estimation of fluid flows, addressing a key challenge in flow control: obtaining flow states online from a limited set of sparse and noisy sensor data. For this task, we propose a generalisation of the classical Luenberger observer. In the present framework, the estimation loop is composed of subsystems modelled as neural networks (NNs). By combining flow information from selected probes and a neural network surrogate model (NNSM) of the flow system, we train NNOs capable of fusing information to provide the best estimation of the states, that can in turn be fed back to a neural network controller (NNC). The NNO capabilities are demonstrated for three nonlinear dynamical systems. First, a variation of the Kuramoto–Sivashinsky (KS) equation with control inputs is studied, where variables are sparsely probed. We show that the NNO is able to track states even when probes are contaminated with random noise or with sensors at insufficient sample rates to match the control time step. Then, a confined cylinder flow is investigated, where velocity signals along the cylinder wake are estimated by using a small set of wall pressure sensors. In both the KS and cylinder problems, we show that the estimated states can be used to enable closed-loop control, taking advantage of stabilising NNCs. Finally, we present a legacy dataset of a turbulent boundary layer experiment, where convolutional NNs are employed to implement the models required for the estimation loop. We show that, by combining low-resolution noise-corrupted sensor data with an imperfect NNSM, it is possible to produce more accurate and robust estimates. Our approach presents better robustness to noise when compared with direct reconstructions via super-resolution NNs and predictions from graph NNs and Fourier neural operators.
High-latitude environments subject residents to extreme seasonal variations in light. This qualitative study examined how civilians living at high northern latitudes experience and manage sleep, mood and time across winter darkness and summer light. Twenty-eight adults residing in Scandinavia, Estonia and Canada completed an in-depth online, open-ended survey. Using reflexive thematic analysis, we identified a lived ecology of seasonal strain spanning physiology, emotion and temporal experience. Participants described winter as heavier sleep with difficult awakenings, inertia and flatter affect and summer as shallow, fractured sleep and a “wired” restlessness. Evening-type (“night-owl”) individuals reported greater strain across both seasons: winter mornings felt biologically unworkable, whereas summer nights never properly “started.” Crucially, people also reported changes in how they experienced time itself. Under unstable photoperiods, “day” and “night” became things to make rather than to feel: weeks “blurred” without deliberate anchors, prompting intentional “temporal scaffolds” such as fixed wake times and mealtimes, blackout in summer, morning light in winter, seasonal rituals, scheduled outdoor exposure, and, for some, temporary relocation. We interpret these accounts within circadian alignment and social zeitgeber frameworks and extend them by specifying temporal experience, not just sleep or mood, as a key outcome of environmental light. Implications include chronotype-aware screening in primary care, normalising circadian and temporal hygiene in public messaging, and embedding light scheduling and routine-based supports within fatigue-risk management for isolated, confined and extreme operations. The findings provide an ecological description of civilian adaptation at high latitude and generate testable predictions for future quantitative and operational studies.
Bayesian modeling applied to accelerator mass spectrometry radiocarbon (AMS 14C) dates on samples associated with burials and seasonal campsites of various cultures suggests a revised chronology for the Sal steppes and northern fringes of the Kuma-Manych Depression in the Lower Don region in the south of the Russian Plain. The new chronological framework makes it possible to eliminate existing time gaps and refine or extend chronological periods. It also shows short overlapping periods with co-existence of regional groups. The time range covers several millennia, from the fifth millennium BC to the middle of the second millennium AD. The new radiocarbon chronology reveals significant regional differences. These results are very important because the Lower Don region stands out from other regions due to its geographical location, and because its populations had a large impact on the cultural development in eastern Europe and beyond throughout millennia.
In maritime transportation, pilotage plays a crucial role in ensuring navigational safety. Marine pilots possess in-depth knowledge of local waters, currents and weather conditions, guiding ships safely through complex waterways. This expertise minimises risks such as collisions and groundings, thereby protecting both the ship and the environment, and promoting safe, efficient maritime traffic management. However, grounding accidents in pilotage waters can still lead to severe environmental, economic and operational damage, including oil spills, ecosystem harm and costly salvage efforts. Continuous improvements in pilotage are therefore vital to minimise these risks. In this study, with the combination of HFACS methodology and Apriori algorithm, factors contributing to grounding accidents in ships navigating with marine pilots and ship features are examined, and strong association rules among factors are achieved. The prominent factors discovered are ‘Ship–Marine Pilot Communication Problems’, ‘Inappropriate Passage Plan’, ‘Ineffective Usage of Bridge Equipment’, ‘Port Authority Resource Management’ and ‘Ineffective Teamwork’. Ship-marine pilot communication problems are the most prevalent factor in these derived rules which is appearing in 8 of 9 rules and exerting a substantial influence on the accidents. Inappropriate passage planning, identified in 6 rules, emerges as another significant and recurrent contributing factor. Based on the association rules, this study provides significant insights and actionable recommendations for stakeholders to prevent grounding accidents in marine pilot-assisted navigation.
This work presents a predictive two-point statistical closure framework for turbulence formulated in physical space. A closure model for ensemble-averaged, incompressible homogeneous isotropic turbulence (HIT) is developed as a starting point to demonstrate the viability of the approach in more general flows. The evolution equation for the longitudinal correlation function is derived in a discrete form, circumventing the need for a Fourier transformation. The formulation preserves the near-exact representation of the linear terms, a defining feature of rapid distortion theory. The closure of the nonlinear higher-order moments follows the phenomenological principles of the eddy-damped quasi-normal Markovian (EDQNM) model of Orszag (J. Fluid Mech., vol. 41, 1970, pp. 363–386). Several key differences emerge from the physical-space treatment, including the need to evaluate a matrix exponential in the evolution equation and the appearance of triple integrals arising from the non-local nature of the pressure–Poisson equation. This framework naturally incorporates non-local length-scale information into the evolution of turbulence statistics. Verification of the physical-space two-point closure is performed by comparison with direct numerical simulations of statistically stationary forced HIT and with classical EDQNM predictions and experimental data for decaying HIT. Finally, extensions to inhomogeneous and anisotropic turbulence are discussed, emphasising advantages in applications where spectral methods are ill-conditioned, such as compressible flows with discontinuities.